Lithium-iron battery diaphragm and lithium-iron diaphragm
A battery separator and lithium-iron technology, applied in the field of lithium-iron battery separator and lithium-iron battery, can solve the problems of thermal runaway, battery life reduction, heat accumulation, etc., to improve extrusion resistance, reduce self-discharge rate, and ensure transmission. The effect of efficiency
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[0047] In a further preferred embodiment of the present invention, the preparation method of the lithium iron battery separator specifically includes the following steps:
[0048] The polyolefin masterbatch is subjected to extrusion plasticization, biaxial stretching and solvent washing in sequence to obtain a lithium iron battery separator.
[0049] Through extrusion and plasticization, the performance of the produced diaphragm is uniform and stable. Through bi-directional stretching, the transverse tensile strength and longitudinal tensile strength of the diaphragm are improved, and the small molecule porogen in the diaphragm is removed from the diaphragm by solvent washing. It is washed out to obtain a membrane with uniform pore size.
[0050] In the preferred embodiment of the present invention, the polyolefin masterbatch contains a small molecule porogen, and the small molecule porogen is commercially available.
[0051] In a typical but non-limiting embodiment of the present inv...
Embodiment 1
[0065] This embodiment provides a lithium iron battery separator, which is made of polypropylene, its thickness is 25μm, porosity is 50%, puncture strength is 700Mpa, transverse tensile strength is 90Mpa, longitudinal tensile strength is 120Mpa, transverse heat The shrinkage rate is 4.5%, the longitudinal heat shrinkage rate is 1.5%, and the air permeability is 450Sec / 100mL.
Embodiment 2
[0067] This embodiment provides a lithium iron battery separator, which is made of polypropylene, its thickness is 35μm, porosity is 40%, puncture strength is 850Mpa, transverse tensile strength is 100Mpa, longitudinal tensile strength is 150Mpa, transverse heat The shrinkage rate is 0.5%, the longitudinal heat shrinkage rate is 0.1%, and the air permeability is 250Sec / 100mL.
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