Concrete water reducing agent as well as preparation method and application thereof

A concrete water reducing agent and water solution technology, which is applied in the field of concrete building materials, can solve the problems of early strength effect, long concrete setting time, insufficient slump retention performance, etc., and achieves delaying hydration reaction, improving water solubility and electrocatalysis The effect of enhancing the slump protection effect

Active Publication Date: 2022-04-15
重庆建研科之杰新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there is a method of compounding retarding components in PCE. Although this method can improve the slump of concrete to a certain extent, it still cannot fully meet the requirements of slump retention performance, and it will also cause the concrete to set for too long. intensity is affected

Method used

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  • Concrete water reducing agent as well as preparation method and application thereof

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Effect test

Embodiment 1

[0027] This embodiment provides a concrete water reducer and its preparation method, wherein the water reducer is made of the following raw material components by weight: 330 parts by weight of methallyl polyoxyethylene ether, 400 parts by weight of water, thioglycolic acid 3 parts by weight, 29 parts by weight of acrylic acid, 1.8 parts by weight of hydrogen peroxide, 0.4 parts by weight of vitamin C, 1.5 parts by weight of graphene oxide, 18 parts by weight of caustic soda, and 15 parts by weight of methyl 2-chloroacrylate.

[0028] Concrete preparation method comprises the following steps:

[0029] (1) Take 1.5 parts by weight of graphene oxide and 300 parts by weight of water into the reaction kettle, turn on the high-power industrial-grade continuous flow energy-concentrating ultrasonic disperser, the control parameters are: ultrasonic frequency 20±1kHz, ultrasonic power 3000W, ultrasonic 15min, then add 18 parts by weight of caustic soda and 15 parts by weight of 2-chlor...

Embodiment 2

[0033] This embodiment provides a concrete water reducer and its preparation method, wherein the water reducer is made of the following raw material components in parts by weight: 370 parts by weight of methallyl polyoxyethylene ether, 440 parts by weight of water, isopropyl 4 parts by weight of alcohol, 37 parts by weight of methacrylic acid, 2.2 parts by weight of ammonium persulfate, 0.8 parts by weight of sodium bisulfite, 2 parts by weight of graphene oxide, 19 parts by weight of caustic soda, and 16 parts by weight of 2-chloroacrylic acid.

[0034] Concrete preparation method is with embodiment 1.

Embodiment 3

[0036] This embodiment provides a concrete water reducer and its preparation method, wherein the water reducer is made of the following raw material components in parts by weight: 410 parts by weight of methallyl polyoxyethylene ether, 470 parts by weight of water, mercaptopropylene 4.8 parts by weight of acid, 49 parts by weight of citraconic acid, 2.6 parts by weight of hydrogen peroxide, 0.4 parts by weight of ferrous sulfate, 3 parts by weight of graphene oxide, 20 parts by weight of caustic soda, and 18 parts by weight of 2-chloroacrylic acid.

[0037] Concrete preparation method is with embodiment 1.

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Abstract

The invention provides a concrete water reducing agent as well as a preparation method and application thereof. The preparation method of the concrete water reducing agent comprises the following steps: step 1, uniformly mixing graphene oxide and water, adding solid alkali, and reacting with 2-chloroacrylic acid to prepare carboxylated graphene dispersion liquid; step 2, adding methyl allyl polyoxyethylene ether or isopentenyl polyoxyethylene ether into the carboxylated graphene dispersion liquid, uniformly mixing, adding an initiator, and uniformly mixing; 3, respectively preparing a water solution I mixed by a chain transfer agent and a reducing agent and a water solution II of an olefine acid compound; step 2, simultaneously dropwise adding an aqueous solution I and an aqueous solution II into the mixed solution obtained in the step 2 at 45 DEG C or below, controlling the dropwise adding time of the aqueous solution I and the aqueous solution II to be 2-3.5 hours, after dropwise adding is completed, carrying out heat preservation reaction for 1-2 hours, and after the reaction is completed, regulating the pH to 6.8-7.2 by adopting a pH regulator. The concrete water reducing agent disclosed by the invention can be effectively used as a special water reducing agent for concrete, and has excellent water reducing effect and slump retaining effect.

Description

technical field [0001] The invention belongs to the technical field of concrete building materials, and in particular relates to a concrete water reducer and its preparation method and application. Background technique [0002] In recent years, China has increased its internal infrastructure construction and actively participated in the export of key foreign engineering projects and high-speed rail technology. This is inseparable from the improvement of high-performance concrete technology. Concrete admixtures, especially polycarboxylate superplasticizers ( PCE) also present higher and more diverse demands. Predecessors have done a lot of work on the preparation, performance, application and mechanism of action of PCE, and have achieved certain results. However, in terms of basic theoretical research, due to different research systems and set boundary conditions, researchers have drawn different or even contradictory conclusions on the relationship between PCE molecular str...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/26C08F283/06C08F220/06C08F220/22C08F220/04C08F222/02C04B103/30
CPCY02W30/91
Inventor 李卫黄小文李渝江孟祥杰
Owner 重庆建研科之杰新材料有限公司
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