Production method of disperse dye blue B56#
A production method and technology for dispersing blue, applied in anthracene dyes, organic dyes, chemical instruments and methods, etc., can solve the problems of raw material waste, environmental pollution, waste of raw materials, etc., and achieve the effect of reducing the discharge of three wastes
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Embodiment 1
[0021] A kind of production method of dye disperse blue B56#, by utilizing sodium sulfite to treat 1-aminoanthraquinone DMF residue to purify and produce mixed nitrate, then the mixed nitrate is sequentially passed through mononitration, mononitration refining, condensation, dinitration, hydrolysis, reduction and In the process of bromination transformation, the product disperse blue B56# is finally obtained; the mother liquor recovered by hydrolysis is reprocessed to recover the by-product 2,4-dinitrophenol.
[0022] The reprocessing of the recovered mother liquor by hydrolysis specifically includes the following steps:
[0023] (1) adding the mother liquor recovered by hydrolysis into the refining kettle, slowly adding mass fraction of 98% sulfuric acid at room temperature to adjust the solution to a pH value of 5, the amount of sulfuric acid is 45% of the quality of the mother liquor recovered by hydrolysis; then adjust the reaction temperature to 65°C, The reaction time is...
Embodiment 2
[0029] A kind of production method of dye disperse blue B56#, by utilizing sodium sulfite to treat 1-aminoanthraquinone DMF residue to purify and produce mixed nitrate, then the mixed nitrate is sequentially passed through mononitration, mononitration refining, condensation, dinitration, hydrolysis, reduction and In the process of bromination transformation, the product disperse blue B56# is finally obtained; the mother liquor recovered by hydrolysis is reprocessed to recover the by-product 2,4-dinitrophenol.
[0030] The reprocessing of the recovered mother liquor by hydrolysis specifically includes the following steps:
[0031] (1) adding the reclaimed mother liquor by hydrolysis to the refining kettle, slowly adding mass fraction of 90% sulfuric acid at room temperature to adjust the solution to a pH value of 7, the amount of sulfuric acid is 50% of the quality of the reclaimed mother liquor by hydrolysis; then adjust the reaction temperature to 60°C, The reaction time is 0...
Embodiment 3
[0035] A kind of production method of dye disperse blue B56#, by utilizing sodium sulfite to treat 1-aminoanthraquinone DMF residue to purify and produce mixed nitrate, then the mixed nitrate is sequentially passed through mononitration, mononitration refining, condensation, dinitration, hydrolysis, reduction and In the process of bromination transformation, the product disperse blue B56# is finally obtained; the mother liquor recovered by hydrolysis is reprocessed to recover the by-product 2,4-dinitrophenol.
[0036] The reprocessing of the recovered mother liquor by hydrolysis specifically includes the following steps:
[0037] (1) adding the mother liquor recovered by hydrolysis to the refining kettle, slowly adding mass fraction of 95% sulfuric acid at room temperature to adjust the solution to a pH value of 5, the amount of sulfuric acid is 45% of the quality of the mother liquor recovered by hydrolysis; then adjust the reaction temperature to 70°C, The reaction time is 1...
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