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High-recovery battery negative electrode slurry, preparation method thereof and lithium battery

A battery negative electrode and recovery technology, which is applied to the high recovery battery negative electrode slurry and its preparation method and the field of lithium batteries, can solve the problems of complicated and tedious operation and limited adjustment range, and achieves good sag, large wetting angle, and battery The effect of increased capacity

Pending Publication Date: 2021-07-09
云南航开科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This adjustment method is complicated and cumbersome to operate, and the parameters need to be adjusted continuously until the required thin zone length is reached. Secondly, this adjustment method is greatly affected by the properties of the slurry and the assembly of the die head, and the adjustment range is limited.

Method used

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  • High-recovery battery negative electrode slurry, preparation method thereof and lithium battery
  • High-recovery battery negative electrode slurry, preparation method thereof and lithium battery
  • High-recovery battery negative electrode slurry, preparation method thereof and lithium battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The negative electrode slurry has a viscosity recovery rate of more than 73% in a thixotropic test, and the length of the thinned area of ​​the negative electrode sheet prepared by it is 2.2mm. The production process is as follows: ① dry mix 100% negative electrode graphite and 100% conductive agent, turn on revolution, disperse at a linear speed of 6m / s, stir and disperse for 30min; ② add the first CMC solution, and the amount of CMC is 60% of the total amount added , open revolution, disperse linear speed 10m / s, stir and disperse for 30min ③ add the remaining CMC solution and appropriate amount of deionized water, the solid content is 55%, open revolution, disperse linear speed 10m / s, stir and disperse for 30min ④ finally add SBR solution, open Revolution, dispersing line speed 6m / s, stirring and dispersing for 20min to obtain sample 1.

Embodiment 2

[0033] A negative electrode slurry, the viscosity recovery rate of which is above 76% in the thixotropic test, and the length of the thinned area of ​​the negative electrode sheet prepared by it is 1.5mm. The production process is as follows: ① dry mix 100% negative electrode graphite and 100% conductive agent, turn on revolution, disperse at a linear speed of 6m / s, stir and disperse for 30min; ②add the first CMC solution, and the amount of CMC is 50% of the total amount added , open revolution, disperse linear speed 10m / s, stir and disperse for 30min ③ add the remaining CMC solution and appropriate amount of deionized water, the solid content is 55%, open revolution, disperse linear speed 10m / s, stir and disperse for 30min ④ finally add SBR solution, open Revolution, dispersing line speed 6m / s, stirring and dispersing for 20min to obtain sample 2.

Embodiment 3

[0035] A negative electrode slurry whose viscosity recovery rate in a thixotropy test is above 80%, and the length of the thinned area of ​​the negative electrode sheet prepared by it is 1.0mm. The production process is as follows: ① Dry mix 100% negative electrode graphite and 100% conductive agent, open revolution, disperse at a linear speed of 6m / s, stir and disperse for 30min ②Add the first CMC solution, the amount of CMC is 40% of the total amount added , open revolution, disperse linear speed 10m / s, stir and disperse for 30min ③ add the remaining CMC solution and appropriate amount of deionized water, the solid content is 55%, open revolution, disperse linear speed 10m / s, stir and disperse for 30min ④ finally add SBR solution, open Revolution, dispersing line speed 6m / s, stirring and dispersing for 20min to obtain sample 3.

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Abstract

The invention relates to a preparation method of high-restorability battery negative electrode slurry, which comprises the following steps: mixing negative electrode graphite and a conductive agent, stirring and dispersing to obtain a dry powder mixture; preparing a CMC solution and dividing the CMC solution into a first CMC solution and a second CMC solution, wherein the first CMC solution accounts for 40-60% of the mass fraction of the prepared CMC solution; adding a first CMC solution into the dry powder mixture, and stirring and dispersing to obtain a first mixed solution; adding a second CMC solution and water into the first mixed solution, performing stirring and dispersing, obtaining a second mixed solution, wherein the solid content of the second mixed solution is 50%-60%; and adding an SBR solution into the second mixed solution, and stirring and dispersing to obtain the product. Through the mode, the viscosity of the battery negative electrode slurry is increased, the slurry leveling property is reduced, the sagging becomes good, the infiltration angle becomes large in the sagging and die head extrusion process, then a thin area is shortened, and the battery capacity is correspondingly increased.

Description

technical field [0001] The invention relates to the technical field of batteries, in particular to a high recovery battery negative electrode slurry, a preparation method thereof and a lithium battery. Background technique [0002] The formation of negative electrode coating thinning area-the coating process is actually a spreading and wetting process of the slurry on the substrate, and the slurry can be spread on the substrate, requiring its surface tension to be lower than the surface energy of the substrate. There is a contact angle at the edge of the coating slurry, which is defined as the angle between the gas-liquid interface tangent and the solid-liquid interface at the intersection of gas, liquid and solid. When the included angle is less than 90 degrees, the slurry can wet the substrate, and the distance from the three-phase intersection point to the stable point of wet film thickness is the thinning zone. The schematic diagram of the contact angle and the thinned ...

Claims

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Application Information

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IPC IPC(8): H01M4/04H01M10/052H01M10/42
CPCH01M4/04H01M10/052H01M10/4235Y02E60/10
Inventor 王瑛
Owner 云南航开科技有限公司
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