Photosensitive resin composition and color filter using same
A technology of photosensitive resin and composition, which can be used in optical filters, photosensitive materials for opto-mechanical equipment, optics, etc., and can solve problems such as difficult chemical resistance and weak heat resistance.
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manufacture example 1
[0106] Production Example 1: Production of Copolymer Represented by Chemical Formula 2
[0107]Put the rhodamine series dye monomer represented by the following chemical formula A and 2-ethylhexyl acrylate monomer into the flask equipped with cooling tube and stirrer according to their respective weight ratios, according to the rhodamine series dye list 8% by weight of the sum of monomer and 2-ethylhexyl acrylate monomer was put into 2,2'-azobis(2,4-dimethylvaleronitrile) initiator. Afterwards, based on 100 parts by weight of the total amount of the initiator and the monomer, 200 parts by weight of propylene glycol methyl ether acetate (PGMEA solvent) was added, and stirring was started slowly under nitrogen atmosphere. The reaction solution was heated to 80° C. and stirred for 8 hours to obtain a copolymer resin represented by the following Chemical Formula 2 containing an aliphatic hydrocarbon. The solid content of the copolymer resin solution obtained by the method describ...
experiment example 1、 comparative example 1、 and comparative example 2
[0115] With the composition described in the following Table 1, after dissolving the photoinitiator in the solvent, it stirred at normal temperature for 2 hours. According to the composition in Table 1, an acrylic binder resin and a photopolymerizable monomer were added, and stirred at room temperature for 2 hours. According to the composition in Table 1, after adding the coloring agent, stir at room temperature for 1 hour, then add surfactant and coupling agent, and stir at room temperature for 1 hour. The prepared solution was filtered three times to remove impurities, and the photosensitive resin compositions of Experimental Example 1, Comparative Example 1, and Comparative Example 2 were produced. When manufacturing the said photosensitive resin composition, the components used are as follows.
[0116] (A) Acrylic binder resin
[0117] (A-1) Acrylic adhesive resin (SM-CRG-300S, SMS company)
[0118] (B) Colorant
[0119] (B-1) Copolymer of Production Example 1
[0120...
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