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Driving electrolyte and electrolytic capacitor using the same

一种电解电容器、电解液的技术,应用在液体电解电容器、电解电容器、电容器等方向,能够解决耐热性不充分、降低电导率、电解电容器性能劣化等问题

Inactive Publication Date: 2009-05-20
PANASONIC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, when the above-mentioned dibasic acids or salts having side chains are used as the solute of the electrolytic solution for driving, in the case of only these dibasic acids or salts having side chains, for example, due to only one carboxyl group There are side chains, resulting in insufficient heat resistance at high temperatures. In addition, the longer the use time, the more the esterification reaction between the carboxyl group in the solute and alcohol such as ethylene glycol will be carried out, which will greatly reduce the conductivity at high temperature. , thus causing significant degradation to the performance of electrolytic capacitors

Method used

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  • Driving electrolyte and electrolytic capacitor using the same
  • Driving electrolyte and electrolytic capacitor using the same
  • Driving electrolyte and electrolytic capacitor using the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1 to 7

[0058] Adding to the solvent: the solute containing the compound represented by the general formula (1) and the compound represented by the general formula (2) shown in Table 1; and a nitro compound, to make each driver of Examples 1 to 7 Using the electrolytic solution, the respective driving electrolytic solutions of Comparative Examples 1 to 5 were prepared at the same time. The molar ratio 100:0 described in the following tables means that the ratio of "the number of moles of the compound represented by the general formula (1)" to "the number of moles of the compound represented by the general formula (2)" is substantially In a state of 100 to 0. It can be exemplified: after removing the compound represented by the general formula (2) from the solute containing the compound represented by the general formula (1) and the compound represented by the general formula (2), it becomes The compound shown in (2) and the remaining components are the state of the compound shown by ...

Embodiment 8 to 14

[0074] To solvent addition: containing the solute of the compound shown in Table 1 by the compound shown in general formula (1) and by the compound shown in general formula (2); One or more are selected from phosphoric acid, phosphorous acid, its salt and The compound in the alkyl phosphate ester was used to prepare the driving electrolyte solutions of Examples 8 to 14, and at the same time to prepare the driving electrolyte solutions of Comparative Examples 6 to 10.

[0075] Table 4 shows the composition of these driving electrolytes, the electrical conductivity and sparkover voltage before the heating test, and the change in electrical conductivity and sparkover voltage after a heating test at 110°C for 1000 hours in an ampoule. . In this table, the change in electrical conductivity refers to the rate of increase or decrease in the electrical conductivity after 1000 hours have elapsed when the initial value is set to 100%.

[0076] Table 4

[0077]

[0078] As shown in ...

Embodiment 15 to 21

[0090] Addition of organic solvents to ethylene glycol: the solute containing the compound shown in Table 1 by the compound shown in the general formula (1) and the compound shown in the general formula (2); nitro compound and / or at least one selected From phosphoric acid, phosphorous acid, their salts and compounds in alkyl phosphates; and polyols, to make various driving electrolytes for electrolytic capacitors.

[0091] Table 6 shows the composition of these driving electrolytes, the electrical conductivity and sparkover voltage before the heating test, and the changes in electrical conductivity and sparkover voltage after a heating test at 110°C for 1000 hours in an ampoule. . In this table, the change in electrical conductivity refers to the rate of increase or decrease in the electrical conductivity after 1000 hours have elapsed when the initial value is set to 100%.

[0092] Table 6

[0093]

[0094] As shown in Table 6, each driving electrolytic solution of Exampl...

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Abstract

A driving electrolyte containing a solvent, a solute containing the following compounds represented by General Formulae (1) and (2) prepared by synthesis, and a nitro compound, (wherein, each of R<1 >and R<2 >is independently an alkyl group; each of M<1 >and M<2 >is a functional group selected from the group consisting of a hydrogen atom, an ammonium group and an amine group; and n is an integer of 0 to 14), (wherein, R<3 >is an alkyl group; R<4 >is a functional group selected from the group consisting of a hydrogen atom, a methyl group and an ethyl group; M<3 >is a functional group selected from the group consisting of a hydrogen atom, an ammonium group and an amine group; and m is an integer of 0 to 14).

Description

technical field [0001] The present invention relates to an electrolytic solution for driving and an electrolytic capacitor using the electrolytic solution. technical background [0002] Among conventional driving electrolytes used for electrolytic capacitors, ethylene glycol is used as a solvent, and organic carboxylic acids such as azelaic acid, sebacic acid, and adipic acid or their salts are used as solutes. liquid is known to the public. This non-aqueous driving electrolyte has been used for high-voltage capacitors for a long time because it maintains good chemical conversion properties even at temperatures above 100°C. Here, the formation property refers to the film repairing ability for repairing a defect in the dielectric oxide film when the defect is generated. [0003] In addition, the above-mentioned non-aqueous electrolytic solution for driving is easy to deteriorate due to the esterification reaction at high temperature, so 1,6-decanedicarboxylic acid, 5,6-deca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G9/035H01G9/022H01G2/00H01G9/145
CPCH01G9/035H01G9/145
Inventor 高冈涼子本田一光椿雄一郎杉原之康
Owner PANASONIC CORP
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