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Multilayer ceramic capacitor and method for manufacturing the same

A technology of ceramic capacitors and ceramics, which is applied in the direction of laminated capacitors, capacitors, fixed capacitors, etc., can solve problems such as cracks, lower reliability of internal electrodes and external electrodes, and achieve good solderability, high-efficiency manufacturing, and connection reliability. high effect

Active Publication Date: 2016-09-28
MURATA MFG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] However, there is a problem in that, in the process of firing the conductive paste, the internal electrodes expand due to the diffusion of the metal material constituting the conductive paste to the internal electrode side, and when viewed from the end face side, for example, the Cracks are generated from both ends of the uppermost and lowermost internal electrodes toward the four corners of the ceramic body
In addition, there is also a problem that, when the temperature at which the conductive paste is fired is lowered in order to suppress diffusion, the bonding reliability between the internal electrodes and the external electrodes is lowered.

Method used

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  • Multilayer ceramic capacitor and method for manufacturing the same
  • Multilayer ceramic capacitor and method for manufacturing the same
  • Multilayer ceramic capacitor and method for manufacturing the same

Examples

Experimental program
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experiment example 1

[0087] In order to confirm the importance of the multilayer ceramic capacitor of this embodiment, samples of sample numbers 1 to 10 in Table 1 were prepared using a conductive paste containing Cu powder as a conductive component and Sn added ( multilayer ceramic capacitors).

[0088] In addition, the detailed specifications of the conductive paste are as follows.

[0089] The amount of solid content: 25vol%

[0090] Ratio of Cu powder in solid content: 70vol%

[0091] Ratio of glass in solid content: 25vol%

[0092] Ratio of Sn in solid content: 5vol%

[0093] Particle size of Cu powder: 3μm

[0094] Glass particle size: 2μm

[0095] Composition of glass: BaO-SrO-B 2 o 3 -SiO 2 Glass-like frit (glass frit is converted into oxide, BaO: 10% by weight to 50% by weight, B 2 o 3 : 3% to 30% by weight, SiO 2 : 3% to 30% by weight glass)

[0096] In addition, when preparing the samples of sample numbers 1 to 10 in Table 1, the conductive paste was applied to the first end...

experiment example 2

[0129] In addition, in addition to setting the thickness of the external electrode main body to 40 μm, setting the thickness of the interdiffusion layer on the external electrode side to 10% of the thickness of the external electrode main body, and setting the thickness of the interdiffusion layer on the internal electrode side to 0.2 μm to 7 μm Samples of sample numbers 11 to 15 in Table 2 were produced in the same manner as in the case of the samples of Experimental Example 1 (samples in Table 1) described above, except that the samples were changed within the range of .

[0130] Furthermore, a test for checking the number of crack occurrences and a 0Ω discharge test were implemented for each of the produced samples.

[0131] In addition, the number of occurrences of cracks was checked by grinding the samples (multilayer ceramic capacitors) from the side (the end face of the ceramic body on which the external electrodes were formed) including the surface in the thickness dire...

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Abstract

A multilayer ceramic capacitor and method of manufacturing same are provided; the multilayer ceramic capacitor contains Ni in internal electrodes, and includes a sintered metal layer containing Cu in external electrodes. At a joined portion between each internal electrode and each external electrode, mutual diffusion layers of Cu and Ni extend across the internal and external electrodes. On each internal electrode, a mutual diffusion layer is present with a thickness t1, which is defined by a dimension from a first end surface or a second end surface to an interior end in a longitudinal direction, not smaller than about 0.5 um and not greater than about 5 um. On each external electrode, a mutual diffusion layer is present with a thickness t2, which is defined by a dimension from the first end surface or the second end surface to an exterior end in the longitudinal direction, not smaller than about 2.5% and not greater than about 33.3% of a thickness t0 of a sintered metal layer.

Description

technical field [0001] The present invention relates to a ceramic capacitor and a method of manufacturing the same. More specifically, it relates to a multilayer ceramic capacitor having a structure in which an external electrode is arranged on a ceramic body having internal electrodes so as to be electrically connected to the internal electrode, and a method of manufacturing the same. . Background technique [0002] As one of representative ceramic electronic components, there is a multilayer ceramic capacitor disclosed in, for example, JP-A-2006-213946. [0003] Such as Figure 4 As shown, this multilayer ceramic capacitor has a structure including a ceramic laminate (ceramic body) 110 in which a plurality of internal electrodes 102 (102a, 102b) are laminated via a ceramic layer 101 as a dielectric layer, and a A pair of external electrodes 104 (104a, 104b) provided on a pair of end faces 103 (103a, 103b) of the ceramic laminate 110, and the pair of external electrodes 10...

Claims

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Application Information

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IPC IPC(8): H01G4/008H01G4/012H01G4/12H01G4/232H01G4/30
CPCH01G4/008H01G4/012H01G4/12H01G4/2325H01G4/30
Inventor 西坂康弘齐藤义人
Owner MURATA MFG CO LTD
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