Unlock instant, AI-driven research and patent intelligence for your innovation.

Lithium-iron battery diaphragm and lithium-iron diaphragm

A battery separator and lithium-iron technology, applied in the field of lithium-iron battery separator and lithium-iron battery, can solve the problems of thermal runaway, battery life reduction, heat accumulation, etc., to improve extrusion resistance, reduce self-discharge rate, and ensure transmission. The effect of efficiency

Inactive Publication Date: 2018-12-18
GUANGZHOU GREAT POWER ENERGY & TECH CO LTD
View PDF3 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Secondary batteries have been rapidly developed because they can be recharged and reused, but they cannot replace primary batteries due to their low primary capacity, high self-discharge rate, short storage time, poor safety performance, need to be charged after use, unstandardized models, and poor versatility. The primary battery has developed rapidly in recent years due to its advantages of high primary capacity, slow discharge level, standardized model and good versatility.
[0005] The safety performance of lithium primary batteries has always been concerned, and the separator plays an important role in the safety of lithium primary batteries. However, the existing separators have high tensile strength and low puncture strength, making them suitable for use in lithium iron batteries , it is easy to be pierced by dust burrs on the positive electrode sheet, causing local micro-short circuit inside the battery, causing battery self-discharge, and battery life is significantly reduced. , and then cause a large area of ​​short circuit inside the battery, aggravate the accumulation of heat, cause thermal runaway, and cause the battery to burn or explode

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Lithium-iron battery diaphragm and lithium-iron diaphragm
  • Lithium-iron battery diaphragm and lithium-iron diaphragm
  • Lithium-iron battery diaphragm and lithium-iron diaphragm

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0047] In a further preferred embodiment of the present invention, the preparation method of the lithium iron battery separator specifically includes the following steps:

[0048] The polyolefin masterbatch is subjected to extrusion plasticization, biaxial stretching and solvent washing in sequence to obtain a lithium iron battery separator.

[0049] Through extrusion and plasticization, the performance of the produced diaphragm is uniform and stable. Through bi-directional stretching, the transverse tensile strength and longitudinal tensile strength of the diaphragm are improved, and the small molecule porogen in the diaphragm is removed from the diaphragm by solvent washing. It is washed out to obtain a membrane with uniform pore size.

[0050] In the preferred embodiment of the present invention, the polyolefin masterbatch contains a small molecule porogen, and the small molecule porogen is commercially available.

[0051] In a typical but non-limiting embodiment of the present inv...

Embodiment 1

[0065] This embodiment provides a lithium iron battery separator, which is made of polypropylene, its thickness is 25μm, porosity is 50%, puncture strength is 700Mpa, transverse tensile strength is 90Mpa, longitudinal tensile strength is 120Mpa, transverse heat The shrinkage rate is 4.5%, the longitudinal heat shrinkage rate is 1.5%, and the air permeability is 450Sec / 100mL.

Embodiment 2

[0067] This embodiment provides a lithium iron battery separator, which is made of polypropylene, its thickness is 35μm, porosity is 40%, puncture strength is 850Mpa, transverse tensile strength is 100Mpa, longitudinal tensile strength is 150Mpa, transverse heat The shrinkage rate is 0.5%, the longitudinal heat shrinkage rate is 0.1%, and the air permeability is 250Sec / 100mL.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
strengthaaaaaaaaaa
tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention provides a lithium-iron battery diaphragm and a lithium-iron battery, and relates to the technical field of separators, wherein the thickness of the diaphragm is 25-35[mu]m, and the porosity of the diaphragm is 40-50%, and the puncture strength of the diaphragm is 700-1200Mpa, which alleviates the technical problem that when is used in a lithium-iron battery, an existing diaphragm is easy to pierce, causing a micro-short circuit inside the battery, causing battery self-discharge, at the same time, it is easy to induce safety accidents, the lithium-iron battery diaphragm providedby the invention can not only ensure the transmission efficiency of electrolyte ions, but also avoid the dust and burr puncture on the positive electrode sheet of the lithium-iron battery, thus ensuring the safety of the lithium-iron battery, and meanwhile, the thickness of the lithium-iron battery diaphragm provided by the invention is moderate, so as to ensure the stability of the lithium-ironbattery in use.

Description

Technical field [0001] The invention relates to the technical field of diaphragms, in particular to a lithium-iron battery diaphragm and a lithium-iron battery. Background technique [0002] With the continuous advancement of electronic information technology, consumer electronic products continue to develop towards diversification, miniaturization, and high power. The performance requirements of all aspects of batteries are also rapidly increasing, requiring high energy density, high power density and price. Suitable, easy to use, low self-discharge rate, long storage life, especially for the energy density and power density of the battery puts forward higher and higher requirements. [0003] Secondary batteries have developed rapidly due to rechargeable and repeated use, but they cannot replace primary batteries due to their low primary capacity, high self-discharge rate, short storage time, poor safety performance, need to be recharged after use, and poor model versatility. The...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): H01M2/16H01M2/14H01M10/052H01M50/403H01M50/417H01M50/489H01M50/491H01M50/494
CPCH01M10/052H01M50/403H01M50/411Y02E60/10
Inventor 郭镖薛建军薛江丽崔燕陈玮周意君
Owner GUANGZHOU GREAT POWER ENERGY & TECH CO LTD