A quantitative detection method for edetate disodium and sodium pyrosulfite in Shenqi Fuzheng injection
A quantitative detection method, the technology of edetate disodium, is applied in the direction of measuring devices, instruments, scientific instruments, etc., which can solve the problems of quality and safety hazards, additives that have not established a public quality control method, and the deviation of feeding amount, etc., to achieve optimization Use, ensure the quality and safety of drugs, and ensure the effect of drug safety
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Embodiment 1
[0042] 1 Instruments and reagents
[0043] 1.1 Instrument: Ion chromatograph: DIONEX ICS-2000 (Dionex); Chromatographic column: IonPac AS11-HC (4×250mm) (Dion); Guard column: IonPac AH11-HC (4×50mm) (Dion company); Detector: conductivity detector (Dion Corporation); eluent tank: EGCII KOH (090581489019). Millipore pure water meter.
[0044] 1.2 Reagent: edetate disodium reference substance (batch number: 20100311, Hangzhou Liren Pharmaceutical Co., Ltd.); sodium metabisulfite reference substance (batch number: 20100301, Hunan Erkang Pharmaceutical Co., Ltd.). Sep-Pak Cartridges Vac C18 3cc Cartridges (Waters). Shenqi Fuzheng Injection was provided by Limin Pharmaceutical Factory of Livzon Group. The reagents acetonitrile and formic acid used in the experiment were chromatographically pure, and the water was ultrapure water.
[0045] 2 Methods and Results
[0046] 2.1 Preparation of the test solution: Accurately measure 1mL of Shenqi Fuzheng Injection, purify it through a ...
Embodiment 2
[0097] Example 2 Screening of Shenqi Fuzheng Injection Dilution Multiples
[0098] Preparation of the test solution:
[0099] Test solution 1: dilute 10 times
[0100] Precisely measure 1mL of Shenqi Fuzheng Injection, purify it through a C18 small column, elute with deionized water, set the volume to a 10mL measuring bottle, and set the volume to obtain the product.
[0101] Test solution 2: dilute 20 times
[0102] Precisely measure 1mL of Shenqi Fuzheng Injection, purify it through a C18 column, elute with deionized water, set the volume to a 10mL measuring bottle, then precisely measure 2.5mL into a 5mL measuring bottle, and set the volume to obtain the product.
[0103] Test solution 3: dilute 50 times
[0104] Precisely measure 1mL of Shenqi Fuzheng Injection, purify it through a C18 small column, elute with deionized water, set the volume to a 10mL measuring bottle, then precisely measure 10mL into a 50mL measuring bottle, and set the volume to obtain the product.
...
Embodiment 3
[0115] Embodiment 3 chromatographic column is selected
[0116] Compare AS11-HC and Biobasic two kinds of ion chromatographic columns, experimental condition is described with reference to embodiment 1, experimental result is as chromatographic Figure 9 and 10 .
[0117] The baseline of the AS11-HC graph is stable, and the resolution is better than that of the Biobasic graph. Therefore choose AS11-HC ion chromatography column.
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