Unlock instant, AI-driven research and patent intelligence for your innovation.
A novel hydrogen bond cross-linked stretchable conductive polymer and its synthesis method
What is Al technical title?
Al technical title is built by PatSnap Al team. It summarizes the technical point description of the patent document.
A conductive polymer and hydrogen bond technology, applied in the field of new hydrogen bond cross-linked stretchable conductive polymer and its synthesis, can solve the problems of weak force and stability, achieve mild reaction conditions, good application prospects, and large theory The effect of guidance and technical support
Active Publication Date: 2021-06-04
合肥龙之韵医药技术有限公司
View PDF1 Cites 0 Cited by
Summary
Abstract
Description
Claims
Application Information
AI Technical Summary
This helps you quickly interpret patents by identifying the three key elements:
Problems solved by technology
Method used
Benefits of technology
Problems solved by technology
The formation of hydrogen bonds is mainly due to electrostatic force, and its bond energy is mostly 25-40kJ / mol, which is slightly stronger than van der Waals force, but its force and stability are significantly weaker than covalent bonds and ionic bonds
Method used
the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more
Image
Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
Click on the blue label to locate the original text in one second.
Reading with bidirectional positioning of images and text.
Smart Image
Examples
Experimental program
Comparison scheme
Effect test
Embodiment 1
[0055] A hydrogen-bonded cross-linked intrinsically stretchable conductive polymer based on EDOT oligomers, prepared by the following steps:
[0056] (1) Synthesis of stretchable group N2, N6-bis(2-(5-(tributyltin)thiophene)ethyl)pyridine-2,6-dicarboxamide (SnBu 3 -PDCA-SnBu 3 ):
[0057]
[0058] 1a) Dissolve 2,6-pyridinedicarboxylic acid (5.00g, 30mmol) in the raw material, add dropwise oxalyl chloride (11.43g, 90mmol) at 0°C, after the addition is complete, raise the temperature of the solution to 25°C, and stir to form 2,6-pyridine dicarboxylic acid chloride, the yield is 95%;
[0059] 1b) The resulting 2,6-pyridinedicarboxylic acid chloride (6.00 g, 360 mmol) and 2-thienylethylamine (12.00 g, 640 mmol) were dissolved in triethylamine (5 mL) and CH 2 Cl 2 (40mL) in a mixed solution, react at room temperature to generate N2, N6-bis(2-(thiophen-2-yl)ethyl)pyridine-2,6-dicarboxamide (PDCA), which is obtained after separation and purification with a silica gel column w...
Embodiment 2
[0075] A ProDOT-Bu based 2 Hydrogen bond crosslinking of oligomers intrinsically stretchable conductive polymers, prepared by the following steps:
[0076] (1) Synthesis of stretchable group N5, N5'bis(2-(2,2'-(tributyltin)-thiophene)ethyl)-[2,2'-bipyridine]-5,5'-bis Formamide (SnBu 3 -BPDCA-SnBu 3 ):
[0077]
[0078] 1a) Suspend 2,2'-bipyridine 5,5'-dicarboxylic acid (1.00 g, 4.10 mmol) in thionyl chloride (20 mL) at room temperature, and add a few drops of dimethylformaldehyde to the above suspension amide (DMF), then turned into a clear red solution. The solution was stirred continuously for several hours, then the thionyl chloride was distilled off under reduced pressure. The pale yellow solid remaining in the flask was washed several times with cold dichloromethane to give the product 2,2'-bipyridine 5,5'-dicarbonyl chloride (BPYDC).
[0079] 1b) The resulting 2,2'-bipyridine 5,5'-diformyl chloride (5.00 g, 17.80 mmol) and 2-thienylethylamine (5.65 g, 44.5 mmol)...
the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More
PUM
Login to View More
Abstract
The invention discloses a novel hydrogen bond cross-linked stretchable conductive polymer and a synthesis method, belonging to the technical field of polymer synthesis. The above-mentioned novel hydrogen-bonded cross-linked stretchable conductive polymer includes a hydrogen-bonded cross-linked stretchable group and a functional conductive group; the hydrogen-bonded cross-linked stretchable group is a nitrogen-containing heterocycle; the The functional conductive groups are oligomers of 3,4-dioxyethylenethiophenes (EDOT), thiophenes, selenophenes and pyrroles and their derivatives. The novel hydrogen bond cross-linked stretchable conductive polymer prepared by the invention is based on the intrinsic stretchable group as the core, so that the polymer has good stretchable self-healing properties.
Description
technical field [0001] The invention relates to the technical field of polymer synthesis, in particular to a novel hydrogen bond cross-linked stretchable conductive polymer and a synthesis method. Background technique [0002] Since the research team of Mac Diarmid, a chemist at the University of Pennsylvania, first discovered that doped polyacetylene (PA) has metal-like conductivity in 1976, people have deepened their understanding of the structure and understanding of conjugated polymers. Improvement, the birth of a new interdisciplinary discipline of conductive polymers. In subsequent studies, conductive polymers such as polypyrrole, polyparaphenylene, polyphenylene sulfide, polythiophene, and polyaniline were gradually discovered. The special structure and excellent physical and chemical properties of conductive polymers make it a research hotspot in materials science. As one of the irreplaceable emerging basic organic functional materials, conductive polymer materials ...
Claims
the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More
Application Information
Patent Timeline
Application Date:The date an application was filed.
Publication Date:The date a patent or application was officially published.
First Publication Date:The earliest publication date of a patent with the same application number.
Issue Date:Publication date of the patent grant document.
PCT Entry Date:The Entry date of PCT National Phase.
Estimated Expiry Date:The statutory expiry date of a patent right according to the Patent Law, and it is the longest term of protection that the patent right can achieve without the termination of the patent right due to other reasons(Term extension factor has been taken into account ).
Invalid Date:Actual expiry date is based on effective date or publication date of legal transaction data of invalid patent.
Login to View More 
Login to View More