A low carbon number light color sulfur-free chlorine-free ash-free polymerization inhibitor and its application
A technology of polymerization inhibitor and carbon number, which is applied in the field of low-carbon number, light-colored, sulfur-free, chlorine-free, ash-free polymerization inhibitors, can solve the problems of few reports, achieve the effect of reducing scaling and coking substances, and protecting human health
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[0058] The present invention does not specifically limit the preparation method of the polymerization inhibitor, which can be prepared by a mixing method.
[0059] The second aspect of the present invention provides an application of the above-mentioned low-carbon number, light-colored, sulfur-free, chlorine-free, and ashless polymerization inhibitor for the high-temperature distillation and separation process of light mixed oil.
[0060] The light mixed oil of the present invention is a mixture of gasoline and diesel. The high-temperature distillation of the present invention is the distillation and separation of light mixed oil under the condition of normal pressure and ≤250°C.
Embodiment 1
[0064] This example provides a polymerization inhibitor. The preparation raw materials of the polymerization inhibitor include, in parts by weight, 15 parts of diphenylamine derivatives, 30 parts of p-phenylenediamine derivatives, 15 parts of succinimide and 30 parts of carbon Nine aromatic hydrocarbons; the diphenylamine derivative is 4-hydroxydiphenylamine, and the succinimide is N-methylsuccinimide;
[0065] The structural formula of the p-phenylenediamine derivative is shown in formula (1):
[0066]
[0067] R 1 , R 2 Both are sec-butyl groups.
[0068] The N-methylsuccinimide was purchased from Nanjing Kangmanlin Chemical Industry Co., Ltd.
[0069] This example also provides the above-mentioned preparation method of the polymerization inhibitor, which includes the following steps: mixing the preparation raw materials of the polymerization inhibitor to obtain the polymerization inhibitor.
Embodiment 2
[0071] This example provides a polymerization inhibitor. The preparation raw materials of the polymerization inhibitor include, in parts by weight, 25 parts of diphenylamine derivatives, 40 parts of p-phenylenediamine derivatives, 20 parts of succinimide and 35 parts of carbon Nine aromatic hydrocarbons; the diphenylamine derivative is 4-hydroxydiphenylamine, and the succinimide is N-ethylsuccinimide;
[0072] The structural formula of the p-phenylenediamine derivative is shown in formula (1):
[0073]
[0074] R 1 , R 2 Both are sec-butyl groups.
[0075] The N-ethylsuccinimide was purchased from Nanjing Kangmanlin Chemical Industry Co., Ltd.
[0076] This example also provides the above-mentioned preparation method of the polymerization inhibitor, which includes the following steps: mixing the preparation raw materials of the polymerization inhibitor to obtain the polymerization inhibitor.
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