A kind of antistatic release emulsion with good stability and preparation method thereof

A stable performance, antistatic technology, applied in the direction of conductive coatings, coatings, etc., can solve the problems of increasing the amount of catalyst, antistatic performance failure, long production cycle, etc., to achieve good storage stability, enhanced conductivity, peeling force stable effect

Active Publication Date: 2020-11-13
中山市聚力有机硅技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since most of the antistatic agents or antistatic emulsions currently on the market do not have a release function, the conventional antistatic release film preparation method is to perform antistatic treatment on the film substrate, and then perform release treatment, so that it will Increase the process, resulting in a long production cycle, and in the release treatment, the antistatic substance will easily lead to the weakening or even failure of the catalytic activity of the catalytic system during the film forming process, so it is necessary to increase the amount of catalyst to solidify and form a film
The two-step method of antistatic treatment and release treatment to prepare antistatic release film not only increases the cost, but also leads to unstable peeling force of the release film during later storage, and even affects the stability of antistatic performance. lead to failure of antistatic performance

Method used

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  • A kind of antistatic release emulsion with good stability and preparation method thereof
  • A kind of antistatic release emulsion with good stability and preparation method thereof
  • A kind of antistatic release emulsion with good stability and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] An antistatic release emulsion with good stability, which is composed of 20 parts of alkenyl polysiloxane, 8.5 parts of hydrogen-containing polysiloxane, 0.05 parts of phenyl hydroxy network silicone resin, 0.05 parts of conductive polymer polythiophene, 2 parts of single-armed carbon nanotube aqueous solution, 3.5 parts of epoxy-containing linear silane coupling agent, 5.9 parts of surfactant, and 60 parts of water.

[0047] The alkenyl polysiloxane consists of 5 parts of linear vinyl-terminated polyorganosiloxane with a viscosity of 100 mPa·s and 15 parts of vinyl-terminated MQ resin with a viscosity of 700 mPa·s.

[0048] The hydrogen-containing polysiloxane is a methylhydrogensiloxane-dimethylsiloxane cyclic copolymer (the hydrogen content is 0.8mmol / g).

[0049] The structural formula of the phenyl hydroxy reticular silicone resin is as follows:

[0050]

[0051] Wherein, R, R", R"' are the same or different linear or branched aryl groups of 6-20 carbon atoms o...

Embodiment 2

[0063] A kind of antistatic release type emulsion with good stability, by weight, it is composed of: 5 parts of alkenyl polysiloxane, 4 parts of hydrogen-containing polysiloxane, 1 part of phenyl hydroxy network silicone resin, 5 parts of conductive polymer polythiophene, 0.05 parts of single-armed carbon nanotube aqueous solution, 5 parts of epoxy-containing linear silane coupling agent, 10 parts of surfactant, and 69.95 parts of water.

[0064] The alkenyl polysiloxane is a vinyl-terminated MT resin with a viscosity of 100 mPa·s.

[0065] The hydrogen-containing polysiloxane is a methylhydrogensiloxane-dimethylsiloxane cyclic copolymer (hydrogen content is 0.45mmol / g).

[0066] The structural formula of the phenyl hydroxy reticular silicone resin is as follows:

[0067]

[0068] Among them, R, R", R"' are the same or different linear or branched aryl groups with 6 to 20 carbon atoms or aralkyl groups with 7 to 20 carbon atoms, and R' is a hydroxyl group;

[0069] The pr...

Embodiment 3

[0080] A kind of antistatic release emulsion with good stability performance, by weight, it is composed of: 9 parts of alkenyl polysiloxane, 0.5 part of hydrogen-containing polysiloxane, 0.8 part of phenyl hydroxy network silicone resin, 2.5 parts of conductive polymer polythiophene, 1.2 parts of single-armed carbon nanotube aqueous solution, 1 part of linear silane coupling agent containing epoxy group, 1 part of surfactant, and 85 parts of water.

[0081] The alkenyl polysiloxane is a linear vinyl-terminated polyorganosiloxane with a viscosity of 500 mPa·s.

[0082] The hydrogen-containing polysiloxane is dimethyl polysiloxane (hydrogen content: 1.7 mmol / g) whose two ends are capped with dimethylhydrogensiloxy groups.

[0083] The structural formula of the phenyl hydroxy reticular silicone resin is as follows:

[0084]

[0085] Among them, R, R", R"' are the same or different linear or branched aryl groups with 6 to 20 carbon atoms or aralkyl groups with 7 to 20 carbon a...

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Abstract

The invention relates to the technical field of release emulsion, and discloses antistatic release emulsion with excellent stability performance and a method for preparing the antistatic release emulsion. The antistatic release emulsion with the excellent stability performance comprises, by weight, 5-20 parts of alkenyl polysiloxane, 0.5-10 parts of hydrogen-containing polysiloxane, 0.05-1 part ofphenyl hydroxyl reticular silicon resin, 0.05-5 parts of conductive polymer polythiophene, 0.05-2 parts of single-wall carbon nano-tube aqueous solution, 1-5 parts of linear silane coupling agents with epoxy groups, 1-10 parts of surfactants and 60-85 parts of water. The antistatic release emulsion and the method have the advantages that the antistatic release emulsion can be applied to thin filmbase materials, and prepared release films are excellent in stable antistatic property and stable in release property; the antistatic release emulsion is suitable for online coating, working procedures can be reduced, and the cost can be lowered.

Description

technical field [0001] The invention relates to the technical field of release emulsions, in particular to an antistatic release emulsion with good stability and a preparation method thereof. Background technique [0002] During the handling or use of glass, high-grade plates, electronic products and other products, the surface is prone to contact pollution or scratches, so a protective film is used to cover the surface to avoid pollution or damage. Generally, plastic films are used, but plastic films The dielectric constant is small, it is a non-conductor, and its insulation performance is high, so it will generate static electricity. However, the accumulation of static electricity on the surface of the plastic film can easily cause the surface to absorb dust, even cause discharge, and cause a fire. Therefore, in order to avoid the accumulation of static electricity on the surface of the plastic film, the plastic film is usually treated with antistatic treatment to enhance ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/07C09D183/05C09D183/04C09D165/00C09D5/24C09D7/61C09D7/65C09D7/63
CPCC08K2201/011C08L2201/04C08L2205/02C08L2205/025C08L2205/035C09D5/24C09D7/61C09D7/63C09D7/65C09D165/00C09D183/04C08L83/04C08L65/00C08L83/06C08K3/041C08K5/19C08L71/02C08K3/04
Inventor 曹坚林秦碧殷苏荣坚梁敏思
Owner 中山市聚力有机硅技术有限公司
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