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Novel anti-corrosion coating and preparation method thereof

An anti-corrosion coating, a new technology, applied in the direction of anti-corrosion coatings, coatings, epoxy resin coatings, etc., can solve the problems of polluted fluids, low efficiency, and reduce the mechanical properties of coatings, so as to increase wear resistance and enhance anti-corrosion performance Effect

Active Publication Date: 2016-08-10
NORTHEAST GASOLINEEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The traditional application of corrosion inhibitor is to disperse the corrosion inhibitor into the fluid to prevent corrosion during the flow of the fluid, but this utilization method is inefficient, and the introduction of the corrosion inhibitor into the solution will pollute the fluid
[0004] In addition, because the resin solution often cannot coexist with water, it is difficult to disperse the water-soluble corrosion inhibitor into the resin. Simply mixing the corrosion inhibitor with the resin will affect the mechanical properties of the resin to a certain extent, just like adding some foam to the cement wall. Will greatly reduce the mechanical properties of the coating

Method used

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  • Novel anti-corrosion coating and preparation method thereof
  • Novel anti-corrosion coating and preparation method thereof
  • Novel anti-corrosion coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] (1) Metal surface pretreatment:

[0048] Use sandblasting to quickly surface-treat the metal surface and put it into an ethanol solution for ultrasonic cleaning to remove impurities such as grease and dust on the surface. The mass concentration of the ethanol solution is 75%, take it out and dry it naturally, and save it for later use;

[0049] (2) Preparation of anti-corrosion coating emulsion:

[0050] ①Put the fly ash that has been ground and passed through a 300-mesh sieve into a sodium hydroxide solution with pH=8 and stir for 8 hours, then filter and dry to obtain alkali-treated fly ash;

[0051] ② After adding 5 parts of phenylphosphonic acid, 5 parts of kh550 and 5 parts of water to 40 parts of alkali-treated fly ash, add them to the reflux device already equipped with 50 parts of ethanol, react at 60°C for 6 hours, filter and dry after reaction Dry;

[0052] ③ Pour 20 parts of saturated water-soluble imidazoline corrosion inhibitor solution into the fly ash a...

Embodiment 2

[0069] (1) Metal surface pretreatment:

[0070] Use 400-mesh sandpaper to quickly polish the metal surface, then put it into an ethanol solution for ultrasonic cleaning to remove impurities such as grease and dust on the surface.

[0071] (2) Preparation of emulsion used for coating:

[0072] ①Put the fly ash that has been ground and passed through a 350-mesh sieve into a sodium hydroxide solution with pH=9 and stir for 9 hours, then filter and dry to obtain alkali-treated fly ash;

[0073] ② Add 0.5 parts of phenylphosphonic acid and 1 part of stearic acid to 30 parts of fly ash after alkali treatment, add them into the reflux device already equipped with 40 parts of ethanol, react at 70°C for 7 hours, filter and dry after reaction ;

[0074] ③ Pour 15 parts of saturated water-soluble benzotriazole solution into the fly ash after the grafting treatment in step ②, stir evenly and then dry;

[0075] ④ After adding 5 parts of nano-carbon black to the mixture obtained in step ...

Embodiment 3

[0085] (1) Metal surface pretreatment:

[0086] Use 10MPa high-pressure water jet to treat the metal surface to remove impurities such as grease and dust on the surface. The pipeline is naturally dried and reserved for future use.

[0087] (2) Preparation of emulsion used for coating:

[0088] ①Put the fly ash that has been ground and passed through a 350-mesh sieve into a sodium hydroxide solution with pH=14 and stir for 9 hours, then filter and dry to obtain alkali-treated fly ash;

[0089] ② After adding 0.5 parts of phenylphosphonic acid and 2 parts of fluorosilane to 20 parts of alkali-treated fly ash, add them into the reflux device already equipped with 40 parts of ethanol, react at 80°C for 6 hours, filter and dry after reaction;

[0090] ③ Pour 10 parts of saturated water-soluble benzotriazole solution into the fly ash after the grafting treatment in step ②, stir evenly and then dry;

[0091] ④ Pour 20 parts of ethyl acetate solvent into the dried product in step ③,...

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Abstract

The invention discloses a novel anti-corrosion coating and a preparation method thereof and solves the problem of reduction of mechanical performances of the coating since a corrosion inhibitor on a fly ash anti-corrosion coating in the prior art is difficult to disperse. In the invention, through a reflux method, phenyl phosphonic acid and a surfactant are grafted on surface of fly ash, wherein the phenyl phosphonic acid and the surfactant are hydrolyzed during a heating process and are connected to a part of hydroxyl groups on the surface of the fly ash. The grafted fly ash finally turns into sea urchin-like granules. The phenyl phosphonic acid increases dispersion of fly ash particles in resin and combination area of the fly ash particles with resin, thereby greatly improving anti-wear performance of coating. The phenyl phosphonic acid and the surfactant can enable the corrosion inhibitor to be dispersed in nano-micro pores in the fly ash more uniformly, thereby achieving the corrosion inhibition effect and improving the anti-corrosion performance of the coating.

Description

technical field [0001] The invention relates to a pipeline anticorrosion coating and a preparation method thereof. Background technique [0002] Fly ash powder is often used as an inorganic filler to improve the mechanical properties, temperature resistance, corrosion resistance and wear resistance of metal pipeline coatings. However, in the preparation process, the fly ash and resin are usually simply mixed and ground. Finally, the performance of fly ash in the coating has not been effectively improved. [0003] The traditional application of corrosion inhibitor is to disperse the corrosion inhibitor into the fluid to prevent corrosion during the flow of the fluid, but this method of utilization is inefficient, and the introduction of the corrosion inhibitor into the solution will pollute the fluid. [0004] In addition, because the resin solution often cannot coexist with water, it is difficult to disperse the water-soluble corrosion inhibitor into the resin. Simply mixin...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D163/02C09D175/04C09D175/02C09D5/08C09D7/12B05D3/00B05D3/12B05D3/10
CPCB05D3/002B05D3/102B05D3/12C08K5/3445C08K5/3472C08K9/02C08K9/04C08K11/00C08K2201/011C09D5/08C09D7/61C09D7/62C09D163/00C08L75/04C08K13/08C08K3/28C08K3/04C08L75/02
Inventor 汪怀远王池嘉朱艳吉刘战剑胡玥
Owner NORTHEAST GASOLINEEUM UNIV
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