A kind of sulfur-containing Schiff base zn-na coordination polymer and its preparation method and application
A technology of coordination polymer and sulfur-containing Schiff base, which is applied in chemical instruments and methods, luminescent materials, antibacterial drugs, etc., can solve the problems of few research reports, and achieve good structural stability, increased activity, and good luminescence. performance effect
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Embodiment 1
[0041] Example 1 The synthesis of one-dimensional chain-like sulfur-containing Schiff base Zn-Na coordination polymers, the reaction steps are as follows:
[0042] Add 0.72mmol (162.19mg) o-vanillin thiosemicarbazone, 0.54mmol (about 118.54mg) zinc acetate, 0.8mmol (97.95mg) sodium perchlorate to 24mL N,N'-dimethylformamide , in a mixed solvent of acetonitrile and water (volume ratio 2:3:1), heated and refluxed in a water bath for 4 hours, adjusted the pH value to 6-8 with ammonia water, continued heating and stirring, controlled the temperature at 70°C, and reacted for 16 hours to obtain a colorless The solution was filtered, sealed, and naturally volatilized at room temperature. After three weeks, a light yellow crystal suitable for X-ray single crystal structure analysis was precipitated, with a yield of 52.36%. M.P.302~304℃; IR main absorption peaks are: 3245(w), 3434(m), 3275(m), 2912(w), 2805(w), 1580(vs), 1492(vs), 1439(vs ), 1296(s), 1232(s), 1140(m), 1113(m), 9676(m)...
Embodiment 2
[0044] Synthesis of One-dimensional Chain Sulfur-Containing Schiff Base Zn–Na Coordination Polymers
[0045] Add 0.64mmol (144.17mg) o-vanillin thiosemicarbazone, 0.56mmol (about 166.59mg) zinc nitrate hexahydrate, 0.54mmol (76.71mg) sodium sulfate to 30mL N,N'-dimethylacetamide , in a mixed solvent of acetonitrile and tetrahydrofuran (volume ratio 1:3:2), heat and reflux in a water bath for 3-5 hours, use ethylenediamine to adjust the pH value to 6-8, continue heating and stirring, control the temperature at 80°C, and react for 15-5 hours. After 18 hours, a light yellow solution was obtained, which was filtered, sealed, and evaporated naturally at room temperature. After three weeks, a light yellow crystal suitable for X-ray single crystal structure analysis was precipitated, with a yield of 53.62%.
Embodiment 3
[0047] Synthesis of One-dimensional Chain Sulfur-Containing Schiff Base Zn–Na Coordination Polymers
[0048] Add 0.48mmol (108.13mg) o-vanillin thiosemicarbazone, 0.48mmol (about 137.35mg) zinc sulfate heptahydrate, 0.48mmol (65.32mg) sodium acetate to 25mL N,N'-dimethylacetamide , in a mixed solvent of tetrahydrofuran and ethanol (volume ratio 5:10:8), heat and reflux in a water bath for 3 to 5 hours, adjust the pH value to 6 to 8 with triethylamine, continue heating and stirring, and control the temperature at 70 to 80°C. After ~20 hours, a light yellow solution was obtained, which was filtered, sealed, and naturally volatilized at room temperature. After three weeks, a light yellow crystal suitable for X-ray single crystal structure analysis was precipitated, with a yield of 54.21%.
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