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A 3D printer of continuous fiber reinforced composite material and its printing method

A technology for enhancing composite materials and 3D printers, applied in the field of printers, can solve problems such as performance index requirements, microstructure defects, complex processes, etc., and achieve the effect of improving comprehensive performance, improving mechanical properties, and excellent comprehensive performance.

Active Publication Date: 2021-07-09
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the products of 3D printers have poor mechanical properties such as strength and stiffness, and cannot be used in the engineering field very well. It is necessary to use fillers to enhance the modified composite materials.
Invention patent (patent number 2015107817291, named as a reinforced PLA material for 3D printing) discloses that 3D printing materials use chopped carbon fiber to reinforce PLA, and invention patent (patent number 2018109685159, named lignin / microcrystalline cellulose Composite, reinforced polylactic acid 3D printing material and its preparation method), all short fibers or powders are chemically pretreated first, and then the reinforced polylactic acid 3D printing material is prepared by melt extrusion blending and wire drawing molding, these The orientation distribution of the filler has a large randomness, and the filler is prone to agglomeration and uneven dispersion during the blending process, resulting in defects in its microstructure and resulting in mechanical properties that are far from the expected performance indicators.
But this production method has the following disadvantages: (1) The steps are cumbersome, and the silk material needs to be pre-soaked in the photocurable resin before production, and crosslinking reaction occurs under ultraviolet light irradiation, the production efficiency is low, and the process is complicated; The cost of cured resin is high, the bonding strength with the plastic matrix interface is low, and it is easy to peel off (3) Light-cured resins often have certain corrosiveness and toxicity, and there is dissolution of mercury, silver, copper, and zinc, and organic volatilization occurs during the crosslinking reaction. points, not enough energy saving and environmental protection
But this kind of printer head structure has the following disadvantages: (1) The fiber filaments are located at the outer end of the feeding pipe, only half of the fibers can be wrapped by the resin, and it is impossible to ensure that the fiber filaments are completely infiltrated by the molten resin, resulting in the bonding strength of the fiber-resin matrix interface. Low, easy to peel off; (2) Fibers that are not infiltrated by resin cannot be bonded to the cooled upper layer of resin material, resulting in low interlayer bonding strength of printed parts and poor mechanical properties of parts; (3) The printing nozzle must control the movement of the wire feeding tube at any time to ensure that the fiber is under the molten resin, otherwise it cannot play the role of covering the fiber, but the angle control of the wire feeding tube is very difficult, and it is impossible to control the wire feeding tube flexibly and accurately The rotation angle will inevitably limit the shape of the printed part, so it is impossible to print a 3D model with complex shapes

Method used

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  • A 3D printer of continuous fiber reinforced composite material and its printing method

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Experimental program
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Effect test

Embodiment 1

[0034] When the continuous fiber of the core layer is a soft ultrafine metal wire, such as an ultrafine stainless steel wire, the diameter is 0.016-0.07mm; the silk material is selected from a soft printing wire, and in this embodiment, X60 resin from Diabase Engineering Company is selected. It has strong toughness, excellent tensile strength and wear resistance, and its elongation at break exceeds 7 times itself. The printing method of the present invention can make the molten X60 resin fully infiltrate and wrap the ultra-fine stainless steel wire, and continuously extrude through the nozzle to print out a composite material whose core layer is reinforced by continuous ultra-fine stainless steel wire. Printed by this method 3D model parts, using the special rigidity and variable bending characteristics of metal filaments, combined with a plastic substrate with good toughness, makes the printed parts have a special variable shape memory wrinkle effect, and has anti-magnetic, an...

Embodiment 2

[0036] When PLA is used as the plastic filament, the printed parts are fragile and easy to break. In the past, PLA printed parts can only be used for model display, but cannot be used, which greatly limits its application field. In order to better improve and enhance the toughness of printed parts, continuous aramid fibers can be used as reinforcing fibers. In this embodiment, DuPont’s Kevlar fibers are selected, with a diameter of 0.2mm. The continuous fibers have low density, high tensile strength Tensile strength, high modulus of elasticity characteristics. Through the printing method of the present invention, the molten PLA filament can be fully soaked into the aramid fiber, and continuously extruded through the nozzle, and the PLA composite material whose core layer is reinforced by continuous aramid fiber can be printed out. The 3D model printed by this method Parts, through the use of the high tensile strength characteristics of the core aramid fiber, can play a good ro...

Embodiment 3

[0038] When the continuous fiber of the core layer is made of inorganic non-metallic wire, such as carbon fiber, glass fiber, basalt fiber, etc., although the continuous fiber has high strength, it is brittle and easy to break when the fiber length is too long. Therefore, the previous reinforcement methods often Reinforced with short fibers, the effect of short fiber reinforcement is not as good as that of long fibers. Nylon 3D printing material has good toughness, but compared with ABS, nylon is not hard enough to meet the rigidity requirements of parts. Through the printer nozzle structure of the present invention, the nylon 3D printing filament with good toughness can be used as the plastic filament, so that the molten nylon plastic can fully infiltrate and wrap the inorganic continuous fiber, and continuously extrude through the nozzle to print out the core layer as a continuous inorganic fiber. Fiber-reinforced nylon-based composite materials, 3D model parts printed by th...

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Abstract

The invention discloses a 3D printer of a continuous fiber reinforced composite material and a printing method thereof, comprising a heating block, a heating element is arranged in the heating block; a first channel, a second branch channel, and a third branch channel are opened in the heating block, The first channel, the second branch channel, and the third branch channel are arranged in a Y shape, the first channel is provided with a nozzle, the second branch channel, and the third branch channel are respectively connected with throat pipes, and each throat pipe is connected with a cooling pipe, The push-in connector has a channel in the heating block, the channel is located between the second branch channel and the third branch channel, the channel communicates with the first channel, and also includes a feeding device for feeding the wire into the quick-plug connector. The orientation of the continuous fiber in the composite material is controllable through the conduit, the channel, and the first channel, and the comprehensive performance of the 3D printed part is effectively improved.

Description

technical field [0001] The invention belongs to the technical field of printers, relates to a 3D printer of continuous fiber reinforced composite materials, and also relates to a printing method of the 3D printer. Background technique [0002] 3D printers are based on extruding raw materials, using 3D design software to print a 3D model of the drawn product. 3D printing technology is a kind of additive manufacturing technology, which has the advantages of low manufacturing cost and short production cycle. At present, the products of 3D printers have poor mechanical properties such as strength and stiffness, and cannot be used in the engineering field very well. Fillers need to be used to reinforce the modified composite materials. Invention patent (patent number 2015107817291, named as a reinforced PLA material for 3D printing) discloses that 3D printing materials use chopped carbon fiber to reinforce PLA, and invention patent (patent number 2018109685159, named lignin / micr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C64/118B29C64/295B29C64/314B29C64/336B33Y30/00B33Y40/00B33Y40/10
CPCB33Y30/00B33Y40/00B29C64/118B29C64/295B29C64/336
Inventor 于旻乔宇杰葛正浩孙立新
Owner SHAANXI UNIV OF SCI & TECH