Preparation method of nanometer aggregated zirconia powder for hot spraying

A technology of zirconia powder and nano-zirconia, which is applied to devices and coatings for coating liquid on the surface, can solve the problems of high cost, the difference between practical application and scale of production, and difficulty in large-scale production, etc. The effect of low cost, easy control of process parameters and simple equipment

Inactive Publication Date: 2006-05-17
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are also problems of high cost and difficulty in achieving large-scale production
In addition, there are some studies and discussions on combining the above preparation methods with plasma spray pyrolysis and supercritical drying, but they are still far from the actual application and scale of production.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Get 9.8 kilograms of yttrium oxide partially stabilized nano-zirconia powder (its ZrO 2 with Y 2 o 3 The mass ratio is 93:7), adding 0.2 kg of polyvinyl alcohol adhesive, after mixing thoroughly, then adding 10 kg of clean water and stirring to form a uniformly dispersed and suspended slurry for use.

[0026] Use dry and pure compressed air as the carrying gas, the gas pressure is controlled at 0.8Mpa, and the slurry is sprayed into the drying tower by a two-flow nozzle. The atomized slurry shrinks into a reunited hollow spherical shape by its own surface tension, and is dried in hot air , The heating temperature of the drying tower heater is controlled between 150 and 280 ° C, and the adjustment of the temperature is limited to the sufficient drying of the powder. The dried agglomerated powder is then drawn into a cyclone for collection by means of an aspirator. The collected powder is sieved with a mechanical sieve, and the powder between 180-325 mesh sieves is tak...

Embodiment 2

[0030] Get 9.5 kilograms of yttrium oxide partially stabilized nano-zirconia powder (its ZrO 2 with Y 2 o 3The mass ratio is 94:6), add 0.1 kg of dextrin, 0.2 kg of polystyrene and polyvinyl alcohol adhesives, mix thoroughly to form a 10 kg solid mixture, then add 10 kg of clean water and stir until uniform Disperse and suspend the slurry for use.

[0031] Spray the slurry into the drying tower with a centrifugal atomizing nozzle. The rotational speed of the centrifugal atomizer is 800-2000r / min. The atomized slurry particles shrink into a solid spherical shape by their own surface tension, and are dried in hot air. The heating temperature of the tower heater is controlled between 150 and 280 ° C, and the adjustment of the temperature is limited to the sufficient drying of the powder. The dried agglomerated powder is then drawn into a cyclone for collection by means of an aspirator. The collected powder is sieved with a mechanical sieve, and the powder between 180-325 mesh...

Embodiment 3

[0035] Get 9.8 kilograms of yttrium oxide partially stabilized nano-zirconia powder (its ZrO 2 with Y 2 o 3 The mass ratio is 94:6), adding 0.1 kg of carboxymethyl cellulose and polyvinyl alcohol adhesive, mixed thoroughly to make 10 kg of solid mixture, and then adding 10 kg of clean water and stirring to form a uniformly dispersed suspension The slurry is ready for use.

[0036] Use dry and pure compressed air as the carrying gas, the gas pressure is controlled at 0.8Mpa, and the slurry is sprayed into the drying tower by a two-flow nozzle. The atomized slurry shrinks into a reunited hollow spherical shape by its own surface tension, and is dried in hot air , The heating temperature of the drying tower heater is controlled between 150 and 280 ° C, and the adjustment of the temperature is limited to the sufficient drying of the powder. The dried agglomerated powder is then drawn into a cyclone for collection by means of an aspirator. The collected powder is sieved with a ...

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Abstract

A method for preparing nano-agglomerated zirconia powder for thermal spraying. It mixes the partially stabilized nano-zirconia powder with a particle size of 20-60nm yttrium oxide and the binder at a mass ratio of 95:5-98:2, and adds 1-1.3 times the weight of the mixture to prepare the raw material. Then use the spray drying process to make micron-sized aggregate powder in the range of 110-300°C, and then process the aggregated powder by plasma spheroidization or sintering densification to make it dense and maintain the same nanocrystalline structure. 40~90μm powder. The obtained powder can meet the technical requirements of plasma spraying or flame spraying. The technology has few technological processes, simple operation, large production capacity, safety and reliability, and low manufacturing cost, and is suitable for continuous large-scale industrial production.

Description

technical field [0001] The invention relates to a method for preparing a surface engineering material for thermal spraying, in particular to a method for preparing a nanocrystalline agglomerated zirconia powder material for plasma spraying or flame spraying. Background technique [0002] Zirconia is a partial acidic oxide with a melting point of 2760°C, low thermal conductivity and good chemical stability. It is stable in high temperature oxidation and weak reducing atmospheres, and can withstand SO 2 , CO and CO 2 Corrosion of high temperature gas. But pure ZrO 2 The material is generally not used as a high-temperature resistant coating because of its crystalline transformation that can cause denudation. As the temperature changes, different crystal forms of zirconia crystals will appear: normal temperature to 1000 ° C, monoclinic crystal β-ZrO 2 ; Over 1000°C, transforms into tetragonal α-ZrO 2 , with a volume change of about 7%. When it is cooled again, the monoclin...

Claims

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Application Information

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Patent Type & AuthorityPatents(China)
IPC IPC(8): C09D1/00B05D1/08
Inventor程旭东
OwnerWUHAN UNIV OF TECH