Composite shape-setting phase change material and preparation method thereof

A shape-setting phase-change material and a technology for phase-change materials, which are applied in the field of composite shape-setting phase-change materials and their preparation, can solve problems such as poor thermal stability, and achieve the effects of reducing phase separation, a simple and convenient preparation method, and broad application prospects.

Active Publication Date: 2019-08-23
GUILIN UNIV OF ELECTRONIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Aiming at the defects of phase separation and poor thermal stability in the composite phase change material, the present invention uses sepiolite fiber as the adsorption support matrix of the phase change material, utilizes the porous structure of sepiolite to realize the encapsulation and setting of the phase change material, and utilizes its Moisture absorption and desorption properties lock the crystal water of the crystalline hydrated salt phase change material to prevent its evaporation and phase separation, improve the phase change energy storage effect and thermal stability of the phase change material, and reduce the cost of the fixed phase change material

Method used

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  • Composite shape-setting phase change material and preparation method thereof
  • Composite shape-setting phase change material and preparation method thereof

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Embodiment

[0032] Step 1: Acid treatment of sepiolite

[0033] Sepiolite and hydrochloric acid (0.1 mol / L) were mixed with a solid-to-liquid ratio of 1:20, ultrasonicated and stirred for 1 hour, then left to stand for 12 hours to remove the quartz impurities at the bottom, washed repeatedly until neutral, suction filtered, dried, grind.

[0034] Step 2: High temperature treatment of sepiolite

[0035] Put the sepiolite obtained in step 1 into the muffle furnace, 420 o C activated for 2 h.

[0036] Step 3: Organic treatment of sepiolite

[0037] The 5g sepiolite that step 2 obtains is configured into the suspension of 20 g / L, pours in the three-necked flask, 50 o C preheat for 15 min. Mix and shake 2 ml KH570 (1% mass fraction) with 100 ml ethanol solution (95% mass fraction) for 30 minutes to obtain the silane coupling agent hydrolyzate into a three-necked flask, then add sodium hexametaphosphate (7 mass fraction %) as a dispersant, 95 o C was refluxed and condensed for 2 h, and f...

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Abstract

The invention provides a composite shape-stabilized phase change material. The phase change material is a crystallized hydrated salt phase change material, and a support material is meerschaum. A preparation method of the phase change material comprises the following steps: performing acid treatment, high-temperature treatment and organic treatment on the meerschaum in sequence; performing an adsorption reaction on the treated meerschaum and a saturated aqueous solution of a crystallized hydrated salt under a vacuum condition to obtain a novel composite shape-stabilized phase change material. The composite shape-stabilized phase change material has the advantages that 1) packaging and shape stabilizing of the phase change material are realized through the porous structure of the meerschaum, the loss of phase change material crystal water is limited successfully through a functional group of the meerschaum, phase separation is reduced, and the crystallization performance and phase change energy storage feature of the crystallized hydrated salt phase change material are ensured; 2) raw materials of the support material and the phase change material are low in prices and readily-available; the composite preparation method is simple and convenient. By adopting the composite shape-stabilized phase change material and the preparation method, the phase separation phenomenon, overcooling phenomenon and leakage are reduced, and the stability of the phase change material in a long-term use process is improved; the phase change material has a wide application prospect in the phase change heat storage field.

Description

technical field [0001] The invention relates to a phase-change heat storage material, in particular to a composite shape-fixed phase-change material and a preparation method thereof. [0002] technical background [0003] Energy is the basis for the survival and development of human beings. With the continuous progress of society, the situation of energy shortage is becoming more and more serious. There are two basic ways to solve this problem: one is to rely on scientific and technological progress to develop new energy; the other is to improve the utilization rate of existing energy and reduce energy consumption. Phase change material is an energy-saving and environmentally friendly material that was discovered in the 1960s and developed and applied after the 1970s. It is also a clean energy storage material. Phase change materials are substances that absorb or release a large amount of heat during the phase change process for thermal energy storage and temperature regulat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/06
CPCC09K5/063
Inventor 张焕芝崔韦唯夏永鹏孙立贤徐芬
Owner GUILIN UNIV OF ELECTRONIC TECH
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