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Environmentally friendly adhesive for plywood with ultra-high solid content, preparation method and application thereof

An ultra-high solid content, plywood technology, applied in the direction of polymer adhesive additives, non-polymer adhesive additives, adhesives, etc. The effect of improving the bond strength

Active Publication Date: 2021-05-07
NANJING FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The adhesive utilizes the catalytic effect of ammonium dihydrogen phosphate on the caramelization of sucrose to form a low-molecular-weight prepolymer with a solid content of 70.6-85.6%. content defects, improve heat curing rate and bond strength

Method used

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  • Environmentally friendly adhesive for plywood with ultra-high solid content, preparation method and application thereof
  • Environmentally friendly adhesive for plywood with ultra-high solid content, preparation method and application thereof
  • Environmentally friendly adhesive for plywood with ultra-high solid content, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] An environmentally friendly adhesive for plywood with ultra-high solid content, its components are composed of the following components by weight ratio:

[0024]

[0025] Adhesive preparation process:

[0026] Weigh the corresponding raw material components in parts by weight. When preparing the adhesive, first mix sucrose, citric acid and water, and react at 90°C for 1 hour under low-speed stirring conditions, and then add ammonium dihydrogen phosphate and sodium sulfite to the mixture. In the reaction system, react at 100°C for 1 hour under low-speed stirring conditions, then add sodium sulfite to the reaction system, react at 90°C for 0.5 hours under high-speed stirring conditions, and finally close the reaction kettle, and wait until the temperature of the reaction system drops to room temperature Add polyacrylamide to the solution, and stir at low speed for 0.2 hours.

[0027] The solid content of the prepared adhesive is 85.6%.

[0028] Described water is dis...

Embodiment 2

[0032] An environmentally friendly adhesive for plywood with ultra-high solid content, its components are composed of the following components by weight ratio:

[0033]

[0034] Adhesive preparation process:

[0035] Weigh the corresponding raw material components in parts by weight. When preparing the adhesive, first mix sucrose, citric acid and water, and react for 1.5 hours at 80°C under low-speed stirring conditions, and then add ammonium dihydrogen phosphate and sodium sulfite to the mixture. In the reaction system, react at 90°C for 2 hours under low-speed stirring conditions, then add sodium sulfite to the reaction system, react at 80°C for 1 hour under high-speed stirring conditions, and finally close the reaction kettle until the temperature of the reaction system drops to room temperature Add polyacrylamide to the solution and stir at low speed for 0.5 hours.

[0036] The solid content of the prepared adhesive is 77.2%.

[0037] Described water is distilled wate...

Embodiment 3

[0041] An environmentally friendly adhesive for plywood with ultra-high solid content, its components are composed of the following components by weight ratio:

[0042]

[0043] Adhesive preparation process:

[0044] Weigh the corresponding raw material components in parts by weight. When preparing the adhesive, first mix sucrose, citric acid and water, and react at 85°C for 1 hour under low-speed stirring conditions, and then add ammonium dihydrogen phosphate and sodium sulfite to the mixture. In the reaction system, react at 95°C for 3 hours under low-speed stirring conditions, then add sodium sulfite to the reaction system, react at 85°C for 1 hour under high-speed stirring conditions, and finally close the reaction kettle until the temperature of the reaction system drops to room temperature Add polyacrylamide to the solution and stir at low speed for 0.3 hours.

[0045] The solid content of the prepared adhesive is 70.6%.

[0046] Described water is distilled water. ...

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Abstract

The invention discloses an environment-friendly adhesive for plywood with ultra-high solid content, and its components include the following components by weight percentage: 100 parts of sucrose, 20-40 parts of ammonium dihydrogen phosphate, 3-4 parts of sodium sulfite, polyacrylamide 2-3 parts, 0.05-2 parts of citric acid, 25-63 parts of water; the solid content of the environmental-friendly adhesive for plywood is 70.6-85.6%. It also discloses its preparation method, its application in the preparation of plywood, and the prepared plywood. The adhesive provided by the present invention uses ammonium dihydrogen phosphate to catalyze the hydrolysis and caramelization of sucrose during the synthesis process to form a low molecular weight prepolymer, and uses the Maillard reaction to produce a chemical crosslinking reaction during the curing process. The viscosity of the adhesive is moderate, and the solid content can reach 70.6-85.6%, which improves the defect that the traditional natural adhesive for plywood cannot increase the solid content due to excessive viscosity, and improves the thermal curing rate and bonding strength.

Description

technical field [0001] The invention relates to an environment-friendly adhesive for plywood with ultra-high solid content, a preparation method and application thereof. Background technique [0002] Synthetic resin adhesives pollute the environment and oil resources are gradually scarce. The development of environmentally friendly adhesives based on renewable raw materials has become an important research method; traditional natural adhesives for plywood are mostly modified with soybean protein isolate or starch. The adhesive has low solid content and high viscosity, and there are problems such as spraying water and smearing during application, which is inconvenient to use. Therefore, it is of great practical significance to develop natural adhesives with ultra-high solid content and low viscosity. Contents of the invention [0003] The purpose of the present invention is to provide an environmentally friendly adhesive for plywood with ultra-high solid content. The adhes...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J105/00C09J11/06C09J11/08B27D1/08B27D1/04
CPCB27D1/04B27D1/08C09J11/06C09J11/08C09J105/00C08L33/26C08K5/092
Inventor 赵中元孙世静
Owner NANJING FORESTRY UNIV