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Security element formed from at least two inks applied in overlapping patterns, articles carrying the security element, and authentication methods

a security element and overlapping pattern technology, applied in the field of luminescent authentication, can solve the problems of inability to consider reliable methods, bulky and expensive, and inability to know the emission spectra of common markers (e.g. fluorescent dyes and pigments) in advance or easily determine them

Active Publication Date: 2021-02-23
SICPA HLDG SA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The cascade effect provides a robust and reliable authentication method that is simpler to implement, resistant to counterfeiting, and can be used in handheld devices without the need for complex equipment, ensuring the security element's genuineness.

Problems solved by technology

This approach has the drawback that the emission spectra of common markers (e.g. fluorescent dyes and pigments) can either be known in advance or can be easily determined.
Therefore, in terms of authentication, this method cannot be considered as reliable, since other marking dyes emitting in a close range may provide enough contrast to be considered as genuine.
With a standard imaging sensor, performing multi (or hyper) spectral imaging, e.g. in the NIR (near infrared range) range, would require techniques such as: (1) custom Bayer-like filters (involving expensive developments) (2) Fabry-Perot configurations (currently bulky and fairly expensive), (3) complex cameras using AOTF (Acousto-Optic Tunable Filters, which also bulky and expensive), (4) switchable band-pass interference filters (with inconvenient moving parts), or (5) imaging spectrographs requiring push-brooms (unsuitable for handheld readers).
Thus, the finer analysis of spectral properties generally requires complex, bulky and expensive equipment, and is difficult to implement in handheld devices or widely distributed authentication equipment.
However, this device does not provide an image of the mark, making it unsuitable for code reading or geometrical checks of the printed mark.

Method used

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  • Security element formed from at least two inks applied in overlapping patterns, articles carrying the security element, and authentication methods
  • Security element formed from at least two inks applied in overlapping patterns, articles carrying the security element, and authentication methods
  • Security element formed from at least two inks applied in overlapping patterns, articles carrying the security element, and authentication methods

Examples

Experimental program
Comparison scheme
Effect test

examples

[0226]The following Example is given for illustrative purposes only, and the present invention is not limited to the Example.

[0227]To illustrate the cascade effect, Lumogen® F Yellow 083 (BASF) (lum 1) and Lumogen® F Orange 240 (BASF) (lum 2) were employed. Their spectroscopic emission and excitation properties are shown in FIGS. 2 and 3 as measured on a Horiba Fluorolog-III spectrofluorometer.

[0228]The yellow dye (lum 1) acts as donor. Its emission spectrum shows two overlapping peaks at ca. 530 and 550 nm when excited at 480 nm. 530 nm is exactly one excitation peak of the orange dye (acting as acceptor, lum2) which emits at 580 nm when excited at 530 nm.

[0229]In consequence, under e.g. 400 nm excitation, the orange dye alone will be little excited, as 400 nm is not within λ2a (intensity of emission ˜1×107 units). Conversely, if the orange acceptor dye is in close contact with the yellow donor dye, in the pattern overlap regions, the emission of the donor dye at 530 nm in the regi...

formulation examples

[0277]In the following formulation examples, two different formulations of INK1 were tested based on the following blank properties in order to determine the effect of ink compositions on the observed cascade effect:

[0278]1) INK1 with solvent-based blank formulation (FORMULATION blank A) where the dry inks layer is thin and hence pigments are concentrated and much of them are close to the top surface

[0279]2) INK1 with UV-curable resin blank formulation (FORMULATION blank B) where dry ink layer is significantly thicker, the pigments are homogeneously distributed along the thickness (z axis) of the print layer, and consequently, the pigment concentration at the surface of the print is reduced as compared to the solvent based ink

[0280]Both of these inks blanks are used for silk-screen inks and their respective formulations are described in details below. For the formulation example described here, two examples of INK1 using the two different blanks were formulated by adding 15%-weight ...

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Abstract

Security element including a first and second pattern formed by a first and second material respectively in or on a first and a second region of a substrate respectively, the first pattern partially overlapping with said second pattern, the first material comprising a first luminescent dye, which upon excitation by electromagnetic radiation falling within its excitation wavelength range emits electromagnetic radiation in a first emission wavelength range, the second material comprising a second luminescent dye, which upon excitation by electromagnetic radiation falling within its excitation wavelength range emits electromagnetic radiation in a second emission wavelength range, said first emission wavelength range overlapping with the excitation wavelength range of the second luminescent dye, so that upon irradiation within the excitation wavelength range of the first luminescent dye the second luminescent dye is excited, in the overlapping area of the patterns, to emit electromagnetic radiation in the emission wavelength range.

Description

[0001]The present invention concerns a security element comprising at least two patterns PAT1 and PAT2 formed from two inks INK1 and INK2, respectively. Each of INK1 and INK2 comprises a luminescent (i.e. fluorescent and / or phosphorescent) dye or pigment, whereof the one present in INK1 (“the donor”) is capable of exciting the other present in INK2 (“the acceptor”), resulting in a cascade effect in terms of energy transfer in overlapping areas of PAT1 and PAT2. The present invention also relates to the use of this security element for authenticating articles, such as banknotes, value papers, identity documents, cards, tickets, labels, security foils, security threads and the like, articles being provided with the security element, and a method for the authentication of such articles.1. BACKGROUND ART[0002]The authentication of luminescent, in particular fluorescent, markers with imaging devices is commonly accomplished by imaging / observing the authentication mark in a certain spectr...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): G01N21/64B42D25/378B42D25/382B42D25/387G07D7/0043G07D7/1205C09D11/037C09D11/50G07D7/20G07D7/12C09D11/101C09D11/033C09D11/30C09D11/106B42D25/405B41M3/14C09D11/54
CPCB42D25/378B41M3/144B42D25/382B42D25/387B42D25/405C09D11/033C09D11/037C09D11/101C09D11/106C09D11/30C09D11/50C09D11/54G01N21/643G07D7/0043G07D7/12G07D7/1205G07D7/20G01N2021/6441G07D2207/00
Inventor DORIER, JEAN-LUCCARNERO, BENITOMILOS-SCHOUWINK, MIA
Owner SICPA HLDG SA