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A kind of water-based electromagnetic shielding coating and preparation method thereof

An electromagnetic shielding coating, water-based technology, applied in conductive coatings, polyester coatings, anti-corrosion coatings, etc., can solve the problems of low adhesion of water-based coatings, people's health effects, easy to be oxidized, etc., to achieve good adhesion, excellent electromagnetic Shielding effect, low VOC effect

Active Publication Date: 2021-08-17
SHANDONG OBO NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Electromagnetic shielding coatings have excellent antistatic and electromagnetic shielding properties, but at present, most electromagnetic shielding coatings use solvent-based electromagnetic shielding coatings, which have a serious impact on the environment and people's health
With the continuous attention of the whole society to environmental protection and green development, water-based electromagnetic shielding coatings have emerged as the times require, but there are some shortcomings in the existing water-based electromagnetic shielding coatings: water-based coatings have low adhesion and are easy to fall off; the performance of silver-based electromagnetic shielding coatings Good, but it is prone to silver migration; copper-based electromagnetic shielding coatings are easily oxidized, etc.

Method used

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  • A kind of water-based electromagnetic shielding coating and preparation method thereof
  • A kind of water-based electromagnetic shielding coating and preparation method thereof
  • A kind of water-based electromagnetic shielding coating and preparation method thereof

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preparation example Construction

[0108] The present invention is to improve the utility of the preparation method, the complete process route, and the reaction preferably also includes a post-processing step. The present invention is not particularly limited to the specific steps of the post-treatment, as described in the artificial processes well known to those skilled in the art, and those skilled in the art can choose and adjust and adjust according to actual production, product requirements, and quality requirements. The post-treatment preferably includes water washing and separation, more particularly preferably water washing to neutral and centrifugation.

[0109] The present invention then obtained the insertion graphite obtained by the above steps to expand the expansion graphite.

[0110] The present invention is not particularly limited to the temperature of the high temperature expansion, and those skilled in the art can be selected and adjusted according to actual production, product requirements, and...

Embodiment 1

[0155] High-conductive graphene

[0156] The raw materials were 1000 megadownload megadownload megadownload megadownload. 10 g of graphite was mixed with 50 g of dihydrocarbon and mixed with 50 g of sodium carbonate, and the mixture was mechanically stirred, and the reaction was reacted at room temperature for 20 hours, then 400 g of water was diluted, and centrifugally gave the inserted graphite. The inserted graphite is placed in a muffle furnace of 1000 ° C, and expands 30s. 5 g of expanded graphite was dispersed in 5LN-methylpyrrolidone, 800 W ultrasonic strip 8h, 300 rmp ball milling 2 h, centrifugal water was washed, resulting in high conductive graphene.

[0157] High conductive graphene prepared in Example 1 of the present invention is characterized.

[0158] See figure 1 , figure 1 A atomic force micrograph of high conductive graphene prepared for the first embodiment of the present invention.

[0159] Depend on figure 1 The atomic force microscope showed that the graphen...

Embodiment 2

[0174] 10 g of deionized water, 0.5 g of dispersing agent, 0.1 g defoamer, 0.1 g of graft, 0.1g wetting agent, 0.7 g of rheological modifier agent in the specified container, is preliminaryly mixed; 5g of titanium powder 5G rust-proof pigment, 10 g of crystalline stone powder, 1 g graphene (Example 1 Preparation) Dry powder and prior to preliminary mixing solutions were added to the ball mill, so that the material was 30 or less. The grinding slurry was poured into the specified container, and the deionized water 1 g, anti-laminosid 1 g, 0.5 g of film forming aid was added, and mixed mixture was mixed, and the mixture was mixed and mixed.

[0175] The 43 g of aqueous resin and 0.5 g of the attachment promoter were weighed at 500 rpm in the specified container for 10 min to mix well, resulting in a component B.

[0176] The A component and the B component were stirred at 500 rpm for 15 min to mix evenly. Stay for 30 min to obtain aqueous graphene electromagnetic shield coating.

[...

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Abstract

The invention provides a water-based electromagnetic shielding coating, comprising: A component and B component; the A component is a graphene slurry; the graphene slurry includes graphene, a curing agent, a filler, a first auxiliary agent, dispersant and water; the B component includes water-based resin and the second auxiliary agent. The present invention adjusts the way of adding graphene raw materials. Among the conventional components of water-based electromagnetic shielding coatings, specific types of components are selected as auxiliary agents to form graphene slurry with graphene, and then it is combined with other components as a whole. Mixing, so that graphene can be uniformly dispersed in the coating, so as to obtain a water-based graphene electromagnetic shielding coating with good adhesion, impact resistance, salt spray resistance, electrical conductivity and heat dissipation, which fills the water-based electromagnetic shielding lack of. Moreover, the preparation process is simple, the conditions are mild, safety and environmental protection, the production cost is effectively reduced, the market demand is met, and industrialized large-scale production is easy.

Description

Technical field [0001] The invention relates to the field of aqueous coating, involving an aqueous electromagnetic shielding coating and a method of preparation thereof, and more particularly to aqueous electromagnetic shield coating containing graphene and a preparation method thereof. Background technique [0002] Graphene is a new material of a single-layer sheet structure composed of carbon atoms as a two-dimensional crystal having only one atom thickness consisting of carbon atoms, which is the thinnest in the application field. Materials and the strongest materials, there is also a good elasticity; at the same time, graphene also has excellent conductivity, can reduce internal resistance, improve the cycle stability of supercapacitors; in addition, graphene is almost completely transparent, only Absorbed 2.3% of the light and very dense, even the smallest gas atom (helium atom) can not penetrate. These characteristics have enabled graphene in energy storage materials, envir...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/00C09D167/08C09D163/00C09D179/02C09D127/12C09D175/04C09D5/24C09D5/08
Inventor 赵永彬张在忠李鹏宇李伟铭程金杰
Owner SHANDONG OBO NEW MATERIAL CO LTD