Microporous polyethylene film having excellent physical properties, productivity, and quality consistency, and method of producing same

Abstract

Disclosed herein is a microporous polyethylene film for a battery separator and a method of producing the same. The microporous polyethylene film is made from a resin composition. The resin composition comprises 100 parts by weight of a polyethylene composition including 10-50 wt % polyethylene having a weight average molecular weight of from 2×105 to less than 5×105 (component I) and 90-50 wt % diluent (component II), and 0-150 parts by weight of inorganic powder (component III). The film has a puncture strength of 0.20 N / μm or more and a gas permeability (Darcy's permeability constant) of 1×10−5 Darcy or more. The microporous polyethylene film has excellent physical properties, thus improving the performance and stability of a battery.

Description

BACKGROUND OF THE INVENTION [0001] 1. Field of the Invention [0002] The present invention relates to a microporous polyethylene film and a method of producing the same. More particularly, the present invention pertains to a microporous polyethylene film and a method of producing the same, in which a resin composition suitable for a roll-type stretching in a machine direction is employed, and a two-step biaxial stretching process, where stretching is implemented in a transverse direction using a tenter after stretching is conducted in the machine direction under a condition that stretching is dispersedly conducted, is conducted, thus assuring high productivity, quality consistency, and excellent physical properties. Thereby, the film can improve the performance and stability of a battery using it. [0003] 2. Description of the Related Art [0004] Having chemical stability and superior physical properties, a microporous polyolefin film is widely used as various battery separators, filte...

AI Technical Summary

Benefits of technology

The present invention provides a microporous polyethylene film for batteries that has excellent productivity and consistent quality, can produce goods having various physical properties, and ensures the stability of a battery. The film has a puncture strength of 0.20 N / mm or more and a gas permeability (Darcy's permeability constant) of 1×10−5 Darcy or more. The method of producing the film involves melt-extruding a resin composition, stretching the sheet, and extracting the diluent from the film. The film has at least 3 stretching rolls with a speed of 1.02 times a predetermined value times faster than the speed of the immediately preceding roll.

Problems solved by technology

However, the method does not use a stretching process.

However, all of the examples in the patents are limited to simultaneous biaxial stretching, or give explanations only of the biaxial stretching, but do not mention stretching temperatures in machine and transverse directions.

In other words, the patents do not disclose a characteristic of the two-step biaxial stretching in which the stretching is conducted in the transverse direction using a tenter after the stretching is conducted in the machine direction using a roll, a characteristic of simultaneous biaxial stretching, or a difference between the two characteristics.

However, since there are no chucks on a portion which is not held, no holding power is applied thereto, so it shrinks even though stretching is conducted.

Accordingly, there occurs a major disadvantage in that stretching ratios in the transverse direction are different from each other between the portions which are seized and not seized by the chucks.

Moreover, the chunk used for simultaneous stretching must be designed to endure two-directional stresses simultaneously applied in machine and transverse directions during the stretching, thus it has a complicated structure and a stretching device is costly in comparison with a chuck used to conduct unidirectional stretching.

Furthermore, it is disadvantageous in that it provides reduced stretching speed, inconsistent quality, and poor yield due to structural problems with the stretching device.

With respect to physical properties of goods, the most significant disadvantage of the commercial simultaneous biaxial stretching device is that, since the stretching ratio is fixed during a designing stage because of the complicated structure and cost, it is impossible to produce goods requiring the stretching ratio to be changed.

For example, when using the simultaneous biaxial stretching device in which stretching ratios are set to 6 times in both machine and transverse directions, it is impossible to conduct stretching so that the stretching ratio is changed to be 5 or 7 times. This means that it is difficult to produce goods having various physical properties in order to meet various needs of consumers.

However, even though the two-step biaxial stretching method is extensively used to produce a thin film, up to now, it has not been applied to the stretching process before extraction in a microporous polyolefin film wet process field.

That is to say, in a sheet mixed with an excess amount of an organic liquid compound like oil, since the liquid substance is present on the surface of the sheet, it is difficult to precisely conduct stretching in the machine direction using the roll and a typical stretching method because the sheet slips from the roll.

Additionally, since it inevitably comes into contact with the roll during the stretching, the physical properties of the microporous film are deteriorated due to damage to the surface of the sheet caused by frictional force.

Particularly, if the sheet is stretched while being pressed using a pinching roll so as to prevent the sheet from slipping, undesirably, the sheet is forcibly made thin and the pore structure of the sheet is deformed and destroyed.

However, since the hard sheet from which the compatible organic liquid compound is removed must be stretched, the stretching ratio of the sheet is reduced, thus breakage easily occurs, the stretching ratio is limited, and defective fractions increase due to small pores.

Furthermore, since the sheet which is subjected to an extraction process before the stretching is conducted is thick, a disadvantage, such as reduced extraction efficiency, occurs, as in the production of a microporous polyolefin film through a dry process.

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