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A kind of catalyst for high activity fluid bed

An activator and catalyst technology, applied in the field of high-activity fluid bed catalysts, can solve the problems of poor catalyst efficiency and reduced catalytic capacity, and achieve the effect of ensuring effective use, high activity and improving use efficiency

Active Publication Date: 2019-09-03
中石化南京催化剂有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the actual production process, catalysts often have poor efficiency, especially multi-level catalysis, which often has problems such as good results in the early stage and sharp decline in catalytic ability in the later stage.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A catalyst for a high-activity fluid bed, which includes a three-layer activator and a carrier; the carrier is a zeolite molecular sieve, the first layer of catalyst is an active metal oxide catalyst, and the second layer of catalyst is platinum-doped oxidation Aluminum nano catalyst, the third layer of catalyst is molybdenum oxide catalyst.

[0025] The catalyst is divided into three parts, the first part is the active metal oxide catalyst, the second part is the lining active metal oxide catalyst, the outer surface is covered with a platinum-doped alumina nano-catalyst, and the third part is the lining Active metal oxide catalyst, the middle layer is coated with platinum-doped alumina nano-catalyst, and the outer layer is molybdenum oxide catalyst.

[0026] The ratio of the active metal oxide catalyst, the platinum-doped alumina nano-catalyst and the molybdenum oxide catalyst is 4:2:1.

[0027] The metal oxide catalyst uses iron oxide and nickel oxide, the loading of...

Embodiment 2

[0031] A kind of preparation method for high activity fluid bed catalyst is as follows:

[0032] 1) Soak the zeolite molecular sieve in 1mol / L alkali solution for 20min, then wash it with distilled water for 5 times, and let it dry naturally;

[0033] 2) Soak the zeolite molecular sieve in step 1) in the dilute solution of ferric nitrate and nickel nitrate, coat by dipping and pulling, then burn at 400°C for 2-3 hours, and cool naturally;

[0034] 3) Soak the zeolite molecular sieve coated with the metal oxide catalyst in step 2) in the platinum-doped alumina nanosuspension, coat the film by dipping and pulling, burn at 200°C for 2 hours, and cool naturally;

[0035] 4) Soak the zeolite molecular sieve in step 3) in molybdenum nitrate solution, pull the coating, burn at 300°C for 1 hour, and cool naturally;

[0036] 5) Put the zeolite molecular sieve prepared in step 4) into a muffle furnace for gradient high-temperature burning, burning at 200°C for 2 hours, burning at 400°C...

Embodiment 3

[0041] A kind of preparation method for high activity fluid bed catalyst is as follows:

[0042] 1) Soak the zeolite molecular sieve in 1mol / L alkali solution for 20min, then wash it with distilled water for 5 times, and let it dry naturally;

[0043] 2) Soak the zeolite molecular sieve in step 1) in the dilute solution of ferric nitrate and nickel nitrate, coat the film by dipping and pulling, then burn at 500°C for 2-3 hours, and cool naturally;

[0044] 3) Soak the zeolite molecular sieve coated with the metal oxide catalyst in step 2) in the platinum-doped alumina nanosuspension, coat the film by dipping and pulling, burn at 300°C for 2 hours, and cool naturally;

[0045] 4) Soak the zeolite molecular sieve in step 3) in molybdenum nitrate solution, pull the coating, burn at 300°C for 1 hour, and cool naturally;

[0046] 5) Put the zeolite molecular sieve prepared in step 4) into a muffle furnace for gradient high-temperature burning, burning at 200°C for 2 hours, burning...

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Abstract

The invention discloses a catalyst for a high-activity fluidized bed. The catalyst comprises three layers of active agents and a carrier. The carrier is a zeolite molecular sieve, the first layer of catalyst is a reactive metal oxide catalyst, the second layer of catalyst is a platinum doped aluminum oxide nano catalyst, and the third layer of catalyst is a molybdenum oxide catalyst. The catalyst has proper hole structure distribution and active metal dispersity, and has the advantages of being simple in preparation process, high in activity, incapable of causing saturation of unsaturated olefin and the like.

Description

technical field [0001] The invention belongs to the technical field of gasoline processing, and in particular relates to a high-activity fluid bed catalyst. Background technique [0002] Catalysis is the reaction in which the activation energy of the reactants is changed through the catalyst, the chemical reaction rate of the reactants is changed, and the amount and quality of the catalyst do not change before and after the reaction. In order for a chemical reactant to undergo a chemical reaction, it must change its chemical bond. Changing or breaking a chemical bond requires a certain amount of energy support. The minimum energy threshold required to change a chemical bond is called the activation energy. The activation energy of the chemical reaction is easier to carry out, and the reaction rate is greatly increased. [0003] As early as BC, China had been able to use distiller's yeast (biological enzyme catalyst) to make wine. In the middle of the 18th century, the use ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J29/04B01J37/025B01J35/10
CPCB01J29/04B01J37/024B01J35/394B01J35/60
Inventor 夏百庆
Owner 中石化南京催化剂有限公司
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