Cement clinker magnesium granule cored wire, application and production technology of steel for large heat input welding

A technology for high-energy welding and cement clinker, which is applied in the manufacture of converters, etc., can solve the problems of difficult Mg content, adjustment of Mg addition timing, inability to fully realize Mg independent control, low temperature toughness, low alloy and high strength, etc. and high utilization rate, dispersion of inclusions, and improvement of low temperature toughness

Inactive Publication Date: 2016-10-12
NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Application Information

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Problems solved by technology

[0005] Magnesium metal is a relatively active element with a boiling point of 1107°C. Due to the high temperature of molten steel in the steelmaking process, its vapor pressure is as high as 2.0×10 6 Pa, so the addition of magnesium in molten steel is prone to evaporation loss and oxidation loss. Improper addition will cause strong oxidation reaction and strong splash in molten steel, which is easy to cause safety problems, and it is also difficult to accurately control Mg in steel
European patent EP1052303A2 "Low-alloy high-strength steel with excellent low-temperature toughness when welded with large input energy" introduced the method of using Ti-Mg composite to obtain fine oxide particles in the test steel, but this test method is only suitable for laboratory vacuum smelting furnace smelting
Chinese patent CN 103938065 A "A Method for Compositely Adding Magnesium and Titanium to Steel for Large Energy Input Welding" adopts the method of feeding Mg-Y-Ni alloy wire in the tundish to increase the Mg concentration in the molten steel, and it is inevitable to add Mg at the same time The introduction of other elements, it is difficult to achieve separate adjustment of Mg content
Chinese patent CN 101724774 A "method of adding magnesium in the process of welding thick steel plate with large input energy", and Chinese patent CN 102191356 A "inclusion control method of thick steel plate for large input The Ni-Mg alloy method obtains a stable Mg yield in steel, but this method is suitable for smelting in a small-scale vacuum smelting furnace, and cannot realize the large-scale industrial production of converter-continuous casting, and it will inevitably bring other element, it is difficult to adjust the Mg content and the timing of adding Mg
Chinese patent CN 203048979 U "a solid metal magnesium alloy cored wire for steelmaking desulfurization", although its method is used for steelmaking desulfurization, not for microalloying of steel for high heat input welding, its solid metal magnesium The core of the alloy cored wire is a magnesium alloy, and other metal elements will also be brought in when the molten steel is fed, and the independent control of Mg cannot be fully realized
And it contains Mg93.6%, when this cored wire is fed to molten steel, it cannot achieve flame retardancy
When the cored wire is fed into the molten steel, the cored wire is melted by the molten steel, and the red hot cored end will continue to oxidize strongly, burning the entire cored wire all the time, and cannot be used for actual production

Method used

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  • Cement clinker magnesium granule cored wire, application and production technology of steel for large heat input welding
  • Cement clinker magnesium granule cored wire, application and production technology of steel for large heat input welding
  • Cement clinker magnesium granule cored wire, application and production technology of steel for large heat input welding

Examples

Experimental program
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Effect test

Embodiment 1

[0032] A cement clinker-magnesium particle cored wire with a diameter of 13mm, the cored wire includes an outer layer and a core; the outer layer is low carbon steel 08Al with a thickness of 1.0mm; the core is slow release passivated magnesium particles , The core includes a slow-release agent and passivated magnesium particles, the slow-release agent is cement clinker, the slow-release agent accounts for 75% of the core-coated content, and the passivated magnesium particles account for 25% of the core-coated content. Passivated magnesium grains contain 92% magnesium, and the rest are passivating agents and unavoidable impurities.

[0033] The chemical composition and mass percentage range of slow-release agent cement clinker are as follows: CaO: 66%, SiO 2 : 23%, Al 2 o 3 : 6%, Fe 2 o 3 : 3%, H 2 O: 0.5%. The balance is unavoidable impurities.

[0034] The particle size of passivated magnesium particles is 0.5-3 mm, and the proportion of particle size ≤ 80 mesh is 4%. ...

Embodiment 2

[0044] A cement clinker-magnesium particle cored wire with a diameter of 12mm, the cored wire includes an outer layer and a core; the outer layer is low carbon steel 08Al with a thickness of 1.0mm; the core is slow release passivated magnesium particles , The core includes a slow-release agent and passivated magnesium particles, the slow-release agent is cement clinker, the slow-release agent accounts for 75% of the core-coated content, and the passivated magnesium particles account for 25% of the core-coated content. Passivated magnesium grains contain 93% magnesium, and the rest are passivating agents and unavoidable impurities.

[0045] The chemical composition and mass percentage range of slow-release agent cement clinker are as follows: CaO: 65%, SiO 2 : 22%, Al 2 o 3 : 5%, Fe 2 o 3 : 6%, H 2 O: 0.5%. The balance is unavoidable impurities.

[0046] The particle size of passivated magnesium particles is 0.5-3 mm, and the proportion of particle size ≤ 80 mesh is 6%. ...

Embodiment 3

[0056] A cement clinker-magnesium particle cored wire with a diameter of 11mm, the cored wire includes an outer layer and a core; the outer layer is low carbon steel 08Al with a thickness of 1.0mm; the core is slow release passivated magnesium particles , The core includes a slow-release agent and passivated magnesium particles, the slow-release agent is cement clinker, the slow-release agent accounts for 75% of the core-coated content, and the passivated magnesium particles account for 25% of the core-coated content.

[0057] The chemical composition and mass percentage range of slow-release agent cement clinker are as follows: CaO: 64%, SiO 2 : 21%, Al 2 o 3 : 6%, Fe 2 o 3 : 5%, H 2 O: 0.5%. The balance is unavoidable impurities.

[0058] The particle size of passivated magnesium particles is 0.5-3 mm, and the proportion of particle size ≤ 80 mesh is 4%.

[0059] Bulk density of core-coated slow-release passivated magnesium particles is 1.3g / cm 3 .

[0060] The prod...

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Abstract

The invention discloses a cement clinker-magnesium particle cored wire and its application and production process of steel for large heat input welding. The cored wire includes an outer layer and a cored core; the outer layer is low-carbon steel with a thickness of 0.5-1.0 mm; The core is slow-release passivated magnesium particles, the core includes slow-release agent and passivated magnesium particles, the slow-release agent is cement clinker, the slow-release agent accounts for 5-90% of the content of the core, and the passivated magnesium particles account for the content of the core 10-95% of that. Application of the cored wire of the present invention in preparing steel for high heat input welding. The invention feeds the slow-release passivated magnesium grain cored wire with cement clinker as the slow-release agent to the molten steel, the absorption rate of Mg is stable, the effect and utilization rate of Mg are high, the inclusions are dispersed and abundant, and the inclusions containing Mg up to 80% or more. Adopting the present invention has the advantages of simple control, low production cost, and industrialized large-scale production of steel for welding with large heat input.

Description

technical field [0001] The invention belongs to the technical field of low-alloy steel manufacturing, and in particular relates to cement clinker-magnesium grain cored wire and its application and a production process of steel for high-energy-input welding. Background technique [0002] Steel plates are widely used in infrastructure and large structures such as buildings, bridges, pressure vessels, storage tanks, pipelines and ships. The development trend of large-scale and high-rise building components requires that the thickness of the steel plate be increased, and at the same time have higher comprehensive properties, including higher mechanical properties, efficient processing properties, and excellent corrosion resistance and fatigue damage resistance. [0003] However, as the strength of the steel plate increases, its impact toughness and weldability decrease significantly, and the susceptibility to weld cracks increases. In order to improve the welding efficiency of ...

Claims

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Application Information

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IPC IPC(8): C21C7/00C21C5/28
CPCC21C7/0056C21C5/28
Inventor 王硕明张彩军韩毅华朱立光刘增勋孙立根王雁
Owner NORTH CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY
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