Heat-resistant graphene conductive film and preparation method thereof

A conductive film, graphene technology, applied in conductive materials, conductive materials, cable/conductor manufacturing, etc., can solve problems such as poor thermal stability, poor compatibility, and reduced film mechanical stability, and improve thermal stability. , the effect of enhancing viscosity and improving mechanical stability

Pending Publication Date: 2018-09-28
戚明海
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyaniline has been widely studied and applied because of its easy-to-obtain raw materials, simple synthesis process, and good chemical and environmental stability; polyaniline film is a conductive film, which is widely used in solar cells, electrode materials, displays, etc. Among various optoelectronic materials, however, at present, commercially available polyaniline films have poor heat resistance stability, and in order to improve their heat resistance performance, high heat resistant inorganic fillers are often added therein, because the compatibility between inorganic fillers and polyaniline is poor , which will easily reduce the mechanical stability of the film

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A heat-resistant graphene conductive film, which is composed of the following parts by weight:

[0025] Graphene 14, diethylene glycol dibenzoate 2, alkanolamide 1, silane coupling agent kh5502, barium stearate 3, stannous sulfide 0.2, heat-resistant polyethylene wax 7, alkylphenol polyoxyethylene ether 0.2, polyaniline 70, ammonium polyphosphate 2, aluminum dihydrogen phosphate 4, triethanolamine 3.

[0026] In the heat-resistant graphene conductive film, the heat-resistant polyethylene wax is composed of the following raw materials in parts by weight:

[0027] Oxidized polyethylene wax 14, calcium acetylacetonate 2, hexamethylphosphoric triamide 1, stannous sulfide 1, glyceryl monostearate 2;

[0028] The preparation method of the heat-resistant polyethylene wax includes the following steps:

[0029] (1) Take stannous sulfide, add it to 10 times its weight in absolute ethanol, stir evenly to obtain an alcohol solution;

[0030] (2) Take the oxidized polyethylene wax, add it to ...

Embodiment 2

[0041] A heat-resistant graphene conductive film, which is composed of the following parts by weight:

[0042] Graphene 10, diethylene glycol dibenzoate 1, alkanolamide 0.8, silane coupling agent kh5501, barium stearate 2, stannous sulfide 0.1, heat-resistant polyethylene wax 5, alkylphenol polyoxyethylene ether 0.1, polyaniline 60, ammonium polyphosphate 1, aluminum dihydrogen phosphate 3, triethanolamine 2.

[0043] In the heat-resistant graphene conductive film, the heat-resistant polyethylene wax is composed of the following raw materials in parts by weight:

[0044] Oxidized polyethylene wax 10, calcium acetylacetonate 1, hexamethylphosphoric triamide 0.7, stannous sulfide 0.7, glyceryl monostearate 1;

[0045] The preparation method of the heat-resistant polyethylene wax includes the following steps:

[0046] (1) Take stannous sulfide, add it to 7 times its weight in absolute ethanol, stir evenly to obtain an alcohol solution;

[0047] (2) Take the oxidized polyethylene wax, add i...

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PUM

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Abstract

The invention discloses a heat-resistant graphene conductive film, which is composed of the following raw materials by weight: 10-14 parts of graphene, 1-2 parts of diethylene glycol dibenzoate, 0.8-1part of alkanolamide, 1-2 parts of silane coupling agent kh550, 2-3 parts of barium stearate, 0.1-0.2 part of stannous sulfide, 5-7 parts of heat-resistant polyethylene wax, 0.1-0.2 part of alkylphenol ethoxylate, 60-70 parts of polyaniline, 1-2 parts of ammonium polyphosphate, 3-4 parts of aluminum dihydrogen phosphate, and 2-3 parts of triethanolamine. The aluminum dihydrogen phosphate, calciumacetylacetonate and the like added by the invention may improve the heat stability of the finished film, and the aluminum dihydrogen phosphate may also enhance the viscosity between the raw materialsin the cast film forming process, thereby further improving the uniform stability of the film formation.

Description

Technical field [0001] The invention belongs to the field of films, and specifically relates to a heat-resistant graphene conductive film and a preparation method thereof. Background technique [0002] Polyaniline, a kind of polymer compound, has special electrical and optical properties, and can have conductivity and electrochemical properties after being doped. After certain treatments, various equipment and materials with special functions can be prepared, such as urease sensors that can be used as biological or chemical sensors, electron field emission sources, and have more excellent reversibility in the charge and discharge process than traditional lithium electrode materials. Electrode materials, selective membrane materials, anti-static and electromagnetic shielding materials, conductive fibers, anti-corrosion materials, etc. Polyaniline has been widely studied and applied because of its easy-to-obtain raw materials, simple synthesis process, and good chemical and enviro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/12H01B1/04H01B13/00H01B5/00
CPCH01B1/04H01B1/128H01B5/00H01B13/00
Inventor 戚明海
Owner 戚明海
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