A kind of graphene anticorrosion coating and preparation method thereof

A technology of anti-corrosion coatings and graphene, which is applied in the direction of anti-corrosion coatings, epoxy resin coatings, coatings, etc., can solve the problems of poor anti-corrosion performance of coatings, no data on the mechanical properties and anti-corrosion performance of primers, etc., and achieve excellent adhesion , It is conducive to large-scale industrial production and solves the effect of easy reunion

Active Publication Date: 2019-06-28
HUNAN AEROSPACE SANFENG SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Due to the improper selection of film-forming substances, the anti-corrosion performance of the coating prepared by this patent is poor, the adhesion is 0-1 grade, the flexibility is 1-2 grade, and the salt spray resistance time is only 600h
[0007] Patent CN 201610175323.3 mentions a preparation method of zinc-containing graphene anticorrosion primer based on graphene dispersion, but the mechanical properties and anticorrosion performance data of the primer are not given in the patent

Method used

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  • A kind of graphene anticorrosion coating and preparation method thereof
  • A kind of graphene anticorrosion coating and preparation method thereof
  • A kind of graphene anticorrosion coating and preparation method thereof

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Embodiment Construction

[0044] The graphene anticorrosive coating of the present invention will be further described below in conjunction with specific embodiments.

[0045] The coating material formulations of the comparative examples of the present invention and Examples 1-7 are listed in Table 1 and Table 2, respectively.

[0046] Table 1 Graphene anticorrosive coating formula in the comparative example

[0047]

[0048] Note: Unless otherwise specified, all percentage units in the present invention are mass percentages. The A component and B component are calculated at 100% content respectively.

[0049] The preparation method of the graphene anticorrosive coating in the comparative example, the specific steps are as follows:

[0050] 1) Preparation of component A

[0051] a. Add the epoxy resin of the A component formula into the mixing container, and stir at the speed of 1000-1500r / min;

[0052] b. Then add the solvent, zinc powder, graphene and filler of the A component formula in sequence, and continue ...

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Abstract

The invention provides a graphene anticorrosive coating and a preparation method thereof. The graphene anticorrosive coating is prepared from a component A and a component B, wherein in percentage by weight, the component A comprises 20%-30% of epoxy resin, 1%-3% of graphene, 0.5%-2% of a dispersing agent, 15%-25% of talcum powder, 10%-20% of zinc powder and 1%-5% of aluminum paste, and the component B comprises 30%-50% of cashew nut shell oil phenolic amide and 10%-30% of polyamide. The graphene anticorrosive coating provided by the invention is safe and environment-friendly, is moderate in cost, simple and convenient in process, stable in storage, excellent in adhesive force on base materials such as steel, iron and the like, excellent in mechanical performance such as flexibility, wear resistance performance and the like, and prominent in protective effects in chemical media such as an acid, an alkali, a salt and the like, shows excellent protective performance such as high and low temperature resistance, high salinity resistance and the like in a condition of a simulation marine environment experiment, and can be applied as primer for an anticorrosive coating in ocean engineering with various steel and iron materials.

Description

Technical field [0001] The invention relates to a graphene anticorrosive coating and a preparation method thereof, and belongs to the technical field of anticorrosive coatings. Background technique [0002] Graphene is a carbon atom with sp 2 The hexagonal flat film with a honeycomb lattice composed of hybrid orbitals is a two-dimensional material with the thickness of only one carbon atom. It is also the thinnest and hardest nanomaterial known in the world so far. It has an ultra-high specific surface area and excellent Its electrical conductivity, super high strength, toughness and shielding properties make it expected to play an excellent role in the field of conductive coatings and metal anticorrosive coatings. [0003] Graphene is a loose nanomaterial with large surface energy, and it is easy to agglomerate in the resin matrix, which limits the application of graphene in coatings. At present, researchers often optimize the dispersion process or chemically modify the surface o...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D163/00C09D5/10C09D7/61C09D7/65C08G59/62C08G59/46
CPCC08G59/46C08G59/62C08L2205/025C08L2205/035C09D5/103C09D5/106C09D163/00C08L63/00C08L77/00C08K13/02C08K3/04C08K2003/0893C08K3/34C08K2003/0812
Inventor 张刚肖鹏阳区刘琛李真真
Owner HUNAN AEROSPACE SANFENG SCI & TECH CO LTD
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