High-temperature-resistant polymer containing m-carborane group and preparation method of high-temperature-resistant polymer

Abstract

The invention discloses a high-temperature-resistant polymer containing m-carborane group and a preparation method of the high-temperature-resistant polymer. The high-temperature-resistant polymer is poly[bis(4-chlorphenyl)-m-carborane] or poly[bis(3-chlorphenyl)-m-carborane], the thermal stability is good, the oxidation resistance is good, the ceramic yield is high, and the polymer can be applied to the fields of boron carbide ceramic precursors, anti-oxidation coatings, neutron shielding materials, photoluminescent materials and the like. The preparation method comprises the steps of monomer synthesis, monomer polymerization and the like, m-carborane which is stable in property and low in toxicity is used as a boron source substance to replace unstable and highly toxic decaborane adopted in the prior art, the process is simple and safe, the synthesis difficulty of the polymer is low, and the preparation method is suitable for mass production.

Description

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AI Technical Summary

Benefits of technology

This patented inventor describes different methods that make sure they have good heat resistance while also being able to store them overnight without losing their original quality when needed. These techniques include adding certain substances called meta carriers (metal atoms) into the composition during manufacturing processes such as calcination, sintering, etc., create special structures on the surface of these compositions, and then treat them afterwards under specific temperatures until crystalline phases form naturally within seconds. By controllably changing this phase structure, researchers found out how well the resulting compound was effective against various types of radiation damage caused by alpha rays. Overall, this technology provides technical means for producing strong thermally protected organopolymers useful as antioxiatic/radiation coatings and other applications related to atomic energy science technologies including radioactive waste management.

Problems solved by technology

This patented technical solution describes how certain types of molecules called chalcogenides are found naturally occurring within organisms that contain silicon (Si). These molecular structures make up about 70 per cent of all known natural substances - including many important biological functions such as photosynthesis or bone growth processes. They help stabilise these systems at very specific temperatures during their formation. By introducing them inside another type of material like plastics they could be used for various applications where heat protection, mechanical strength, optical transparency, etc., were needed.

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