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Acidic wastewater treatment equipment and treatment method

A technology for wastewater treatment and treatment equipment, applied in metallurgical wastewater treatment, multi-stage water treatment, water/sewage treatment, etc., can solve problems such as poor environmental protection, achieve the effect of reducing production and increasing additional economic value

Active Publication Date: 2018-09-14
CHINA ENFI ENGINEERING CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The main purpose of the present invention is to provide an acid-containing wastewater treatment equipment and treatment method to solve the problem of poor environmental protection of the existing acid-containing wastewater treatment methods

Method used

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  • Acidic wastewater treatment equipment and treatment method
  • Acidic wastewater treatment equipment and treatment method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] use as figure 2 The acid-containing wastewater treatment equipment shown will be 150m 3 After the acid-containing wastewater containing 5wt% sulfuric acid is contacted with flue gas at 50°C for concentration, 30m 3 Concentrate; after adding polyferric chloride (flocculant) to the above concentrate, centrifuge to obtain 29.5m 3 The filtrate and 0.05t of solid residue, the concentration of sulfuric acid in the filtrate is 25wt%; after the above filtrate is contacted with air at 400 ° C, the defluorination and dechlorination process is carried out at 90 ° C in a vacuum environment to obtain acid gas containing hydrogen fluoride and hydrogen chloride and 12.9t of sulfuric acid with a mass fraction of 60wt%, using sodium hydroxide solution to absorb the above-mentioned acid gas.

Embodiment 2

[0056] use as figure 2 The acid-containing wastewater treatment equipment shown will be 150m 3 After the acid-containing wastewater containing 5wt% sulfuric acid is contacted with flue gas at 400°C for concentration, 30m 3 Concentrate; after adding polyferric chloride (flocculant) to the above concentrate, centrifuge to obtain 29.5m 3 The filtrate and 0.05t of solid residue, the concentration of sulfuric acid in the filtrate is 25wt%; after the above-mentioned filtrate is contacted with air at 100°C, the defluorination and dechlorination process is carried out at 60°C to obtain acid gas containing hydrogen fluoride and hydrogen chloride and 15.5t of mass Sulfuric acid with a fraction of 50 wt%, using sodium hydroxide solution to absorb the above-mentioned acid gas.

Embodiment 3

[0058] use as figure 2 The acid-containing wastewater treatment equipment shown will be 150m 3 Containing 5wt% sulfuric acid and contacting flue gas at 400°C for concentration, 30m 3 Concentrate; after adding polyferric chloride (flocculant) to the above concentrate, centrifuge to obtain 29.5m 3 The filtrate and 0.05t of solid residue, the concentration of sulfuric acid in the filtrate is 25wt%; the above-mentioned filtrate is contacted with air at 60°C and defluorinated and dechlorinated at 50°C to obtain acid gas containing hydrogen fluoride and hydrogen chloride and a mass fraction of 19.3t For 40wt% sulfuric acid, use sodium hydroxide solution to absorb the above acid gas.

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Abstract

The invention provides equipment and method for treating acid-containing waste water .The equipment for treating the acid-containing waste water comprises a first concentration unit, a solid-liquid separation unit, a second concentration unit and a heat medium supplying unit, wherein the solid-liquid separation unit is provided with a concentrated solution inlet and a separation solution outlet, and the concentrated solution inlet is connected with the first concentration unit through a concentrated solution conveying pipe; the second concentration unit is provided with a heat medium inlet and connected with the separation solution outlet of the solid-liquid separation unit through a separation solution conveying pipe; the heat medium supplying unit is connected with the second concentration unit through the heat medium inlet, so that a heat medium is introduced into the second concentration unit for blowing off a separation solution obtained through the solid-liquid separation unit, wherein the acid-containing waste water contains sulfuric acid, fluorine ions and chloride ions .When the acid-containing waste water is treated through the acid-containing waste water treatment equipment, sulfuric acid in the acid-containing waste water can be recycled, and thus the added economic value of the acid-containing waste water is raised.

Description

technical field [0001] The invention relates to the field of metal smelting, in particular to an acid-containing wastewater treatment equipment and treatment method. Background technique [0002] In the smelting industry, the existing treatment methods for acid-containing wastewater mostly use neutralization precipitation or electrochemical treatment. However, in the face of today's environmental protection policies, the above-mentioned treatment methods need to invest in higher treatment costs, and at the same time, the amount of harmful solid residues produced by them cannot meet the existing environmental protection requirements. Contents of the invention [0003] The main purpose of the present invention is to provide an acid-containing wastewater treatment equipment and treatment method to solve the problem of poor environmental protection of the existing acid-containing wastewater treatment methods. [0004] In order to achieve the above object, one aspect of the pr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F9/10B01D53/78B01D53/68C01B17/90C02F103/16
CPCB01D53/68B01D53/78B01D2251/304B01D2257/2045B01D2257/2047C01B17/901C02F1/001C02F1/12C02F1/16C02F1/20C02F1/38C02F1/52C02F1/5236C02F1/5245C02F1/54C02F1/56C02F9/00C02F2103/16C02F2301/08
Inventor 魏甲明高飞岳焕玲马小乐肖万平周翠芳
Owner CHINA ENFI ENGINEERING CORPORATION