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Noble metal quantum dots modified multilayer nanocomposite film gas sensor preparation method

A gas sensor and nanocomposite technology, which is applied in the fields of nanotechnology, nanotechnology, nanotechnology for materials and surface science, etc. Reduce costs and other issues to achieve the effects of reduced size, high consistency, and reduced costs

Active Publication Date: 2022-04-22
XI AN JIAOTONG UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In order to solve the above-mentioned defects in the prior art, the object of the present invention is to provide a gas sensor based on noble metal quantum dots modified multi-layer nanocomposite film and its preparation method. The prepared sensor has a simple structure and is easy to package; the structure is miniaturized and the power consumption is low; the preparation process is streamlined, with high sensitivity and meeting the requirements of wafer-level production, which greatly reduces the cost; the sputtering method is used to prepare multiple sensors. Layered nanocomposite film and quantum dots, the gas-sensitive film formed by the two has high consistency

Method used

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  • Noble metal quantum dots modified multilayer nanocomposite film gas sensor preparation method

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preparation example Construction

[0049] The preparation method of the gas sensor based on the noble metal quantum dot modified multi-layer nanocomposite film of the present invention is given below, such as image 3 shown, including the following steps:

[0050] 1) Select a silicon wafer substrate that has undergone double-sided thermal oxidation and nitriding treatment, as shown in Figure 4(c); the selected silicon wafer is an N-type doped silicon wafer;

[0051] 2) Apply EPG535 photoresist evenly to the selected silicon wafer substrate at a low speed of 500r / min for 6s and a high speed of 1500r / min for 40s, see Figure 4(d);

[0052] 3) Dry the silicon wafer coated with photoresist at 80°C-100°C for 5min-10min, and expose for 7s-9s to obtain the sensitive material pattern;

[0053] 4) Use alkaline solution to develop the silicon wafer etched with sensitive material pattern for 17s-25s, dry it with nitrogen gas and dry it at 100°C-120°C for 10min-20min; the concentration of alkaline solution is 5‰NaOH, (5‰ ...

Embodiment 1

[0069] 1) Select a silicon wafer with N-type doping, crystal orientation 100, resistance 1-5ohm.cm, thickness 400um, and then thermally oxidize both sides to form an oxide layer with a thickness of 500nm, and deposit Si on both sides by LPCVD 3 N 4 , the thickness of the formed desalination layer is 150nm;

[0070] 2) Apply EPG535 photoresist evenly to the substrate of the silicon wafer with the desalinated layer after the double-sided oxide layer at a low speed of 500r / min for 6s, and at a high speed of 1500r / min for 40s;

[0071] 3) Bake the silicon wafer evenly covered with photoresist at 95°C for 5 minutes, and then expose the photoresist for 7 seconds with the designed sensitive material mask to obtain the designed sensitive material pattern;

[0072] 4) Place the exposed silicon wafer in a 5‰ NaOH solution for 20 seconds, dry it with nitrogen, and bake it at 110°C for 10 minutes;

[0073] 5) Put the silicon wafer obtained in step 4) into the sputtering machine for fron...

Embodiment 2

[0084] 1) Select a silicon wafer with N-type doping, crystal orientation 100, resistance 1-5ohm.cm, thickness 400um, and then thermally oxidize both sides to form an oxide layer with a thickness of 500nm, and deposit Si on both sides by LPCVD 3 N 4 , the thickness of the formed desalination layer is 150nm;

[0085] 2) Apply EPG535 photoresist evenly to the substrate of the silicon wafer with the desalinated layer after the double-sided oxide layer at a low speed of 500r / min for 6s, and at a high speed of 1500r / min for 40s;

[0086] 3) Bake the silicon wafer evenly covered with photoresist at 80°C for 8 minutes, and then expose the photoresist for 9 seconds with the designed sensitive material mask to obtain the designed sensitive material pattern;

[0087] 4) Place the exposed silicon wafer in a 5‰KOH solution for 17s, dry it with nitrogen, and bake it at 120°C for 15min;

[0088] 5) Put the silicon wafer obtained in step 4) into the sputtering machine for front-side sputter...

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Abstract

The invention discloses a preparation method of a multi-layer nano composite film gas sensor modified by noble metal quantum dots. The double-sided oxide and silicon nitride wafer is used as a substrate, and the multi-layer nano composite film modified by noble metal quantum dots is used as a gas sensing material. The sputtering method is deposited on the silicon wafer substrate, and the test electrode and the test electrode are arranged centrally above the front surface of the silicon nitride layer. The test electrode of the comb-tooth-pronged composite structure is arranged above the sensitive material; the heating wire is in the shape of scissors on the test electrode. The periphery is surrounded by two layers, the lead-out end of the comb-tooth-shaped composite test electrode is set at the scissors mouth of the heating wire, and the heating wire and the test electrode are respectively connected to a pair of symmetrically distributed lead discs. The invention adopts the sputtering method to prepare the multi-layer nano-composite film and the quantum dots, the sensor structure is simple, easy to encapsulate, the structure is miniaturized, and the power consumption is low; The process is streamlined, which combines high sensitivity and meets the production requirements of wafer-level gas sensors.

Description

technical field [0001] The invention relates to MEMS (Micro-Electro-Mechanic System) processing technology, in particular to a method for preparing a gas sensor based on noble metal quantum dot-modified multilayer nanocomposite films. Background technique [0002] Atmospheric pollution has become a common problem faced by human beings. It is urgent to monitor air pollution and take measures to improve air quality and maintain the cleanness of the atmospheric environment on which we live. As the most direct means of detecting gases, gas sensors are widely used in the detection of air pollution, flammable, explosive, toxic and harmful gases. With the development of science and technology, thin-film metal oxide gas sensors based on MEMS technology have become the mainstream gas sensors because of their good sensitivity, selectivity, stability and consistency. However, in some special occasions, it is necessary to have a very high detection limit for the target gas, and a singl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N27/00B32B9/00B32B9/04B32B33/00B82Y30/00B82Y40/00
CPCG01N27/00B32B9/00B32B9/04B32B33/00B82Y40/00B82Y30/00
Inventor 王海容田鑫王久洪曹慧通李剑金成
Owner XI AN JIAOTONG UNIV