Method for preparing photocatalytic composite modified molecular sieve

A compound modification and molecular sieve technology, applied in the field of photocatalytic materials, can solve the problems of limited use of molecular sieve alone, failure to meet the needs of use, and limited output of a single pot, so as to improve the overall catalytic performance, antibacterial and antiviral properties, and excellent photocatalytic properties. Catalytic degradation ability, easy-to-handle effect

Inactive Publication Date: 2018-04-13
MAANSHAN TUORUI METAL SURFACE TECH
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  • Abstract
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AI Technical Summary

Problems solved by technology

In the hydrothermal reaction process of crystal growth, a large amount of water is used as a solvent, occupying most of the volume in the reactor, so that the output of a single reactor is limited, and because the crystallization process needs to be completed at a high temperature, the existence of a large amount of solvent makes the energy per unit output High consumption
At the same time, the use of molecular sieves alone is limited and cannot meet people's needs. Therefore, further compounding and modification are required to improve the application field and efficiency of molecular sieves.

Method used

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Examples

Experimental program
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Embodiment Construction

[0021] A preparation method of photocatalytic composite modified molecular sieve, comprising the following steps:

[0022] (1) Mix glycerin and polyvinylpyrrolidone at a mass ratio of 44:1, heat in an oil bath to 80°C, and stir at 300 rpm for 20 minutes until the solution is completely dispersed, then add 0.5% silver nitrate to it , first keep the temperature and stir for 10 minutes, then raise the temperature to 110°C and stir for 2 hours, and finally cool to room temperature to obtain nano-silver sol for later use;

[0023] (2) Mix and stir sodium hydroxide, sodium metaaluminate and water at a mass ratio of 1.5:3.5:50 until completely dissolved, mix the mixed system with the directing agent solution at a mass ratio of 1.2:1 and continue stirring for 60 minutes to obtain For the initial gel, filter it under vacuum until there is no liquid dripping to obtain a semi-dry gel, then place it in a reaction kettle, raise the temperature to 100°C, and crystallize for 5 hours. After t...

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Abstract

The invention discloses a method for preparing a photocatalytic composite modified molecular sieve. The photocatalytic composite modified molecular sieve is prepared from tetrabutyl titanate, anhydrous ethanol, an alkaline solution, sodium metaaluminate, water glass and silver nitrate. Suction filtration is carried out to prepare semi-dry gel, and the semi-dry gel is used to produce the molecularsieve, so the solid content of a reaction kettle is improved, and the energy consumption in the production of per unit mass of the molecular sieve is reduced; the molecular sieve is modified with alkali, and the abundant meso-porous structures are introduced to the molecular sieve mainly based on micro-pores, so the load capacity of titanium dioxide is greatly improved; and a rich adsorption surface is used to increase the contact area of the titanium dioxide and pollutants, so the photocatalysis effect is efficiently completed, and the photocatalytic degradation of the pollutants is realized.

Description

technical field [0001] The invention relates to the technical field of photocatalytic materials, in particular to a method for preparing photocatalytic composite modified molecular sieves. Background technique [0002] With the rapid development of industry, the problem of environmental pollution is becoming more and more serious. Among them, the discharge of industrial waste water and waste gas is particularly prominent, and all countries have invested heavily in the research of treatment technologies for environmental purification and environmental pollution. Photocatalytic treatment technology has been widely concerned because it can reduce organic pollutants to inorganic substances, has fast reaction speed, high light utilization efficiency and no secondary pollution. Among them, how to improve the ability of photocatalytic materials to deal with environmental pollution has become a research hotspot. [0003] As a photocatalyst, nano-titanium dioxide has a good degrada...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J29/068
CPCB01J29/068B01J35/004B01J2229/18
Inventor 芮明功
Owner MAANSHAN TUORUI METAL SURFACE TECH
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