Security element formed from at least two inks applied in overlapping patterns, articles carrying the security element, and authentication methods
a security element and overlapping pattern technology, applied in the field of luminescent authentication, can solve the problems of inability to consider reliable methods, bulky and expensive, and inability to know the emission spectra of common markers (e.g. fluorescent dyes and pigments) in advance or easily determine them
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examples
[0226]The following Example is given for illustrative purposes only, and the present invention is not limited to the Example.
[0227]To illustrate the cascade effect, Lumogen® F Yellow 083 (BASF) (lum 1) and Lumogen® F Orange 240 (BASF) (lum 2) were employed. Their spectroscopic emission and excitation properties are shown in FIGS. 2 and 3 as measured on a Horiba Fluorolog-III spectrofluorometer.
[0228]The yellow dye (lum 1) acts as donor. Its emission spectrum shows two overlapping peaks at ca. 530 and 550 nm when excited at 480 nm. 530 nm is exactly one excitation peak of the orange dye (acting as acceptor, lum2) which emits at 580 nm when excited at 530 nm.
[0229]In consequence, under e.g. 400 nm excitation, the orange dye alone will be little excited, as 400 nm is not within λ2a (intensity of emission ˜1×107 units). Conversely, if the orange acceptor dye is in close contact with the yellow donor dye, in the pattern overlap regions, the emission of the donor dye at 530 nm in the regi...
formulation examples
[0277]In the following formulation examples, two different formulations of INK1 were tested based on the following blank properties in order to determine the effect of ink compositions on the observed cascade effect:
[0278]1) INK1 with solvent-based blank formulation (FORMULATION blank A) where the dry inks layer is thin and hence pigments are concentrated and much of them are close to the top surface
[0279]2) INK1 with UV-curable resin blank formulation (FORMULATION blank B) where dry ink layer is significantly thicker, the pigments are homogeneously distributed along the thickness (z axis) of the print layer, and consequently, the pigment concentration at the surface of the print is reduced as compared to the solvent based ink
[0280]Both of these inks blanks are used for silk-screen inks and their respective formulations are described in details below. For the formulation example described here, two examples of INK1 using the two different blanks were formulated by adding 15%-weight ...
PUM
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