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Process for preparing proton exchange film fuel cell multi component catalyst

A technology of proton exchange membrane and fuel cell, which is applied in the direction of catalyst carrier, chemical instrument and method, physical/chemical process catalyst, etc. It can solve the problems of high cost, lack of resources, and limitation of the practical speed of fuel cell, so as to achieve less reunion, High purity, effect of improving anti-CO poisoning ability

Inactive Publication Date: 2006-06-07
TSINGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, noble metals such as platinum (Pt) and ruthenium (Ru) are used as electrode catalysts for proton exchange membrane fuel cells (PEMFC), and the cost is high and resources are scarce, which greatly limits the practical speed of fuel cells.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0022] 1) 20 parts of activated carbon, 30 parts of chloroplatinic acid, 30 parts of ruthenium trichloride, and 20 parts of cerium oxide are added to a closed container filled with 75% deionized water to form a premix;

[0023] 2) After the premix is ​​reacted for 6 hours in a nitrogen atmosphere at 200°C and a pressure of 2.5Mpa, it is cooled to room temperature;

[0024] 3) Add 2 parts of sodium thiosulfate and treat at 140°C for 4 hours to uniformly fix platinum, ruthenium and cerium on the original position of the reduction reaction;

[0025] 4) The slurry formed above is filtered, washed, and dried to obtain a PtRuCe / C multi-element catalyst.

example 2

[0027] 1) 25 parts of carbon nanotubes, 50 parts of platinum chloride, 10 parts of ruthenium oxide, and 15 parts of samarium oxide are added to a closed container to which 80% deionized water has been added to form a premix;

[0028] 2) After the premix is ​​reacted for 8 hours at 150°C and a pressure of 2Mpa in an argon atmosphere, it is cooled to room temperature;

[0029] 3) Add 4 parts of sodium dithionite and treat at 120°C for 6 hours to uniformly fix platinum, ruthenium and samarium on the original position of the reduction reaction;

[0030] 4) The slurry formed above is filtered, washed, and dried to obtain a PtRuSm / C multi-element catalyst.

example 3

[0032] 1) 20 parts of activated carbon, 25 parts of platinum oxide, 25 parts of ruthenium oxide, and 30 parts of yttrium oxide are added to a closed container to which 80% deionized water has been added to form a premix;

[0033] 2) After the premix is ​​reacted for 6 hours at 300°C under a pressure of 2Mpa in a nitrogen atmosphere, it is cooled to room temperature;

[0034] 3) Add 2 parts of sodium formate and treat at 200°C for 2 hours to uniformly fix platinum, ruthenium and yttrium on the original position of the reduction reaction;

[0035] 4) The slurry formed above is filtered, washed, and dried to obtain a PtRuY / C multi-element catalyst.

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PUM

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Abstract

The invention relates to the field of fuel cell material preparation, in particular a process for preparing multi-component catalyst for proton interchange film fuel cells through water heating method which comprises, charging carrying agent, one or two noble metallic compounds, one or two rare earth metallic oxides, and deionized water into air-tight container in inert atmosphere under the condition of 110-300 deg. C, pressure 0.3-4 MPa for reaction 1-24 hours, cooling down and adding reduction agent, deacidizing 1-10 hours at 100-200 deg. C, washing, filtering and drying to obtain the multicomponent catalyst.

Description

Technical field [0001] The invention belongs to the technical scope of fuel cell material preparation, and particularly relates to a method for preparing a multi-element catalyst for a proton exchange membrane fuel cell using a hydrothermal method. Background technique [0002] At present, precious metals such as platinum (Pt) and ruthenium (Ru) are used as proton exchange membrane fuel cell (PEMFC) electrode catalysts, which have high cost and lack of resources, which greatly limits the speed of the practical use of fuel cells. In order to reduce the amount of precious metals and improve the dispersibility of precious metals, people use various preparation methods, such as sol-gel method, co-impregnation, co-deposition, colloid method, etc. to provide more specific surface area for the contact of metal particles with the carrier, and reduce the electrode unit area. The amount of Pt used to improve the utilization rate of Pt. [0003] The hydrothermal method is a wet chemical met...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/90H01M4/88B01J23/00B01J32/00
CPCY02E60/50
Inventor 谢晓峰徐景明毛宗强
Owner TSINGHUA UNIV
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