Photocurable resin composition, photocurable resin article, and methods of fabricating the article
A technology of photocurable resin and resin, applied in the fields of photocurable resin, 3D printed resin products, and manufactured products
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[0103]The invention will now be described with reference to the following examples. These examples are provided for the purpose of illustration only, and the invention is not limited to these examples, but encompasses all variations apparent as a result of the teaching provided herein.
[0104] Materials and methods
[0105] Synthesis of Photocurable MDI-PEGMA
[0106] MDI-PEGMA was synthesized using 4,4'-methylene bis(phenylisocyanate) (MDI) (10.00 g, 40.00 mmol), which was added to a round bottom flask with inert atmosphere, stir bar and heated to 60°C. After the MDI reagent melted, poly(ethylene glycol) methacrylate (PEGMA) (32.55 mL, 100.00 mmol) was added dropwise, and reacted at 60° C. for 8 h. Afterwards, the reaction was allowed to proceed overnight at room temperature. The synthesized compound (MDI-PEGMA) was collected using a positive displacement pipette and analyzed by proton NMR spectroscopy ( 1 H NMR) and by Fourier transform infrared spectroscopy (FT-IR...
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