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Preparation method of precipitated white carbon black for high-performance truck tire

A precipitation silica, high-performance technology, applied in chemical instruments and methods, silicates, silicon compounds, etc., can solve the problem that the tire driving performance cannot meet the requirements, shorten the tire service life, and the reinforcement performance is not as good as carbon black. and other problems, to achieve the effect of reducing Mooney viscosity and vulcanization time, improving processing performance, and reducing silanol content

Pending Publication Date: 2021-10-22
FUJIAN ZHENGSHENG INORGANIC MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But because the white carbon black product that prior art produces, its surface hydroxyl is more, causes the interaction between white carbon black and rubber to be smaller than the interaction between carbon black and rubber, and the reinforcing performance of white carbon black to rubber It is not as good as carbon black; if the amount of silica used in the tread rubber of all-steel radial truck tires is too large, the tire driving performance will not meet the requirements, mainly reflected in the decrease of tire wear resistance, thereby shortening the service life of the tire

Method used

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  • Preparation method of precipitated white carbon black for high-performance truck tire

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] The preparation method of the high-performance truck tire of the present invention uses the precipitated silica to operate according to the following steps:

[0031] At first carry out following A reaction and B reaction simultaneously in two reactors respectively:

[0032] A reaction:

[0033] A1. Add water and sodium silicate to the reaction kettle, feed steam to raise the temperature to 85°C under the condition of stirring frequency 45Hz, so that the pH in the reaction kettle is maintained at 9.5, and the modulus of sodium silicate is 3.0;

[0034] A2, add sodium silicate and vitriol oil simultaneously in reactor, make reaction medium pH value be stable at about 9.5; The flow velocity of described sodium silicate is 15m 3 / h, the modulus is 3.0; the flow velocity of the concentrated sulfuric acid is 1.0m 3 / h, mass fraction is 98%; The feeding time of described sodium silicate and the concentrated sulfuric acid is 1.5h;

[0035] A3, stop the addition of sodium sil...

Embodiment 2

[0044] The temperature of the reaction in step A1 is 90° C., and other steps and parameters are the same as in Example 1.

Embodiment 3

[0046] The time of step C1 compound reaction is 30min, and other steps and parameter are with embodiment 1.

[0047] Table 1 shows the comparative analysis of the comprehensive chemical performance indicators of the high wear resistance silica products obtained in the above three examples and the comparison examples of ordinary silica.

[0048] As can be seen from Table 1, the difference between BET and CTAB of the white carbon black product of the embodiment is less than the comparative example, showing that the performance of the white carbon black reinforced rubber of the embodiment is better than that of the comparative example; the surface hydroxyl content of the white carbon black product of the embodiment It is lower than that of the comparative example, indicating that the silica modified with sodium aluminosilicate can reduce the content of silicon hydroxyl groups on the surface, so that the compatibility between silica and rubber is improved.

[0049] Table 1 Compari...

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Abstract

The invention discloses a preparation method of precipitated white carbon black for a high-performance truck tire, wherein composite reaction modification is carried out on superfine sodium aluminosilicate and silicon dioxide to prepare high-wear-resistance composite silicon dioxide. The preparation method comprises the following steps: firstly, respectively carrying out reactions A and B in two reaction kettles, namely reacting water, silicate and an acidifying agent in the reaction A to obtain a silicon dioxide suspension, and reacting water, silicate, an aluminum compound and an acidifying agent in the reaction B to obtain a superfine sodium aluminosilicate suspension; then feeding the superfine sodium aluminosilicate suspension obtained through the reaction in the step B into the silicon dioxide suspension obtained through the reaction in the step A, wherein the mixing volume ratio of the superfine sodium aluminosilicate suspension to the silicon dioxide suspension is 1:10-1:2, so as to prepare the superfine sodium aluminosilicate composite high-wear-resistance white carbon black slurry; and filtering the slurry, performing flash drying or spray drying to obtain a powdery or microbead-shaped white carbon black product, and finally briquetting the white carbon black to obtain a granular high-wear-resistance composite silicon dioxide product. The white carbon black has good compatibility in rubber, and the prepared tire product has low rolling resistance and high control performance and wear resistance.

Description

technical field [0001] The invention relates to a preparation method of inorganic chemical product white carbon black, in particular to a preparation method of precipitation method white carbon black for high-performance truck tires. Background technique [0002] Precipitated hydrated silica, also known as white carbon black, has a flocculent and network structure in its microstructure. The special structure of silica makes it have unique properties, and it is widely used in various fields such as rubber, silicone rubber, paint, heat insulation materials, insulating materials, inks and advanced daily cosmetics. In 1992, Michelin proposed the concept of "green tires", and silica was used in the rubber formula of tires. Silica, as a substitute for carbon black, has a very good reinforcing effect. After adding rubber tires, it can reduce heat generation and rolling resistance, etc., and can maintain the wet skid resistance and wear resistance of tires, reducing The fuel consu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/30C09C3/06C01B33/193C01B33/26C08K9/02C08K3/36
CPCC09C1/3045C09C3/06C01B33/193C01B33/26C08K9/02C08K3/36C01P2006/12C01P2006/19C01P2006/90C01P2004/80Y02T10/86
Inventor 任立荣徐功智曾志恩田明徐钰兴刘安基檀东宇黄永生谢志雄
Owner FUJIAN ZHENGSHENG INORGANIC MATERIAL
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