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An electrolytic process for repairing and restarting an aluminum electrolytic cell

An aluminum electrolytic cell and electrolytic cell technology, applied in the field of electrolytic cells, can solve problems such as high electrolyte viscosity, uneven distribution of anode current, and decrease in current efficiency, and achieve uniform distribution of anode current, prominent substantive features, and reduced voltage fluctuations Effect

Active Publication Date: 2019-11-01
HENAN WANJI ALUMINUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As a result, the electrolysis temperature drops to 890-900°C, the viscosity of the electrolyte is high, the fluidity is poor, the ability to dissolve alumina drops sharply, and a large amount of precipitation and crusting occur at the bottom of the electrolytic tank
The bottom pressure drop of the electrolytic cell increases, the operation stability deteriorates, the current efficiency decreases, the power consumption per ton of aluminum rises sharply, and the production cost remains high. After the electrolytic cell has been in operation for a period of time, the anode plate needs to be replaced. The anode is slow to conduct electricity, and the uneven distribution of anode current causes many sick cells, low current efficiency, power consumption per ton of aluminum is as high as 14900kwh / t-Al, and the production cost remains high. Therefore, we propose a method of repairing and restarting the aluminum electrolytic cell electrolytic process

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] An electrolytic process for repairing and restarting an aluminum electrolytic cell comprises the following steps:

[0022] S1. Reduced operating indicators: the operating current of the electrolytic cell is reduced from 298KA to 290KA, the temperature is lowered to 50°C, and the liquid level of the electrolytic cell is reduced;

[0023] S2. Overhaul: To strengthen the insulation of the electrolytic cell, first use an alumina crust material with a thickness of 0.1mm to thicken the anode insulation material to be flush with the anode steel beam, and then paste a layer of insulation layer on the lower end of the tank cover plate. The thickness of the insulation layer is 1mm;

[0024] S3. Restart: increase the aluminum level to submerge the sedimentation crust at the bottom of the tank to improve the cathode current distribution, reduce the cathode voltage drop, regulate the furnace, and increase the vertical current of the anode;

[0025] S4. Adjust technical parameters t...

Embodiment 2

[0032] An electrolytic process for repairing and restarting an aluminum electrolytic cell comprises the following steps:

[0033] S1. Reduced operating indicators: the operating current of the electrolytic cell is reduced from 298KA to 290KA, the temperature is lowered to 55°C, and the liquid level of the electrolytic cell is reduced;

[0034] S2. Overhaul: To strengthen the insulation of the electrolytic cell, first use an alumina crust material with a thickness of 0.3mm to thicken the anode insulation material to be flush with the anode steel beam, and then paste a layer of insulation layer on the lower end of the tank cover plate. The thickness of the insulation layer is 5mm;

[0035] S3. Restart: increase the aluminum level to submerge the sedimentation crust at the bottom of the tank to improve the cathode current distribution, reduce the cathode voltage drop, regulate the furnace, and increase the vertical current of the anode;

[0036] S4. Adjust technical parameters t...

Embodiment 3

[0043] An electrolytic process for repairing and restarting an aluminum electrolytic cell comprises the following steps:

[0044] S1. Reduced operating indicators: the operating current of the electrolytic cell is reduced from 298KA to 290KA, the temperature is lowered to 60°C, and the liquid level of the electrolytic cell is reduced;

[0045] S2. Overhaul: To strengthen the insulation of the electrolytic cell, first use an alumina crust material with a thickness of 0.5mm to thicken the anode insulation material to be flush with the anode steel beam, and then paste a layer of insulation layer on the lower end of the tank cover plate. The thickness of the insulation layer is 10mm;

[0046] S3. Restart: increase the aluminum level to submerge the sedimentation crust at the bottom of the tank to improve the cathode current distribution, reduce the cathode voltage drop, regulate the furnace, and increase the vertical current of the anode;

[0047] S4. Adjust the technical paramet...

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Abstract

The invention relates to the technical field of electrolytic tanks, in particular to an electrolyzing technology for repair and restarting of an aluminum electrolytic tank. The electrolyzing technology comprises the following steps of S1, reducing of running indexes; S2, overhauling; S3, restarting; S4, adjusting of technical parameters to establish new heat balance; S5, cleaning. The electrolyzing technology for repair and restarting of the aluminum electrolytic tank has the advantages that after the heat-insulation material of the furnace surface is completely manufactured, the molecule ratio is adjusted to about 2.75, the fluidity of electrolyte is good, the anode current is uniformly distributed, the voltage fluctuation is reduced, the stability of the tank is enhanced, the settled crust at the furnace bottle is gradually melted, the series current is gradually increased back to 296KA to reach new heat balance, the voltage drop at the furnace bottom is reduced from 453V to 370V after the technical scheme is adopted, the fluctuation of tank voltage is basically eliminated, the long-time stable running is reached, and the electrolyzing temperature is stabilized to 905 DEG C for along time; the outstanding material characteristics and obvious progress are realized.

Description

technical field [0001] The invention relates to the technical field of electrolytic cells, in particular to an electrolytic process for repairing and restarting an aluminum electrolytic cell. Background technique [0002] Bauxite in Henan, Shanxi and other places is rich in lithium salts and potassium salts, and these lithium salts and potassium salts cannot be effectively removed during the process of converting aluminum ore into alumina. These lithium salts and potassium salts will be brought into the electrolyte of electrolytic aluminum along with the alumina, and gradually enrich in the electrolyte, with the concentration of lithium salts as high as 9-10%. As a result, the electrolysis temperature drops to 890-900°C, the viscosity of the electrolyte is high, the fluidity is poor, the ability to dissolve alumina drops sharply, and a large amount of precipitation and crusting occur at the bottom of the electrolytic tank. The bottom pressure drop of the electrolytic cell i...

Claims

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Application Information

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IPC IPC(8): C25C3/06
Inventor 李跃民王瑞奇王宏伟李小宝马占国郭同民赵红星裴晓斐贾志成
Owner HENAN WANJI ALUMINUM