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Copper-titanium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof

A technology of austenitic stainless steel and heat treatment method, which is applied in the field of austenitic stainless steel and can solve the problems of increased contact resistance and inability to meet the requirements of bipolar plate materials.

Inactive Publication Date: 2019-04-12
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The passivation layer formed by 316L stainless steel without surface treatment in the fuel cell environment will lead to an increase in contact resistance, which cannot meet the requirements of bipolar plate materials

Method used

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  • Copper-titanium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof
  • Copper-titanium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof
  • Copper-titanium-cobalt modified austenitic stainless steel and processing and heat treatment method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Select electrical pure iron, metal chromium sheet, metal nickel plate, 304 stainless steel waste, pure copper block, pure cobalt sheet, and metal titanium as raw materials. The stainless steel composition is as follows: C=0.03, Ni=8.0, Cr=20.0, Ti= 0.12, Cu=0.2, Co=0.1, Mn=1.2, Si=0.8, P≤0.035, S≤0.030, Fe=balance.

[0052] After the corresponding raw materials are weighed according to the composition requirements, the argon shielded arc melting is carried out, and the temperature of the molten pool is maintained at 1720°C during melting; the molten steel is calmed for 10 minutes before pouring, and the molten steel is poured under argon shielding at 1600°C.

[0053] The plate is hot-rolled by a flat-roll mill. The hot-rolling plan is to heat the cast billet to 1290°C, hold it for 5 hours, and then roll it out of the furnace. The hot-rolling start temperature is 1190°C, and the final rolling temperature is 950°C. The total amount of plate hot rolling is 60%.

[0054] T...

Embodiment 2

[0058] 304L stainless steel waste, pure copper block, pure cobalt sheet, and ferro-titanium are selected as raw materials, and the composition of the configured stainless steel is as follows: C=0.014, Ni=9.0, Cr=18.8, Ti=0.16, Cu=0.3, Co=0.5, Mn= 1.2, Si=0.7, P≤0.035, S≤0.030, Fe=balance.

[0059] After weighing the corresponding raw materials according to the composition requirements, vacuum induction melting is carried out, and the temperature of the molten pool is maintained at 1680°C during melting; the molten steel is calmed for 5 minutes before pouring, and the molten steel is vacuum poured at 1500°C.

[0060] The plate is hot-rolled by a flat-roll mill. The hot-rolling plan is to heat the cast slab to 1270°C, heat it for 5 hours and then roll it out of the furnace. The hot-rolling start temperature is 1160°C and the final rolling temperature is 1000°C. The total amount of hot rolling of the plate is 65%.

[0061] The plate is deformed by cold rolling, and the total red...

Embodiment 3

[0065] Select electrical pure iron, metal chromium sheet, metal nickel plate, pure copper block, pure cobalt sheet, titanium iron, and graphite block as raw materials. The stainless steel composition is as follows: C=0.025, Ni=12.0, Cr=18.0, Ti=0.34 , Cu=0.4, Co=0.2, Mn=0.8, Si=0.5, P≤0.035, S≤0.030, Fe=balance.

[0066]After weighing the corresponding raw materials according to the composition requirements, they are induction smelted under the protection of argon gas.

[0067] The plate is hot-rolled with a flat roll mill. The hot-rolling plan is to heat the cast billet to 1280°C, keep it warm for 4 hours, and then roll it out of the furnace. The hot-rolling start temperature is 1180°C, and the final rolling temperature is 980°C. The total amount of hot rolling of the plate is 70%.

[0068] The plate is deformed by cold rolling, and the total reduction of cold rolling is 82%.

[0069] The plate is annealed at 1100°C, the holding time is 60 minutes, and nitrogen protection i...

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Abstract

The invention provides copper-titanium-cobalt modified austenitic stainless steel and a processing and heat treatment method thereof. The copper-titanium-cobalt modified austenitic stainless steel comprises, by mass, no less than 0.03% of C, 8.0%-12.0% of Ni, 18.0%-20.0% of Cr, no less than 0.42% of Ti, 0.2%-0.8% of Cu, 0.1%-0.5% of Co, no less than 2.0% of Mn, no less than 1.0% of Si, no less than 0.035% of P, no less than 0.030% of S, and the balance Fe, wherein 3.98*C<=Ti<=3.98*C+0.3. Thermal-deformation blooming, cold deformation, TiC crushing and dispersion, high-temperature solution treatment, and grain coarsening are sequentially conducted. The corrosion current density of the copper-titanium-cobalt modified austenitic stainless steel in an H2SO4 electrolyte having a concentration of 0.5mol / L and containing 5*10<-6>F<-> at the temperature of 80 DEG C under an oxygen condition is 1.89-2.39[mu]A / cm<2> and is equivalent to that of a stainless steel bipolar plate with a coating on the surface. The copper-titanium-cobalt modified austenitic stainless steel has the characteristics of low hardness and high ductility, and formation of a passage of the bipolar plate is facilitated.

Description

technical field [0001] The invention belongs to the field of austenitic stainless steel, relates to composition design, processing and heat treatment method of high corrosion resistance austenitic stainless steel, and can be widely used in energy, electric power, chemical industry and daily life. technical background [0002] A fuel cell is a device that directly converts the chemical energy between hydrogen fuel and oxidant into electrical energy through an electrode reaction. Due to its high efficiency, low pollution, short construction time, good reliability and maintainability, it is the fourth generation power generation technology after hydropower, thermal power and nuclear power. Among many fuel cells, the proton exchange membrane fuel cell is a new type of fuel cell that develops late, but it develops most rapidly. [0003] In a fuel cell, the conductive separators that support, collect, divide oxidants and reductants and guide the flow of oxidants and reductants on...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/50C22C38/42C22C38/52C22C38/58C22C38/04C22C38/02B21C37/00C21D8/00
CPCB21C37/00C21D8/005C21D2211/001C22C38/02C22C38/04C22C38/42C22C38/50C22C38/52C22C38/58Y02P10/20
Inventor 罗丰华杜帅潘亚飞卢静周海铭赵甲正
Owner CENT SOUTH UNIV