Composite materials for use in injection moulding methods
A technology of composite materials and thermoplastic polymers, applied in the field of composite materials, can solve the problems that composite materials are not suitable for fine structures
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Embodiment 1
[0044] In a first example, the following composition was used for five inventive composite materials 1.A, 1.B, 1.C, 1.D, 1.E: 10% by weight of polyamide PA12 as polymer group 80% by weight of metal powder A, B, C, D or E according to Table 1 (here, the letter of each material indicates the metal powder used) as the first filling component, 8% by weight of fiber length is Wollastonite with a fiber diameter of about 250 μm and about 15 μm as the second filling component and 2% by weight of 3-aminopropyltriethoxysilane and 3-(2,3-glycidoxy) Propyltrimethoxysilane is a tackifier component in a 1:1 weight ratio.
[0045] Table 1A
[0046] Composition number Polymer [wt%] Metal [wt%] Wollastonite [wt%] Tackifier [wt%] 1.A, 1.B (Metal: Bronze) 10 80 8 2 1.C (Metal: Brass) 10 80 8 2 1.D, 1.E (Metal: Copper) 10 80 8 2
[0047] Polyamide PA12 is a thermoplastic polymer composed of 12-aminododecanoic acid monomers. It has been known for...
Embodiment 2
[0071] In another embodiment, the weight content of the components is varied. Compositions 2.A to 2.E of the composite material according to the invention are composed as follows: 8% by weight of polyamide PA12 as polymer component, 85% by weight of metal powders A, B, C, D or E according to Table 1 as First filling component, 5% by weight of wollastonite with a fiber length of about 250 μm and a fiber diameter of about 15 μm as the second filling component and 2% by weight of 3-aminopropyltriethoxysilane and 3-(2,3-Glycidoxy)propyltrimethoxysilane is a tackifier component in a 1:1 weight ratio. According to volume content conversion, it obtains the composition listed in Table 4:
[0072] Table 4
[0073] Composition number Polymer [vol%] Metal [vol%] Wollastonite [vol%] Tackifier [vol%] Density [g / cm 3 ] 2.A, 2.B (Bronze) 33.1 50.2 8.4 8.3 4.7 2.C (brass) 34.1 48.6 8.7 8.5 4.9 2.D, 2.E (copper) 35 47.4 8.9 8.7 5.0
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Embodiment 3
[0079] In yet another embodiment, compositions 3.A to 3.E of the composite material according to the invention each comprise 13% by weight of polyamide PA12 as polymer component, 70% by weight of metal powders A, B according to Table 1 , C, D or E as the first filling component, 15% by weight of wollastonite with a fiber length of about 250 μm and a fiber diameter of about 15 μm as the second filling component and 2% by weight of 3-aminopropyl A tackifier component composed of triethoxysilane and 3-(2,3-glycidoxy)propyltrimethoxysilane in a weight ratio of 1:1. Table 6 below contains compositions converted according to volume content:
[0080] Table 6
[0081] Composition number Polymer [vol%] Metal [vol%] Wollastonite [vol%] Tackifier [vol%] Density [g / cm 3 ] 3.A, 3.B (Bronze) 41.8 32.1 19.6 6.4 3.7 3.C (brass) 42.6 30.8 20 6.6 3.7 3.D, 3.E (copper) 43.3 29.7 20.3 6.7 3.8
[0082] Corresponding to the lower metal conten...
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