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Photocurable resin composition, photocurable resin article, and methods of fabricating the article

A technology of photocurable resin and resin, applied in the fields of photocurable resin, 3D printed resin products, and manufactured products

Active Publication Date: 2021-08-13
RGT UNIV OF CALIFORNIA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Current thermoplastic aligners cannot do this due to material homogeneity

Method used

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  • Photocurable resin composition, photocurable resin article, and methods of fabricating the article
  • Photocurable resin composition, photocurable resin article, and methods of fabricating the article
  • Photocurable resin composition, photocurable resin article, and methods of fabricating the article

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experiment example

[0103]The invention will now be described with reference to the following examples. These examples are provided for the purpose of illustration only, and the invention is not limited to these examples, but encompasses all variations apparent as a result of the teaching provided herein.

[0104] Materials and methods

[0105] Synthesis of Photocurable MDI-PEGMA

[0106] MDI-PEGMA was synthesized using 4,4'-methylene bis(phenylisocyanate) (MDI) (10.00 g, 40.00 mmol), which was added to a round bottom flask with inert atmosphere, stir bar and heated to 60°C. After the MDI reagent melted, poly(ethylene glycol) methacrylate (PEGMA) (32.55 mL, 100.00 mmol) was added dropwise, and reacted at 60° C. for 8 h. Afterwards, the reaction was allowed to proceed overnight at room temperature. The synthesized compound (MDI-PEGMA) was collected using a positive displacement pipette and analyzed by proton NMR spectroscopy ( 1 H NMR) and by Fourier transform infrared spectroscopy (FT-IR...

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Abstract

The present invention relates in part to a photocurable resin composition comprising a first compound formed from the reaction of a diisocyanate and an isocyanate reactive compound comprising a double bond, a second compound comprising one or more double bonds susceptible to polymerization, and a photoinitiator. The invention also relates in part to a method of making the photocurable resin composition. The invention also relates in part to a method of fabricating an article comprising the steps of providing a photocurable resin composition comprising a first compound formed from the reaction of a diisocyanate and an isocyanate reactive compound comprising a double bond, a second compound comprising one or more double bonds susceptible to polymerization, and a photoinitiator; 3D printing the photocurable resin to form an article; and curing the article. The invention also relates in part to a 3D printed resin article.

Description

[0001] Citations to related applications [0002] This application claims priority to U.S. Provisional Application No. 62 / 747,694, filed October 19, 2018, which is hereby incorporated by reference in its entirety. Background technique [0003] Dental malocclusion affects approximately 60% to 75% (or 4.6 to 5.7 billion) of the global population. Therefore, there is a huge global demand for orthodontic treatments to correct malocclusions. Approximately 15% of these cases are treated with orthodontic clear aligners (690 to 855 million patients per year), representing a $1.5 billion market size. From 2018-2021, the compound annual growth rate of this segment is expected to be 12.16%, and by 2021, it may reach 2.7 billion US dollars. The aligners are manufactured through the following process: 1) taking a dental impression of the patient using a 3D scanner; 2) digitizing and converting the dental impression into an STL file compatible with stereolithography CAD software; Orthodo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A61C7/08A61C7/12C08F220/10C08F226/08C08G75/26
CPCA61C7/08B33Y70/00B33Y80/00B33Y10/00C08F222/1065C09D4/06C08F290/067C08G18/7621C08G18/7671C08G18/672C08G18/6715C08L75/16C08F222/102C08F222/103C08F265/06C08F222/10C08G18/48C08F220/346C08F220/286C08F222/1063C08F2/50A61C7/12C08F283/06C09D151/08
Inventor 本杰明·M·吴乔瓦尼·F·A-V
Owner RGT UNIV OF CALIFORNIA
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