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A polymer electrolyte, its preparation method and application
Active
CN120824418B
Improve mechanical properties
avoid corrosion
Electrolyte accumulators manufacture
Polymer electrolytes
Polymer science
This invention provides a
polymer
electrolyte
, its preparation method, and its application. The raw materials of the
polymer
electrolyte
, by
mass
, include the following components: 8-12 parts of an olefin
polymer
, 4-8 parts of a
sodium
salt, 0.4-1.2 parts of hydrophobic
fumed silica
(SiO2), 7-30 parts of a fluorinated small-molecule
plasticizer
, and 35-85 parts of a
solvent
. The polymer
electrolyte
of this invention uses a fluorinated small-molecule
plasticizer
with weak
solvation
ability as the
plasticizer
in the electrolyte, which improves the mechanical properties of the electrolyte membrane. Simultaneously, it forms a competitive coordination effect with the
residual solvent
with strong
solvation
ability, which is beneficial for inhibiting the
corrosion
effect of
sodium
salt on the
current collector
. The hydrophobic
fumed silica
filler reduces the
crystallinity
of the polymer matrix and enhances the mobility of the polymer matrix segments, thereby improving the
ionic conductivity
.
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Owner:
HUNAN YIHUA NEW ENERGY CO LTD
+1
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