Functional degradable material with controllable degradation period and preparation method thereof

A technology for degrading materials and degradation cycles, applied in the field of functional degradable materials and their preparation, can solve the problems of difficult to control degradation time, deviation of material mechanical properties, and insufficient degradation, achieve good stiffness and mechanical properties, and improve friction. Condition, easy demoulding effect

Pending Publication Date: 2021-01-01
GUANGDONG GUOLI SCI & TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] However, the degradation time of these materials is difficult to control. When these degradable materials are used in agricultural production, it is difficult to meet the needs of agricultural production. At present, there are related researches on adding inorganic additives during the preparation of biodegradable materials to achieve the effect of controllable degradation time. , but due to the excessive amount of inorganic additives, the deviation of the mechanical properties of the material and the problem of insufficient degradation

Method used

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  • Functional degradable material with controllable degradation period and preparation method thereof

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preparation example Construction

[0070] In one embodiment, the modified starch preparation method comprises the following steps:

[0071] (1) drying the starch at 80-110°C for 3-5h;

[0072] (2) Add the dried starch and maleic anhydride of step (1) into the reaction kettle by weighing the corresponding weight, and after reacting at 60-90°C for 0.5-3h, take out the reacted product;

[0073] (3) washing the reaction product obtained in step (2) with ethanol for 4-6 times, then suction filtering, and finally placing the filter cake in an oven, drying at 70-90° C. for 12-18 hours to obtain modified starch.

[0074] The modified starch weakens the hydrogen bond between the starch molecules, improves the thermoplasticity of the modified starch and can improve the hydrophobicity of the starch material to a certain extent, and the modified starch is more easily combined with the polymer in the system of the present invention. Combined, the amount of compatibilizer is reduced at the same time, so that the performance...

Embodiment 1

[0091] Embodiment 1 of the present invention specifically provides a functional degradable material with a controllable degradation period. The raw materials include, in parts by weight, 40 parts of polybutylene terephthalate, 6 parts of carbon dioxide copolymer, polybutylene 25 parts of butylene glycol ester, 4 parts of compatibilizer, 0.35 part of lubricant, 4 parts of plasticizer, and 0.2 part of antioxidant.

[0092] The raw material of the functional degradable material with a controllable degradation period also includes a mixture of modified starch, polyglycolic acid and polydioxanone.

[0093] The weight ratio of the modified starch to polybutylene succinate is 0.8:1.

[0094] The addition amount of the mixture of polyglycolic acid and polydioxanone is 4% of the total weight of the raw materials of the functional degradable material with a controllable degradation cycle.

[0095] The weight ratio of polyglycolic acid to polydioxanone is 12:2.

[0096] The polybutylen...

Embodiment 2

[0121] Embodiment 2 of the present invention specifically provides a functional degradable material with a controllable degradation period. The weight ratio of polybutylene succinate is 0.7:1, and the weight ratio of polyglycolic acid and polydioxanone is 10:2.

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Abstract

The invention relates to a degradable material, in particular to a functional degradable material with a controllable degradation period and a preparation method thereof. The functional degradable material with the controllable degradation period is prepared from the following raw materials in parts by weight: 30-50 parts of polybutylene terephthalate, 58 parts of a carbon dioxide copolymer, 10-40parts of polybutylene succinate, 3-5 parts of a compatilizer, 0.2-0.5 part of a lubricant, 3-5 parts of a plasticizer and 0.2-0.5 part of an antioxidant. Raw materials of the functional degradable material with the controllable degradation period further comprise a mixture of modified starch, polyglycolic acid and poly (p-dioxocyclohexanone). By controlling the ratio of the modified starch to thepoly (butylene succinate), the ratio of the mixture of the polyglycolic acid and the poly (p-dioxanone) and the addition amount of the antioxidant, the full-biodegradable material with different degradation periods can be prepared under the composting conditions of the same temperature, humidity, pH value, flora and the like; the material is suitable for products with different degradation periods.

Description

technical field [0001] The invention relates to a degradable material, in particular to a functional degradable material with a controllable degradation cycle and a preparation method thereof. Background technique [0002] In recent years, in the field of environmental protection, the problem of solving the pollution caused by "white garbage" to the ecological environment has attracted much attention. Among them, an effective way to solve this problem is to develop biodegradable materials. Biodegradable materials refer to the natural environment such as soil and / or under conditions such as sandy soil, and / or under specific conditions such as composting conditions or anaerobic digestion conditions or in water-based culture fluid, the degradation is caused by the action of microorganisms existing in nature, and finally completely degraded into carbon dioxide (CO 2 ) or / and methane (CH 4 ), water (H 2 O) and the mineralized inorganic salts of its elements and new biomass ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L69/00C08L67/04C08L3/06C08L23/08C08K5/20C08K5/11C08K5/134
CPCC08L67/02C08L2201/06C08L2205/025C08L2205/035C08L2205/08C08L69/00C08L3/06C08L67/04C08L23/0869C08K5/20C08K5/11C08K5/1345
Inventor 乔志龙甘舸文胜
Owner GUANGDONG GUOLI SCI & TECH CO LTD
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