Toughened glass with scratch resistance and preparation method thereof
A technology for strengthening glass and scratch resistance, applied in the field of tempered glass with scratch resistance and its preparation, can solve the problems of low failure strain, lack of flexural strength, drop resistance, etc., and achieve strong chemical strengthening mechanical properties, The effect of strong performance and excellent scratch resistance
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preparation example Construction
[0067] In another aspect, the present invention provides a method for preparing the above strengthened glass, comprising:
[0068] Step S1: According to the mole percentage of oxide, take SiO 2 63~69%, Al 2 o 3 10-17%, Na 2 O 5~14.5%, K 2 O 0.01~1%, Li 2 O 8~12%, MgO 2.4~4.6% and ZrO 2 0.01~2%, of which, the mole percentage satisfies SiO 2 / (K 2 O+Na 2 O+Li 2 O+MgO): 2.5 to 3.8 to obtain a mixed material;
[0069] Step S2: After melting the mixed materials, forming, annealing and cutting, the certificated glass is obtained;
[0070] Further, the outlet temperature T of the tin bath during the forming process is controlled so that the difference between the outlet temperature T of the tin bath and the transition point temperature Tg of the glass is below 50°C.
[0071] Further, the annealing time in the annealing step is 50-90 min; preferably, the annealing time is 60-80 min; more preferably, the annealing time is 65-75 min.
[0072] Further, the melting temperat...
Embodiment approach 1
[0084] Using the float forming process, the strengthened glass is prepared according to the following method:
[0085] 1. Preparation of raw materials: According to the composition ratios of Examples 1-10 in Table 2 and Comparative Examples 1-5 in Table 3, the raw materials of each oxide were mixed for 10 minutes to obtain a mixed material.
[0086] 2. Melting: Put the mixed material into the melting furnace for melting, adopt the double hot spot melting process, heat the mixed material to 1650 ℃, until the mixed material is completely melted.
[0087] 3. Forming: The melted glass flows through the tin bath, and is formed under the action of the edge puller, and the outlet temperature T of the tin bath is controlled so that the temperature T at the outlet of the tin bath is equal to the transition point temperature Tg of the certified glass. The difference between them is below 50°C.
[0088] 4. Annealing: The formed glass is annealed in an annealing kiln. The annealing time ...
Embodiment approach 2
[0100] Using the float forming process, the strengthened glass is prepared according to the following method:
[0101] 1. Prepare raw materials: according to the composition ratio in Table 4, take the raw materials of each oxide and mix them for 8 minutes to obtain the mixed materials.
[0102] Table 4. The percentage mole ratio of each oxide
[0103] SiO 2
Al 2 o 3
Na 2 o
K 2 o
Li 2 o
MgO ZrO 2
SiO 2 / (K 2 O+Na 2 O+Li 2 O+MgO)
65.78 12.00 6.30 0.60 10.40 3.60 1.30 3.15
[0104] 2. Melting: Put the mixed material into the melting furnace for melting, adopt double hot spot melting process, heat the mixed material at 1640°C until the mixed material is completely melted.
[0105] 3. Forming: The melted glass flows through the tin bath, and is formed under the action of the edge puller, and the outlet temperature T of the tin bath is controlled so that the temperature T at the outlet of the tin bath is equ...
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Abstract
Description
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