A kind of chloroprene rubber modified flame retardant polyurethane sealant and preparation method thereof
A technology of polyurethane sealant and neoprene, which is applied in the field of sealants, can solve the problems of decreased adhesive performance and flame retardant performance, and limited development of flammable properties, and achieves the effect of excellent flame retardant performance and simple preparation method
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Embodiment 1
[0049] A neoprene modified flame-retardant polyurethane sealant, made of the following components in parts by weight:
[0050]
[0051] Wherein, the polyurethane prepolymer is made of the following components in parts by weight:
[0052]
[0053] Modified chloroprene rubber is made of the following components in parts by weight:
[0054]
[0055]
[0056] The isocyanate is one or a combination of any two or more of toluene diisocyanate, 1,5-naphthalene diisocyanate, diphenylmethane diisocyanate, 1,6-hexamethylene diisocyanate or isophorone diisocyanate.
[0057] Polyether polyol is a mixture of polyether diol and polyether triol; the weight content of the polyether diol is 30% to 90%, and the molecular weight of the polyether diol is 500 to 12000, so The molecular weight of the polyether trihydric alcohol is 1000-10000.
[0058] Neoprene is CR2441 type, which is one of AD, AC, CG, HC or AF or any combination of two or more;
[0059] The initiator is one or any com...
Embodiment 2
[0082] A neoprene modified flame-retardant polyurethane sealant, made of the following components in parts by weight:
[0083]
[0084] Wherein, the polyurethane prepolymer is made of the following components in parts by weight:
[0085]
[0086] Modified chloroprene rubber is made of the following components in parts by weight:
[0087]
[0088] The isocyanate is toluene diisocyanate.
[0089] Polyether polyol is the mixture of polyether glycol and polyether trihydric alcohol; The weight content of polyether glycol is 60%, and the molecular weight of described polyether glycol is 6000, and the molecular weight of polyether trihydric alcohol is 5000.
[0090] The neoprene is CR2441 type, which is AD;
[0091] The initiator is BPO;
[0092] The diluent is toluene.
[0093] Flame retardant diluents are phosphate esters;
[0094] Phosphate esters are triethyl phosphate;
[0095] The flame retardant is ammonium polyphosphate;
[0096] The filler is volcanic ash; ...
Embodiment 3
[0106] A neoprene modified flame-retardant polyurethane sealant, made of the following components in parts by weight:
[0107]
[0108]
[0109] Wherein, the polyurethane prepolymer is made of the following components in parts by weight:
[0110]
[0111] Modified chloroprene rubber is made of the following components in parts by weight:
[0112]
[0113] The isocyanate is 1,5-naphthalene diisocyanate.
[0114] The polyether polyol is a mixture of polyether diol and polyether triol; the weight content of the polyether diol is 30%, the molecular weight of the polyether diol is 500, and the molecular weight of the polyether triol is 1000.
[0115] The neoprene is type CR2441, which is AC;
[0116] The initiator is AIBN;
[0117] The diluent is xylene.
[0118] Flame retardant diluents are phosphonates;
[0119] The phosphonate is diethyl ethyl phosphonate;
[0120] The flame retardant is inorganic phosphate;
[0121] Inorganic phosphate is diammonium hydrogen ...
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