Energy absorption method and application thereof
A hydrogen bonding, dynamic technology used in the field of energy absorption
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[0250] The preparation method of a kind of dynamic polymer ionic liquid gel of the present invention comprises the following steps: adding the raw material for preparing the dynamic polymer into the ionic liquid so that the mass fraction of the prepared dynamic polymer is 0.3-75%. Said appropriate means carry out covalent cross-linking, and after the reaction is finished, a dynamic polymer ionic liquid gel is produced. Another preparation method of dynamic polymer ionic liquid gel of the present invention comprises the following steps: swelling the dynamic polymer in a solvent containing ionic liquid so that the mass fraction of the prepared dynamic polymer is 0.3-75%, After fully swelling, the solvent is removed to form a dynamic polymer ionic liquid gel. The ionic liquid is generally composed of organic cations and inorganic anions. As an example, the cations are selected from the group including but not limited to alkyl quaternary ammonium ions, alkyl quaternary azolium ion...
Embodiment 1
[0258] Add 15 molar equivalents of 1,6-hexanedithiol into a dry and clean flask, then add an appropriate amount of THF solvent, stir to dissolve, add an appropriate amount of dibenzoyl peroxide, and an appropriate amount of catalyst sodium iodide, stir well After mixing, reflux reaction at 70° C. for 2 hours, after purification and drying, the dynamic polymer with linear structure was obtained. The material can be used as an interlayer adhesive for lamination between woods, and it can absorb external impact energy while also having certain self-healing properties.
Embodiment 2
[0260] Take a dry and clean reaction bottle, add 10 molar equivalents of 1,2,7,8-dioxoctane, 2.5 molar equivalents of N,N-di(2-hydroxyethyl)-N′-propyl- Urine, 7 molar equivalents of 2,2'-dithiodiethanol, and then add an appropriate amount of dichloromethane to stir and dissolve, and use potassium hydroxide as a catalyst to heat and react to obtain an epoxy-terminated prepolymer. The material can be used as an adhesive for electronic packaging, can absorb and disperse external impact energy, and has certain self-healing properties.
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