A kind of polymer type heavy oil demulsifier and preparation method thereof

A technology of demulsifier and polymer, which is applied in the field of polymer-type viscous oil demulsifier and its preparation, can solve the problems of high demulsification temperature of demulsifier, large amount of demulsifier, long dehydration time, etc., and achieve fast demulsification speed, Strong demulsification ability and low demulsification temperature

Active Publication Date: 2017-11-28
CHINA NAT OFFSHORE OIL CORP +2
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In recent years, research on heavy oil demulsifiers has mainly focused on non-ionic polyether demulsifiers and their composite products. For example, in patent CN 103642518 B, epoxy polyether A and epoxy polyether B are used in a molar ratio of 1:( 0.9 to 1.1) is dissolved in xylene to obtain a viscous oil demulsifier with less dosage and good demulsification and dehydration effect, but the demulsification temperature of the demulsifier is high, energy consumption is large, and dehydration time is long; Ether-type heavy oil demulsifiers are developed, such as patent CN 101255354 B, using acrylic acid series monomers as raw materials to synthesize a non-polyether demulsifier with good hydrophilic and lipophilic properties and good demulsification effect, but the demulsifier Large dosage, high cost

Method used

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  • A kind of polymer type heavy oil demulsifier and preparation method thereof
  • A kind of polymer type heavy oil demulsifier and preparation method thereof
  • A kind of polymer type heavy oil demulsifier and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0025] 1. Preparation of main ingredient of demulsifier:

[0026] (1) In a 250mL four-necked flask equipped with a thermometer, a water separator and a reflux condenser, add 20g of polyether polyol (molecular weight around 2000), 2g of maleic anhydride (the molar ratio of polyether polyol to maleic anhydride 1:2), 0.3g p-toluenesulfonic acid (p-toluenesulfonic acid accounts for 1.5% of the total mass of the reactants) and 150mL toluene, the temperature is raised to 140°C for reaction, and the reaction progress is judged by observing the water output in the water separator. After a total time of 6 hours, a maleic acid polyether ester having the structure of the following formula (III) was obtained.

[0027]

[0028] (2) In the 250mL four-necked flask that thermometer, stirrer and reflux condenser are equipped with, add 0.2g benzoyl peroxide (benzoyl peroxide accounts for 1% of reactant gross mass) and 150mL toluene, start after Use a constant pressure titration funnel to ad...

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Abstract

The invention relates to a polymer type thick oil demulsifying agent and a preparation method thereof. The polymer type thick oil demulsifying agent contains the following components in percentage by weight: 40-60% of demulsifying agent host, 1-5% of pH regulating agent, 1-5% of solid wetting agent, and 30-50% of solvent. The demulsifying agent disclosed by the invention has the advantages of being strong in demulsifying capability, high in demulsifying speed, low in use amount, and low in demulsifying temperature, and can be widely applied to the crude oil demulsifying process in the fields of crude oil extraction, petroleum refining and the like.

Description

Technical field: [0001] The invention relates to technical fields such as crude oil exploitation and processing, and more specifically relates to a polymer type heavy oil demulsifier and a preparation method thereof. Background technique: [0002] The global recoverable reserves of heavy oil are about 400 billion tons, which is 2.7 times the recoverable reserves of conventional crude oil (150 billion tons). After more than 20 years of development, the annual output of heavy oil and tar sands has increased from 20 million tons to nearly 100 million tons. More than 70 heavy oil fields have been discovered onshore in China, with a total geological reserve of about 1.2 billion cubic meters. The annual production has increased from 1 million tons in 1985 to 13 million tons, accounting for 9% of the total onshore crude oil production. The cumulative production has exceeded 100 million tons. Tons; heavy oil in offshore oilfields accounts for 70%, and the development of heavy oil p...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G33/04C08G81/00C08G65/28
CPCC08G65/2609C08G81/00C10G33/04
Inventor 丁秋炜于晓微王素芳徐慧林蓓张艳芳
Owner CHINA NAT OFFSHORE OIL CORP
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