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Method for recovering metal from laterite-nickel ore leaching liquid and producing magnesium salt by using resin adsorption method

A technology of laterite nickel ore and resin adsorption, applied in the direction of improving process efficiency, can solve the problems of low recovery rate of valuable metals, increased production cost, sulfide pollution, etc., and achieves low regeneration cost, long service life, and high purity. Effect

Active Publication Date: 2019-04-09
广西银亿新材料有限公司
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AI Technical Summary

Problems solved by technology

The existing technology generally adopts the alkali or sulfide precipitation method to reclaim valuable metals such as nickel, cobalt, and copper in the laterite nickel ore acid leaching solution. The defects of this technology are: the first is that the alkali consumption is high, which increases the production cost; The treatment of sulfide is likely to cause pollution and safety accidents; the third is that the recovery rate of valuable metals such as nickel and cobalt is generally low under this method

Method used

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  • Method for recovering metal from laterite-nickel ore leaching liquid and producing magnesium salt by using resin adsorption method

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Embodiment Construction

[0024] see figure 1 , the resin adsorption method of the present invention recovers metals in laterite nickel ore leaching solution and produces magnesium salts, comprising the following steps: (1) The laterite nickel ore leaching solution undergoes iron precipitation and solid-liquid separation to obtain iron slag and iron-deposited solution. (2) The iron-precipitated liquid passes through the first ion exchange resin to selectively adsorb nickel to obtain the nickel-adsorbed liquid and the first ion-exchange resin after adsorption; the pH of the iron-precipitated liquid is 2-5; the components of the iron-precipitated liquid And its concentration is: nickel 2g / L-10g / L, cobalt<0.5g / L, manganese<0.5g / L, iron<0.01g / L, magnesium 50g / L-80g / L. The first ion-exchange resin is the corresponding hydrogen-type resin after the LSC-930 resin is converted to hydrogen-type, and the first ion-exchange resin preferentially adsorbs nickel. (3) Analyze the first ion exchange resin after adsor...

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Abstract

The invention discloses a method for recovering metal from a laterite-nickel ore leaching liquid and producing magnesium salt by using a resin adsorption method. The method comprises the following steps that the laterite-nickel ore leaching liquid which is subjected to iron precipitation undergoes adsorption and analysis through a first ion exchange resin to obtain a post-adsorption liquid, and the post-adsorption liquid undergoes the adjustment of the pH value, natural cooling and chilled water cooling in sequence to obtain precipitated magnesium salt and a post-magnesium-extraction liquid;and adsorption and analysis are carried out on the post-magnesium-extraction liquid through a second ion exchange resin to obtain a mixed solution containing nickel, cobalt and manganese. According tothe method, the nickel, the cobalt and the manganese can be selectively adsorbed from the laterite-nickel ore leaching liquid, moreover, the magnesium salt can be produced, separation and recovery ofthe nickel, the cobalt, the manganese and the magnesium are realized, and the technological process is shortened; the ion exchange resin is long in service life and low in regeneration cost, so thatthe production cost is reduced; and the obtained nickel, cobalt and manganese is high in purity and can be used for producing other downstream products, the additional value of the products is high, and the economic benefit is obvious.

Description

technical field [0001] The invention belongs to the technical field of hydrometallurgy, and in particular relates to a method for recovering metal in laterite nickel ore leaching solution and producing magnesium salt by a resin adsorption method. Background technique [0002] The ore grade of laterite nickel ore is low, the cost of smelting is high, and the technical economy is poor compared with nickel sulfide ore. Due to the limitation of raw material grade, the key to the development and utilization of laterite nickel ore is to reduce production cost, simplify production process and production equipment. Atmospheric pressure heap leaching of laterite nickel ore can reduce production costs and increase production capacity, but there are still technical difficulties in the purification of laterite nickel ore leachate and the enrichment of valuable metals. The existing technology generally adopts the alkali or sulfide precipitation method to reclaim valuable metals such as ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/42C22B23/00C22B26/22C22B47/00
CPCC22B3/42C22B23/0453C22B26/22C22B47/00Y02P10/20
Inventor 任卫东和润秀田建华谢华思李勇宾
Owner 广西银亿新材料有限公司
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