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A flexible single-stage two-catalyst hydrocracking process

A technology of hydrocracking and hydroisomerization cracking, which is applied in the fields of hydrotreating process, petroleum industry, hydrocarbon oil treatment products, etc., can solve problems such as poor operation flexibility, and achieve the effect of high viscosity index and low freezing point

Active Publication Date: 2019-07-09
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Therefore, when using the above hydrocracking processes alone, you can only choose different types of single-stage two-dose hydrocracking catalysts according to your needs, or use two molecular sieve composite catalysts, or use two types of hydrocracking catalysts in gradations. However, these processes can only produce tail oil products of one nature, that is, the operation flexibility is relatively poor

Method used

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  • A flexible single-stage two-catalyst hydrocracking process
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Embodiment 1-3

[0042] Protective agents FZC-100, FZC-105 and FZC106 are hydrogenation protective agents developed and produced by Sinopec Fushun Petrochemical Research Institute; catalyst FF-56 is developed and produced by Sinopec Fushun Petrochemical Research Institute Hydrotreating catalyst; Catalyst FC-28 is a single-stage hydrocracking catalyst developed and produced by Sinopec Fushun Petrochemical Research Institute, containing Y-type molecular sieve; Catalyst ZHC-02 is Sinopec Fushun Petrochemical The single-stage hydrocracking catalyst developed and produced by the research institute does not contain molecular sieves; the catalyst FC-14 is a single-stage hydroisomerization cracking catalyst developed and produced by Sinopec Fushun Petrochemical Research Institute, which contains β-type molecular sieves.

[0043] Table 1 Main properties of wax oil feedstock

[0044] wax oil 1 wax oil 2 Density, g / cm 3

0.905 0.918 Distillation range, ℃ 320~546 345~560 ...

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Abstract

The invention discloses a flexible single-stage two-catalyst hydrocracking process. A wax oil raw material and hydrogen are mixed and then enter a single-stage two-catalyst hydrocracking reactor, andthe material passing through an upper hydrogenation pretreatment catalyst bed layer and a single-stage hydrocracking catalyst bed layer is divided into two streams; one material stream is extracted out of the single-stage reactor from the middle of the bed layers, enters a hydroisomerization cracking reactor and subjected to isomerization cracking reaction; the other material stream flows downwards through a single-stage hydrocracking catalyst bed layer at the lower part; and a single-stage hydrocracking reaction product and a hydroisomerization cracking reaction product are respectively separated and fractionated to obtain distillate oil and tail oil products with different specifications. The invention provides the process for simultaneously producing more than two types of light naphtha, heavy naphtha, aviation kerosene, diesel oil and tail oil products with different specifications on a set of hydrogenation process equipment. In the process, heat carried by part of cracked materials can be fully utilized, and coupling operation of the single-stage two-catalyst hydrocracking reactor and the hydroisomerization cracking reactor is achieved.

Description

technical field [0001] The invention belongs to the field of petroleum refining, and in particular relates to a single-stage two-dose hydrocracking process for flexibly producing high-quality naphtha, jet fuel, diesel oil and tail oil products of different properties. Background technique [0002] Hydrogenation technology is an important processing method for lightening heavy oil and upgrading the quality of light oil. Hydrocracking technology has developed rapidly due to the advantages of strong feed oil adaptability, good product flexibility, high liquid product yield, and high product quality. The existing hydrocracking technology can be divided into three types according to the processing flow: one-stage series hydrocracking process, single-stage hydrocracking process and two-stage hydrocracking process. According to whether the tail oil is recycled or not, it can be divided into three types: one-way one-pass process, partial cycle process and full cycle process. Among...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G67/00
CPCC10G67/00C10G2300/1037C10G2300/70C10G2400/04
Inventor 刘涛赵玉琢张学辉刘野李宝忠孙洪江
Owner CHINA PETROLEUM & CHEM CORP
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