Mannitol eutectic auxiliary material and its preparation method and application
A technology of mannitol and mannitol complex is applied in the complex of mannitol and calcium chloride and the field of preparation thereof, and can solve the problems of low hygroscopicity and compressibility, mannitol compressibility and strong hygroscopicity of calcium chloride.
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Embodiment 1
[0076] Embodiment 1: the preparation of mannitol calcium chloride co-crystal
[0077] Add 1.82g of mannitol and 1.11g of anhydrous calcium chloride into 10mL of water, dissolve at room temperature to obtain a clear solution, evaporate the solvent at 80°C to obtain a crystal product after 7 days, filter it with suction, and dry it in vacuum at 25°C for 12 hours to obtain manna Alcohol Calcium Chloride Eutectic.
[0078] The obtained mannitol calcium chloride cocrystal is characterized by powder X-ray diffraction, infrared spectroscopy and differential scanning calorimetry (DSC), and the powder-ray diffraction analysis results are shown in the appendix figure 2 , see the results of infrared analysis image 3 , the results of differential scanning calorimetry analysis are shown in the appendix Figure 4 .
Embodiment 2
[0079] Embodiment 2: the preparation of mannitol calcium chloride co-crystal
[0080] Add 1.82g of mannitol and 1.11g of anhydrous calcium chloride into 20mL of 80% ethanol, heat and dissolve at 60°C to obtain a clear solution, evaporate the solvent at 40°C to obtain a crystal product after 3 days, filter it with suction, and dry it under vacuum at 25°C After 12 hours, the mannitol calcium chloride co-crystal was obtained.
Embodiment 3
[0081] Embodiment 3: the preparation of mannitol calcium chloride co-crystal
[0082] Add 18.24g of mannitol and 11.11g of anhydrous calcium chloride into 20mL of water, dissolve to obtain a clear solution, add 200mL of ethanol to the clear solution under stirring, continue to stir to obtain a white solid product, filter it with suction, and dry it in vacuum at 25°C for 12h to obtain manna Alcohol Calcium Chloride Eutectic.
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Abstract
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