Quantum dot color filter ink compositions and devices utilizing same
A technology of quantum dots and compositions, applied in inks, instruments, applications, etc., can solve problems such as EQE reduction, spectral red shift, and damage to display viewing angles
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Embodiment 1
[0058] Example 1: Ink compositions containing perylene dyes and films formed therefrom.
[0059] To illustrate the improvement that can be achieved by including a light absorbing material in the red subpixel, two QDCF ink compositions were formulated: Ink A and Ink B. Ink A as a reference is an ultraviolet (UV) curable ink containing red light emitting quantum dots. The composition of Ink B is similar to that of Ink A, but contains 1% by weight of perylene derivative dye Lumogen F Yellow083 as a blue light absorbing material.
[0060] Quantum dots: Red luminescent quantum dots are InP / ZnS quantum dots functionalized with hydrophilic ligands from Nanosys.
[0061] Luminescent material: Lumogen F Yellow 083 was purchased from BASF. Lumogen F Yellow 083 has absorption in the blue wavelength region of the visible spectrum, and the maximum absorption in dichloromethane is about 476nm. The dye has multiple emission peaks with a peak maximum at 496 nm in dichloromethane.
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Embodiment 2
[0076] Example 2: Ink compositions containing coumarin dyes and films formed therefrom.
[0077] To illustrate the improvements that can be achieved by including light-absorbing materials in the green subpixel, four QDCF ink compositions were formulated. Ink A2, Ink B2, Ink C2, and Ink D2. Ink A2 as a reference is a UV curable ink containing green luminescent quantum dots. Inks B2, C2, and D2 had a similar composition to ink A, but contained 0.15% to 0.24% by weight of coumarin as a blue light absorbing material.
[0078] Quantum dots: Green luminescent quantum dots were purchased from Nanosys.
[0079] Blue light-absorbing materials: Coumarin 334, Coumarin 314, and Coumarin 6 were purchased from Sigma Aldrich and used in B2, C2, and D2 ink compositions, respectively. Coumarin absorbs in the blue wavelength region of the visible spectrum, with an absorption maximum in the wavelength range from 430 nm to 460 nm.
[0080] Table 2 shows the formulations of ink compositions A2...
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