Composite materials and devices comprising single crystal silicon carbide heated by electromagnetic radiation

Inactive Publication Date: 2007-10-11
ADVANCED COMPOSITE MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0096] Various techniques can be utilized to improve field uniformity. Techniques include: (1) using multiple magnetrons to inject microwave radiation into the chamber at different locations, (2) waveguides and wave-splitting devices to control microwave directionality, (3) metal reflectors, fans, and “stirrers” to disperse the microwave radiation, and (4) turntables or other devices to move the specimen in the field, thereby distributing the flux over the specimen.
[0097] Use of these techniques generally improves the uniformity of heating rates. However, the oven used in the experiments was a single magnetron system, and therefore had distinct

Problems solved by technology

However, not every form of such materials can be used in this way.
However, metal is highly conductive, and this high conductivity can lead to arcing or sparking.
For example, a large mass of solid metal typically cannot be placed in a microwave oven without causing damage from arcing and sparks caused thereby.
However, these systems typically have slow heating rates, thereby negating the benefits associated with microwave heating.
It is known that exposing silicon carbide, ceramic fibers, and microwave absorptive materials to microwave energy may lead to undesirable arcing and sparking.
However, if the object is not autoclaved, the heating rate is unacceptably slow.
There exist limitations on the use of silicon carbide in heat-generating objects.
The heating efficiency of even the most absorptive forms of silicon carbide typically is low.
Indeed, the heating efficiency of typical silicon carbide particulate is so low that such particulate is used to increase the strength and cut-resistance of microwave-heatable food contain

Method used

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  • Composite materials and devices comprising single crystal silicon carbide heated by electromagnetic radiation
  • Composite materials and devices comprising single crystal silicon carbide heated by electromagnetic radiation
  • Composite materials and devices comprising single crystal silicon carbide heated by electromagnetic radiation

Examples

Experimental program
Comparison scheme
Effect test

Example

Example 1

Heating of A Low-Loss Dielectric Fluid

[0076] Refined mineral oil of 100% hydrocarbon (paraffin oil) content has a low dielectric loss when subjected to electromagnetic radiation, including microwave radiation. Therefore, it does not heat when exposed to microwave radiation. Single crystal silicon carbide whiskers (0.6 micron average diameter, 9 micron length) and ultrafine silicon carbide particulate (TABLE 1Temperature Increase, ° C.Mineral Oil (1%Mineral Oil (1%PureTime,Single CrystalSilicon CarbideMineralsecondsSilicon Carbide)Particulate)Oil53.000108.01.002019.72.303032.34.72.7

[0077] As expected, pure mineral oil exhibits only a 2.7° C. temperature rise. Mineral oil with 1% silicon carbide particulate exhibits 4.7° C. temperature rise. Surprisingly, mineral oil with 1% by weight of single crystal silicon carbide whiskers exhibits a 32.3 ° C. temperature rise. The single crystal silicon carbide whiskers used in the invention were far superior to fine powder forms of si...

Example

Example 2

Heating of A Low-Loss Dielectric Fluid

[0078] Single crystal silicon carbide whiskers used in the invention were again added to 100% paraffin mineral oil. In this example, the silicon carbide of the invention was added at increasing weight percentages, with the goal of increasing the dielectric loss tangent with increasing weight percent single crystal silicon carbide whiskers. Each sample was separately subjected to a microwave-energy field of 2.45 GHz at 1000 watts for 20 seconds. The temperature rise is shown in Table 2 below, and is illustrated in FIG. 2: TABLE 2Wt percent Single Crystal SiliconCarbide Whiskers In Mineral OilTemperature Increase, ° C.000.58.71.019.72.032.04.868.79.1122.3

[0079] As can be clearly seen from this data, increasing the concentration of single crystal silicon carbide whiskers accelerated the temperature increase. Thus, the dielectric loss tangent increased with increasing single crystal silicon carbide whisker concentration.

Example

Example 3

Heating of A Low Dielectric Solid

[0080] Alumina is a ceramic material that has a very low dielectric loss tangent in the RF and microwave spectra. Therefore, it does not efficiently convert this energy into heat. Ceramic composites (composite material of the invention) were made by combining alumina with the single crystal silicon carbide whiskers of Example 1. These composites were then hot-pressed into a ceramic composite material of the invention. This ceramic composite was subjected to a microwave field of 2.45 GHz at 1000 watts. The temperature of the ceramic was recorded with time. Results are shown in FIG. 3.

[0081] As can be clearly seen, single crystal silicon carbide whiskers formed composite materials of the invention with alumina and heated rapidly compared with the microwave-transparent matrix material (alumina), and the rate of temperature increase was made larger by a greater proportion, measured as wt percent, of single crystal silicon carbide whiskers in ...

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Abstract

A composite material that increases in temperature upon exposure to electromagnetic radiation comprising single crystal silicon carbide whiskers and fibrils in a matrix material. Also, heat-generating objects comprising the composite material, and a method of generating heat.

Description

FIELD OF THE INVENTION [0001] The invention relates to composite materials that quickly and efficiently increase temperature by absorption of electromagnetic radiation. The invention also relates to devices comprising the composite materials, and to a method of heating using these devices. BACKGROUND OF THE INVENTION [0002] Many materials are known to not absorb microwave energy or other electromagnetic radiation. Such materials may be reflective or transparent to the electromagnetic radiation without being affected thereby. Therefore, these materials do not heat when exposed to microwave or radiowave fields. [0003] Many materials are known to absorb electromagnetic radiation and therefore will heat. Heating with microwave energy is but one example of this phenomenon, and many compositions that heat upon absorption of microwave energy are known. For example, water, fats, and certain food products absorb microwave energy and are heated thereby. Similarly, inorganic compounds such as ...

Claims

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Application Information

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IPC IPC(8): H05B6/80
CPCA23L1/0128C04B35/117C04B35/62236C04B35/645C04B35/803C04B2235/3826Y10T428/2918C04B2235/526C04B2235/5264C04B2235/5276C04B2235/5445C04B2235/6021C04B2235/5244A23L5/15C04B35/80
Inventor QUANTRILLE, THOMAS E.ROGERS, WILLIAM M.
Owner ADVANCED COMPOSITE MATERIALS
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