The invention belongs to the technical field of organic light-emitting materials, and particularly relates to a step-by-step stimuli-responsive crystalline light-emitting material and a preparation method and application thereof. The crystalline
luminescent material is a crystalline material based on a
polysulfide aromatic hydrocarbon type compound, and the
polysulfide aromatic hydrocarbon type compound is a compound based on a tetrathiobenzene mother
nucleus. The compound does not have a
photoluminescence discoloration property in a crystalline state, but has an obvious
photoluminescence discoloration property after the
crystallinity is reduced through force stimulation; and the
wavelength and proportion of
fluorescence /
phosphorescence of the compound and the
molecular orbital of an
excited state can be controlled by adjusting related substituents, so that the
optical property is adjustable. The high-
crystallinity material prepared from the compound has a
response effect on step-by-step stimulation of force and light, so that the high-
crystallinity material can be applied to
encryption anti-counterfeiting,
information storage and the like. The application scenarios include currency anti-counterfeiting,
certificate anti-counterfeiting, commodity
package anti-counterfeiting, bill anti-counterfeiting, artwork anti-counterfeiting,
electronic equipment anti-counterfeiting, logistics anti-counterfeiting, supply chain anti-counterfeiting and the like.