A kind of ferrite modified carbon fiber cloth electrode and its preparation method and application
A carbon fiber cloth, modification and modification technology, applied in chemical instruments and methods, oxidized water/sewage treatment, water/sewage treatment equipment, etc., can solve the problems of low POPs concentration and limited removal
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Embodiment 1
[0102]Example 1 Preparation of ferrite modified carbon fiber cloth electrochemical cathode
[0103]1) Cut the original carbon fiber cloth into a 3.5cm diameter circle, and use a mixture of 10% nitric acid and 10% sulfuric acid solution (nitric acid: sulfuric acid volume ratio 3:1) to perform Soak, after 30 minutes of ultrasonic treatment, react for 48 hours in a thermostat at 50°C. After the solution is cooled, wash it with ultrapure water several times to remove surface residues and impurities until the pH of the washing solution is neutral, and then at 40 Fully dry it in a vacuum oven at ℃ until it reaches a constant quality, then the modified carbon fiber cloth is obtained;
[0104]2) Arrange the above modified carbon fiber to soak in ultrapure water, then add 0.4mol / L Fe(NO3)3·9H2O and 0.2mol / L Cu(NO3)2·3H2O, ultrasonic for 1 hour to mix uniformly and completely dissolve to obtain a mixed solution, and add ammonium fluoride and urea to it, continue to stir, and then place it in a cons...
Embodiment 2
[0105]Example 2 Preparation of ferrite modified carbon fiber cloth electrochemical cathode
[0106]1) Cut the original carbon fiber cloth into a 3.5cm diameter circle and take 1.5mL 30wt% H2O2And 97mL ultrapure water in a 250mL Erlenmeyer flask, and adjust the pH to 3, then add 1.5mL 0.2mol / L Fe2+Solution (may be ferrous sulfate or ferric chloride solution), soak the carbon cloth, after 30 minutes of ultrasonic treatment, react for 48 hours in a thermostat at 50°C, and wash with ultrapure water after the solution is cooled Several times, remove the surface residues and impurities until the pH of the washing solution is neutral, and then fully dry it in a vacuum oven at 40°C until it reaches a constant quality to obtain a modified carbon fiber cloth;
[0107]2) Arrange the above modified carbon fiber to soak in ultrapure water, then add 0.4mol / L Fe(NO3)3·9H2O and 0.2mol / L Cu(NO3)2·3H2O, ultrasonic for 1 hour to mix uniformly and completely dissolve to obtain a mixed solution, and add ammon...
Embodiment 3
[0109]The difference from Example 1 is that the mixture of 10% nitric acid and 10% sulfuric acid solution (volume ratio of nitric acid: sulfuric acid is 3:1) is replaced with 0.3mol / L hypochlorous acid , Others are the same as in Example 1.
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