According to the controllable negative Poisson's ratio structure friction nano-generator and the preparation method thereof, a controllable negative Poisson's ratio
polyurethane skeleton is prepared through a 3D printing technology, and a
polytetrafluoroethylene negative friction shell skeleton is cured on the surface of the negative Poisson's ratio
polyurethane skeleton through a layer-by-layer
assembly accumulation strategy; meanwhile, the natural collagen aggregate foam with the positive Poisson ratio serves as a positive friction layer to be embedded into the shell, and a synergistically compressed core-shell structure is formed. Under the action of external force, the negative Poisson's ratio shell layer shrinks transversely and the positive Poisson's ratio core layer expands longitudinally by utilizing the synergistic effect between the negative Poisson's ratio
polyurethane skeleton and the positive Poisson's ratio natural collagen aggregate, and the negative Poisson's ratio shell layer and the positive Poisson's ratio core layer generate a synergistic compression effect due to Poisson's ratio characteristic difference. And the contact area of a friction interface is obviously increased, and the
mechanical energy absorption efficiency is improved, so that the interface
charge separation effect is optimized. The friction nanometer generator has
high energy conversion efficiency and good flexibility and adaptability, and is suitable for
mechanical energy collection and self-power supply application in intelligent
medical treatment, sports protection equipment and flexible wearable equipment.