A kind of dispersant and preparation method thereof
A technology of dispersant and initiator, which is applied in the field of dispersant and its preparation, can solve problems such as inability to effectively disperse calcium soap flocculents, achieve excellent product performance, improve product performance, and improve dispersion performance
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Embodiment 1
[0030] (1) Add 10 parts by mass of maleic anhydride in a four-necked flask equipped with a thermometer, condenser, dropping funnel and constant speed stirring device, and add 20 parts by mass of deionized water to dissolve simultaneously. In 1 min, 20 parts by mass of 30% sodium hydroxide solution was slowly added dropwise, heated in a water bath, and when the temperature rose to 55°C, 1 part by mass of sodium tungstate, 0.8 parts by mass of ammonium molybdate and 0.5 parts by mass of ammonium vanadate mixed catalyst, then control the rate of addition, drop 8 parts by mass of hydrogen peroxide in 20 minutes, and simultaneously use a 5% sodium hydroxide solution to adjust the pH value, at a temperature of 50 ° C, stirring Speed is 40r / min, react for 1h, the reaction product is extracted with acetone, and after purification, epoxysuccinic acid is obtained;
[0031] (2) The epoxysuccinic acid prepared in step (1) and 3-6 parts by mass of calcium hydroxide initiator are polymeri...
Embodiment 2
[0038](1) add the maleic anhydride of 15 mass parts in the four-necked flask that thermometer, condensing tube, dropping funnel and constant speed stirring device are housed, add the deionized water dissolving of 25 mass parts simultaneously, at stirring speed be 50r / In 1 min, slowly add 30 parts by mass of 30% sodium hydroxide solution dropwise, heat in a water bath, and when the temperature rises to 55°C, add 1.5 parts by mass of sodium tungstate, 1 part by mass of ammonium molybdate and 0.8 parts by mass of ammonium vanadate mixed catalyst, then control the rate of addition, drop 12 parts by mass of hydrogen peroxide within 20min, and simultaneously use a mass fraction of 5% sodium hydroxide solution to adjust the pH value, at a temperature of 60°C, stirring Under the speed of 50r / min, react for 2h, and the reaction product is extracted with acetone, and after purification, epoxysuccinic acid is obtained;
[0039] (2) The epoxysuccinic acid prepared in step (1) and 5 parts...
Embodiment 3
[0046] (1) Add 20 mass parts of maleic anhydride in a four-necked flask equipped with a thermometer, condenser, dropping funnel and constant speed stirring device, and add 30 mass parts of deionized water to dissolve simultaneously, at a stirring speed of 60r / In 1 min, slowly add 40 parts by mass of 30% sodium hydroxide solution dropwise, and heat in a water bath. When the temperature rises to 55°C, add 2 parts by mass of sodium tungstate, 1.2 parts by mass of ammonium molybdate and 1 mass part of ammonium vanadate mixed catalyst, then control the dropping speed, drop 15 mass parts of hydrogen peroxide in 20 minutes, and simultaneously use a mass fraction of 5% sodium hydroxide solution to adjust the pH value, at a temperature of 70 ° C, stirring The speed is 60r / min, react for 3h, and the reaction product is extracted with acetone, and after purification, epoxysuccinic acid is obtained;
[0047] (2) The epoxysuccinic acid prepared in step (1) and 6 parts by mass of calcium h...
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