Preparation method of precipitated white carbon black for high-performance truck tire
A precipitation silica, high-performance technology, applied in chemical instruments and methods, silicates, silicon compounds, etc., can solve the problem that the tire driving performance cannot meet the requirements, shorten the tire service life, and the reinforcement performance is not as good as carbon black. and other problems, to achieve the effect of reducing Mooney viscosity and vulcanization time, improving processing performance, and reducing silanol content
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Embodiment 1
[0030] The preparation method of the high-performance truck tire of the present invention uses the precipitated silica to operate according to the following steps:
[0031] At first carry out following A reaction and B reaction simultaneously in two reactors respectively:
[0032] A reaction:
[0033] A1. Add water and sodium silicate to the reaction kettle, feed steam to raise the temperature to 85°C under the condition of stirring frequency 45Hz, so that the pH in the reaction kettle is maintained at 9.5, and the modulus of sodium silicate is 3.0;
[0034] A2, add sodium silicate and vitriol oil simultaneously in reactor, make reaction medium pH value be stable at about 9.5; The flow velocity of described sodium silicate is 15m 3 / h, the modulus is 3.0; the flow velocity of the concentrated sulfuric acid is 1.0m 3 / h, mass fraction is 98%; The feeding time of described sodium silicate and the concentrated sulfuric acid is 1.5h;
[0035] A3, stop the addition of sodium sil...
Embodiment 2
[0044] The temperature of the reaction in step A1 is 90° C., and other steps and parameters are the same as in Example 1.
Embodiment 3
[0046] The time of step C1 compound reaction is 30min, and other steps and parameter are with embodiment 1.
[0047] Table 1 shows the comparative analysis of the comprehensive chemical performance indicators of the high wear resistance silica products obtained in the above three examples and the comparison examples of ordinary silica.
[0048] As can be seen from Table 1, the difference between BET and CTAB of the white carbon black product of the embodiment is less than the comparative example, showing that the performance of the white carbon black reinforced rubber of the embodiment is better than that of the comparative example; the surface hydroxyl content of the white carbon black product of the embodiment It is lower than that of the comparative example, indicating that the silica modified with sodium aluminosilicate can reduce the content of silicon hydroxyl groups on the surface, so that the compatibility between silica and rubber is improved.
[0049] Table 1 Compari...
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