The invention relates to the technical field of electrostatic film, and in particular, relates to a polyvinyl chloride electrostatic film and a preparation method thereof, wherein the polyvinyl chloride electrostatic film comprises the following raw materials in parts by weight: 80-120 parts of PVC resin, 46-73 parts of a plasticizer, 1-3 parts of a heat stabilizer, 3-7 parts of an anti-electrostatic agent, 0.3-0.7 part of a gelatinizing agent, 0.02-0.03 part of a pigment powder, and 0.1-0.3 part of other auxiliary agents. The polyvinyl chloride electrostatic film has high electrostatic resistance, has high anti-electrostatic effect and protection functions, has high self-adhesive performance, and has excellent stable performance under high temperature conditions; the polyvinyl chloride electrostatic film also has the advantages of being ultra thin, tough, transparent, self-adhesive, good in transparency, small in watermarks and the like, has fewer crystal points and low-temperature resistance, and has excellent comprehensive performance.